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FluoroFix SIGNED

Catalytic C–F Bond Functionalization for the Fixation of Environmentally Persistent Fluorocarbons

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

FluoroFix project word cloud

Explore the words cloud of the FluoroFix project. It provides you a very rough idea of what is the project "FluoroFix" about.

net environmentally molecules hfos damaging bonds successful intermediates organic team reactions reactive building pharmaceuticals hydrofluorocarbons union persistent carbon series agrochemicals species aluminum inert repurpose legislation transform pioneered hydrofluoroolefins construct blocks fluorine volatile complements manufacture idea chemical fixation hfcs industry routes fluorocarbons boron

Project "FluoroFix" data sheet

The following table provides information about the project.

Coordinator	IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE Organization address address: SOUTH KENSINGTON CAMPUS EXHIBITION ROAD city: LONDON postcode: SW7 2AZ website: http://www.imperial.ac.uk/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	United Kingdom [UK]
Project website	http://crimmingroup.org
Total cost	1˙496˙925 €
EC max contribution	1˙496˙925 € (100%)
Programme	1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
Code Call	ERC-2015-STG
Funding Scheme	ERC-STG
Starting year	2016
Duration (year-month-day)	from 2016-04-01 to 2021-03-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE Organization address address: SOUTH KENSINGTON CAMPUS EXHIBITION ROAD city: LONDON postcode: SW7 2AZ website: http://www.imperial.ac.uk/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	UK (LONDON)	coordinator	1˙496˙925.00

Map

Project objective

The objective of my project is to develop new methods to transform environmentally persistent hydrofluorocarbons (HFCs) and hydrofluoroolefins (HFOs), into reactive chemical building blocks that can be used in chemical manufacture. My team will achieve this by developing a series of new chemical reactions that transform inert carbon–fluorine bonds in HFCs or HFOs into reactive carbon–boron or carbon–aluminum bonds. My team will show that these reactive species can be used to construct carbon–carbon bonds. The idea is to develop a net series of reactions that results in the fixation of fluorine from low-value, volatile, and environmentally damaging organic molecules to high-value, non-volatile organic molecules. When successful, this approach should open up new routes that allow the chemical industry to repurpose HFCs and HFOs as chemical intermediates, and not end products, that complements European Union legislation. By the end of this project, my team will have pioneered methods for the production of agrochemicals and pharmaceuticals from environmentally persistent fluorocarbons.

Publications

List of publications.
year	authors and title	journal	last update
2019	MartÃ GarÃ§on, Clare Bakewell, George A. Sackman, Andrew J. P. White, Richard I. Cooper, Alison J. Edwards, Mark R. Crimmin A hexagonal planar transition-metal complex published pages: 390-393, ISSN: 0028-0836, DOI: 10.1038/s41586-019-1616-2	Nature 574/7778	2020-02-04
2019	Greg Coates, Hui Yee Tan, Carolin Kalff, Andrew J. P. White, Mark R. Crimmin Defluorosilylation of Industrially Relevant Fluoroolefins Using Nucleophilic Silicon Reagents published pages: 12514-12518, ISSN: 1433-7851, DOI: 10.1002/anie.201906825	Angewandte Chemie International Edition 58/36	2020-02-04
2019	Nicholas A. Phillips, James Oâ€™Hanlon, Thomas N. Hooper, Andrew J. P. White, Mark R. Crimmin Dihydridoboranes: Selective Reagents for Hydroboration and Hydrodefluorination published pages: 7289-7293, ISSN: 1523-7060, DOI: 10.1021/acs.orglett.9b02515	Organic Letters 21/18	2020-02-04
2019	Thomas N. Hooper, Samantha Lau, Wenyi Chen, Ryan K. Brown, MartÃ GarÃ§on, Karen Luong, Nathan S. Barrow, Andrew S. Tatton, George A. Sackman, Christopher Richardson, Andrew J. P. White, Richard I. Cooper, Alison J. Edwards, Ian J. Casely, Mark R. Crimmin The partial dehydrogenation of aluminium dihydrides published pages: 8083-8093, ISSN: 2041-6520, DOI: 10.1039/c9sc02750e	Chemical Science 10/35	2020-02-04
2019	Richard Y. Kong, Mark R. Crimmin Reversible insertion of CO into an aluminiumâ€“carbon bond published pages: 10.1039/c9cc0281, ISSN: 1359-7345, DOI: 10.1039/c9cc02818h	Chemical Communications	2019-06-06
2019	Nicholas Phillips, Andrew White, Mark Crimmin Selective Hydrodefluorination of Hexafluoropropene to Industrially Relevant Hydrofluoroolefins published pages: 10.1002/adsc.201, ISSN: 1615-4150, DOI: 10.1002/adsc.201900234	Advanced Synthesis & Catalysis	2019-06-06
2019	Clare Bakewell, Andrew J. P. White, Mark R. Crimmin Reversible alkene binding and allylic Câ€“H activation with an aluminium( i ) complex published pages: 2452-2458, ISSN: 2041-6520, DOI: 10.1039/c8sc04865g	Chemical Science 10/8	2019-06-06
2019	MartÃ GarÃ§on, Clare Bakewell, Andrew J. P. White, Mark R. Crimmin Unravelling nucleophilic aromatic substitution pathways with bimetallic nucleophiles published pages: 1805-1808, ISSN: 1359-7345, DOI: 10.1039/c8cc09701a	Chemical Communications 55/12	2019-06-06
2018	MartÃ GarÃ§on, Andrew J. P. White, Mark R. Crimmin Palladium-catalysed magnesiation of benzene published pages: 12326-12328, ISSN: 1359-7345, DOI: 10.1039/C8CC06392C	Chemical Communications 54/87	2019-04-18
2018	Richard Y. Kong, Mark R. Crimmin Carbon Chain Growth by Sequential Reactions of CO and CO 2 with [W(CO) 6 ] and an Aluminum(I) Reductant published pages: 13614-13617, ISSN: 0002-7863, DOI: 10.1021/jacs.8b09761	Journal of the American Chemical Society 140/42	2019-04-18
2018	Thomas N. Hooper, MartÃ GarÃ§on, Andrew J. P. White, Mark R. Crimmin Room temperature catalytic carbonâ€“hydrogen bond alumination of unactivated arenes: mechanism and selectivity published pages: 5435-5440, ISSN: 2041-6520, DOI: 10.1039/c8sc02072h	Chemical Science 9/24	2019-04-18
2018	Clare Bakewell, Andrew J. P. White, Mark R. Crimmin Reactions of Fluoroalkenes with an Aluminium(I) Complex published pages: 6638-6642, ISSN: 1433-7851, DOI: 10.1002/anie.201802321	Angewandte Chemie International Edition 57/22	2019-04-18
2017	Samantha Lau, Bryan Ward, Xueer Zhou, Andrew J. P. White, Ian J. Casely, Stuart A. Macgregor, Mark R. Crimmin Mild sp 2 Carbonâ€“Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory published pages: 3654-3663, ISSN: 0276-7333, DOI: 10.1021/acs.organomet.7b00632	Organometallics 36/18	2019-04-17

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The information about "FLUOROFIX" are provided by the European Opendata Portal: CORDIS opendata.