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ORSETOSY

Organocatalysis at the service of total synthesis: Madangamine alkaloids

Total Cost €

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EC-Contrib. €

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Partnership

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Project "ORSETOSY" data sheet

The following table provides information about the project.

Coordinator
THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD 

Organization address
address: WELLINGTON SQUARE UNIVERSITY OFFICES
city: OXFORD
postcode: OX1 2JD
website: www.ox.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Project website http://dixon.chem.ox.ac.uk/
 Total cost 183˙454 €
 EC max contribution 183˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2014
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2015
 Duration (year-month-day) from 2015-04-27   to  2017-04-26

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD UK (OXFORD) coordinator 183˙454.00

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 Project objective

This project will develop a new, highly enantioselective, state-of-the-art synthetic route to the madangamine alkaloids B, C and E based on a novel organocatalytic desymmetrization reaction as a key step, which will allow the rapid and efficient construction of the BC rings ready for subsequent advancement to the majority of the family members. Evaluation of the anti-cancer biological activity of the different madangamines and late stage intermediates will be carried out. This Fellowship project combines total synthesis, new asymmetric methodology development via organocatalysis and biological evaluation. It has been designed to augment and complement the research and transferable skills sets of the Marie Curie fellow, and will greatly enhance his career prospects accordingly. Through the training and the research results arising, the Fellowship will be beneficial to the fellow, the host institution and European science.

 Publications

year authors and title journal last update
List of publications.
2017 Ángel L. Fuentes de Arriba, Elena Lenci, Mahendra Sonawane, Odilon Formery, Darren J. Dixon
Iridium-Catalyzed Reductive Strecker Reaction for Late-Stage Amide and Lactam Cyanation
published pages: 3655-3659, ISSN: 1433-7851, DOI: 10.1002/anie.201612367
Angewandte Chemie International Edition 56/13 2019-07-24
2016 Angel L. Fuentes de Arriba, Felix Urbitsch, Darren J. Dixon
Umpolung synthesis of branched ?-functionalized amines from imines via photocatalytic three-component reductive coupling reactions
published pages: 14434-14437, ISSN: 1359-7345, DOI: 10.1039/C6CC09172E
Chem. Commun. 52/100 2019-07-24

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