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HELIS

High energy lithium sulphur cells and batteries

Total Cost €

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EC-Contrib. €

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Partnership

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Project "HELIS" data sheet

The following table provides information about the project.

Coordinator
KEMIJSKI INSTITUT 

Organization address
address: HAJDRIHOVA 19
city: LJUBLJANA
postcode: 1000
website: http://www.ki.si

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Slovenia [SI]
 Project website http://www.helis-project.eu/
 Total cost 7˙974˙352 €
 EC max contribution 7˙974˙352 € (100%)
 Programme 1. H2020-EU.2.1.3.2. (Materials development and transformation)
 Code Call H2020-NMP-GV-2014
 Funding Scheme RIA
 Starting year 2015
 Duration (year-month-day) from 2015-06-01   to  2019-05-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    KEMIJSKI INSTITUT SI (LJUBLJANA) coordinator 1˙030˙674.00
2    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS FR (PARIS) participant 1˙056˙500.00
3    SAFT FR (LEVALLOIS PERRET) participant 888˙887.00
4    WESTFAELISCHE WILHELMS-UNIVERSITAET MUENSTER DE (MUENSTER) participant 751˙510.00
5    FUNDACIO INSTITUT DE RECERCA DE L'ENERGIA DE CATALUNYA ES (SANT ADRIA DE BESOS) participant 703˙750.00
6    FRAUNHOFER GESELLSCHAFT ZUR FOERDERUNG DER ANGEWANDTEN FORSCHUNG E.V. DE (MUNCHEN) participant 680˙625.00
7    TEL AVIV UNIVERSITY IL (TEL AVIV) participant 679˙625.00
8    CHALMERS TEKNISKA HOEGSKOLA AB SE (GOETEBORG) participant 632˙559.00
9    ACCUREC-RECYCLING GMBH DE (KREFELD) participant 597˙406.00
10    SOLVIONIC FR (TOULOUSE) participant 298˙500.00
11    PICOSUN OY FI (ESPOO) participant 235˙000.00
12    MAX-PLANCK-GESELLSCHAFT ZUR FORDERUNG DER WISSENSCHAFTEN EV DE (MUENCHEN) participant 173˙000.00
13    PSA AUTOMOBILES SA FR (POISSY) participant 128˙652.00
14    INSTITUT NATIONAL DE L ENVIRONNEMENT ET DES RISQUES INERIS FR (VERNEUIL EN HALATTE) participant 117˙662.00

Map

 Project objective

Lithium sulphur batteries (LSB) are viable candidate for commercialisation among all post Li-ion battery technologies due to their high theoretical energy density and cost effectiveness. Despites many efforts, there are remaining issues that need to be solved and this will provide final direction of LSB technological development. Some of technological aspects, like development of host matrices, interactions of host matrix with polysulphides and interactions between sulphur and electrolyte have been successfully developed within Eurolis project. Open porosity of the cathode, interactions between host matrices and polysulphides and proper solvatation of polysulphides turned to be important for complete utilisation of sulphur, however with this approach didn’t result long term cycling. Additionally we showed that effective separation between electrodes enables stable cycling with excellent coulombic efficiency. The remaining issues are mainly connected with a stability of lithium anode during cycling, with engineering of complete cell and with questions about LSB cells implementation into commercial products (ageing, safety, recycling, battery packs). Instability of lithium metal in most of conventional electrolytes and formation of dendrites due to uneven distribution of lithium upon the deposition cause several difficulties. Safety problems connected with dendrites and low coulombic efficiency with a constant increase of inner resistance due to electrolyte degradation represent main technological challenges. From this point of view, stabilisation of lithium metal will have an impact on safety issues. Stabilised interface layer is important from view of engineering of cathode composite and separator porosity since this is important parameter for electrolyte accommodation and volume expansion adjustment. Finally the mechanism of LSB ageing can determine the practical applicability of LSB in different applications.

 Deliverables

List of deliverables.
Databases from the modelling and engineering of the composite electrodes (1st generation) Documents, reports 2020-02-12 08:39:28
Databases on interfacial electrochemistry modelling Documents, reports 2020-02-12 08:39:28
Databases on electrolyte modelling Documents, reports 2020-02-12 08:39:27
Dissemination and communication plan Documents, reports 2020-02-12 08:39:27
Definition of the starting chemical environment Documents, reports 2020-02-12 08:39:27
Review of recycling processes with directions for Li-S battery recycling Documents, reports 2020-02-12 08:39:27
Web page Websites, patent fillings, videos etc. 2020-02-12 08:39:27
Modelling and design of recycling process Documents, reports 2020-02-12 08:39:27
Characterisation procedures Documents, reports 2020-02-12 08:39:27

Take a look to the deliverables list in detail:  detailed list of HELIS deliverables.

 Publications

year authors and title journal last update
List of publications.
2019 Aleksei Kolesnikov, Dong Zhou, Martin Kolek, Juan Pablo Badillo Jimenez, Peter Bieker, Martin Winter, Marian Cristian Stan
Lithium-Powder Based Electrodes Modified with ZnI 2 for Enhanced Electrochemical Performance of Lithium-Metal Batteries
published pages: A1400-A1407, ISSN: 0013-4651, DOI: 10.1149/2.0401908jes
Journal of The Electrochemical Society 166/8 2020-02-12
2018 Alen Vizintin, Ryan Guterman, Johannes Schmidt, Markus Antonietti, Robert Dominko
Linear and Cross-Linked Ionic Liquid Polymers as Binders in Lithium–Sulfur Batteries
published pages: 5444-5450, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.8b02357
Chemistry of Materials 30/15 2020-02-12
2018 Nejc Pavlin, Silvo Hribernik, Gregor Kapun, Sara Drvarič Talian, Christian Njel, Rémi Dedryvère, Robert Dominko
The Role of Cellulose Based Separator in Lithium Sulfur Batteries
published pages: A5237-A5243, ISSN: 0013-4651, DOI: 10.1149/2.0401903jes
Journal of The Electrochemical Society 166/3 2020-02-12
2018 Jernej Bobnar, Matic Lozinšek, Gregor Kapun, Christian Njel, Rémi Dedryvère, Boštjan Genorio, Robert Dominko
Fluorinated reduced graphene oxide as a protective layer on the metallic lithium for application in the high energy batteries
published pages: , ISSN: 2045-2322, DOI: 10.1038/s41598-018-23991-2
Scientific Reports 8/1 2020-02-12
2019 Tzach Mukra, Yonatan Horowitz, Inna Shekhtman, Meital Goor, Sara Drvarič Talian, Larisa Burstein, Johannes Kasnatscheew, Paul Meister, Mariano Grünebaum, Martin Winter, Hans-Dieter Wiemhöfer, Diana Golodnitsky, Emanuel Peled
Disiloxane with nitrile end groups as Co-solvent for electrolytes in lithium sulfur batteries – A feasible approach to replace LiNO3
published pages: , ISSN: 0013-4686, DOI: 10.1016/j.electacta.2019.03.144
Electrochimica Acta 2020-02-12
2016 Vigneshwaran Thangavel, Kan-Hao Xue, Youcef Mammeri, Matias Quiroga, Afef Mastouri, Claude Guéry, Patrik Johansson, Mathieu Morcrette, Alejandro A. Franco
A Microstructurally Resolved Model for Li-S Batteries Assessing the Impact of the Cathode Design on the Discharge Performance
published pages: A2817-A2829, ISSN: 0013-4651, DOI: 10.1149/2.0051614jes
Journal of The Electrochemical Society 163/13 2020-02-12
2019 Deidre Wolff, Lluc Canals Casals, Gabriela Benveniste, Cristina Corchero, Lluís Trilla
The Effects of Lithium Sulfur Battery Ageing on Second-Life Possibilities and Environmental Life Cycle Assessment Studies
published pages: 2440, ISSN: 1996-1073, DOI: 10.3390/en12122440
Energies 12/12 2020-02-12

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