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3MC SIGNED

3D Model Catalysts to explore new routes to sustainable fuels

Total Cost €

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EC-Contrib. €

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Partnership

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 3MC project word cloud

Explore the words cloud of the 3MC project. It provides you a very rough idea of what is the project "3MC" about.

morphology    dioxide    reaction    overcome    desired    3d    mimic    cu    monoxide    actitivity    products    atoms    chemical    spatial    components    closely    unprecedented    mechanisms    realistic    copper    depends    nature    of    composition    mesoporous    plastics    tool    fundamental    catalytic    nanoalloys    promoters    convert    bimetallic    sustainable    renewable    water    oxygenates    hampers    tune    conditions    critical    interface    individual    materials    manufactured    assembled    hydrogen    industrially    composite    heterogeneity    size    fuels    variation    critically    molecules    electronic    catalyst    formed    currently    surface    ordered    trial    oxygen    biomass    model    instance    rational    small    selectivity    metal    structural    chemicals    silica    questions    catalysts    solar    oil    carbon    influence    predominantly    promoted    characterization    containing    transition    error    time    structure    resolution    active    ones    precision    drugs    nanoparticles    combination    sites   

Project "3MC" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITEIT UTRECHT 

Organization address
address: HEIDELBERGLAAN 8
city: UTRECHT
postcode: 3584 CS
website: www.uu.nl

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Netherlands [NL]
 Total cost 1˙999˙625 €
 EC max contribution 1˙999˙625 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2014-CoG
 Funding Scheme ERC-COG
 Starting year 2015
 Duration (year-month-day) from 2015-09-01   to  2020-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITEIT UTRECHT NL (UTRECHT) coordinator 1˙999˙625.00

Map

 Project objective

Currently fuels, plastics, and drugs are predominantly manufactured from oil. A transition towards renewable resources critically depends on new catalysts, for instance to convert small molecules (such as solar or biomass derived hydrogen, carbon monoxide, water and carbon dioxide) into more complex ones (such as oxygenates, containing oxygen atoms in their structure). Catalyst development now often depends on trial and error rather than rational design, as the heterogeneity of these composite systems hampers detailed understanding of the role of each of the components.

I propose 3D model catalysts as a novel enabling tool to overcome this problem. Their well-defined nature allows unprecedented precision in the variation of structural parameters (morphology, spatial distribution) of the individual components, while at the same time they mimic real catalysts closely enough to allow testing under industrially relevant conditions. Using this approach I will address fundamental questions, such as: * What are the mechanisms (structural, electronic, chemical) by which non-metal promoters influence the functionality of copper-based catalysts? * Which nanoalloys can be formed, how does their composition influence the surface active sites and catalytic functionality under reaction conditions? * Which size and interface effects occur, and how can we use them to tune the actitivity and selectivity towards desired products?

Our 3D model catalysts will be assembled from ordered mesoporous silica and carbon support materials and Cu-based promoted and bimetallic nanoparticles. The combination with high resolution characterization and testing under realistic conditions allows detailed insight into the role of the different components; critical for the rational design of novel catalysts for a future more sustainable production of chemicals and fuels from renewable resources.

 Publications

year authors and title journal last update
List of publications.
2018 C.E. Pompe, M. Slagter, P.E. de Jongh, K.P. de Jongh
Impact of heterogeneities in silica-supported copper catalysts on their stability for methanol synthesis
published pages: 1-9, ISSN: 0021-9517, DOI: 10.1016/j.cat.2018.06.14
journal of catalysis 365 2019-06-07
2018 Jessi E. S. van der Hoeven, Tom A. J. Welling, Tiago A. G. Silva, Jeroen E. van den Reijen, Camille La Fontaine, Xavier Carrier, Catherine Louis, Alfons van Blaaderen, Petra E. de Jongh
In Situ Observation of Atomic Redistribution in Alloying Gold–Silver Nanorods
published pages: 8467-8476, ISSN: 1936-0851, DOI: 10.1021/acsnano.8b03978
ACS Nano 12/8 2019-04-18

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The information about "3MC" are provided by the European Opendata Portal: CORDIS opendata.

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