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NONNH

Mechanism of hydrogenation and transfer hydrogenation of polar unsaturations catalyzed by non N-H systems

Total Cost €

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EC-Contrib. €

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Partnership

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Project "NONNH" data sheet

The following table provides information about the project.

Coordinator
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS 

Organization address
address: RUE MICHEL ANGE 3
city: PARIS
postcode: 75794
website: www.cnrs.fr

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country France [FR]
 Project website https://rinaldo-poli.jimdo.com/funding/nonnh/
 Total cost 185˙076 €
 EC max contribution 185˙076 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2014
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2015
 Duration (year-month-day) from 2015-07-12   to  2017-07-11

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS FR (PARIS) coordinator 185˙076.00

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 Project objective

The project addresses the reduction of polar unsaturations catalyzed by metal complexes under strongly basic conditions. This is an important reaction that enters the manufacture of many high added value fine chemicals. The role of the strong base for catalysts that do not contain active protons in the ligand donor functions is unclear, as well as the relationship between the mechanisms of hydrogenation by H2 and transfer hydrogenation. The sought mechanistic understanding can lead to the design of improved catalysts and operating conditions. The project will be implemented by a multifaceted approach that includes synthesis, characterization, catalysis, kinetics, and computations and be further enriched by parahydrogen NMR studies through a 3-month secondment at the University of York. This multisectorial training will put the ER on an excellent basis to further develop his professional career in research. The ER has an excellent basic training from one of the premier institutions in his Country and an outstanding publication record. The ER will be expected to mentor undergraduate students in the group, to deliver 4 presentations at group meetings, to present his results in at least one international conference and to contribute to drafting research publications. The project is expected to lead to high impact fundamental knowledge resulting in high quality publications, presentations at international conferences, and popularized articles in University magazines.

 Publications

year authors and title journal last update
List of publications.
2017 S.M. Wahidur Rahaman, Jean-Claude Daran, Eric Manoury, Rinaldo Poli
The cyclooctadiene ligand in [IrCl(COD)]2 is hydrogenated under transfer hydrogenation conditions: A study in the presence of PPh3 and a strong base in isopropanol
published pages: 14-21, ISSN: 0022-328X, DOI: 10.1016/j.jorganchem.2016.10.009
Journal of Organometallic Chemistry 829 2019-07-23
2017 Ekaterina M. Titova, S.M. Wahidur Rahaman, Elena S. Shubina, Rinaldo Poli, Natalia V. Belkova, Eric Manoury
Catalytic redox isomerization of allylic alcohols with rhodium and iridium complexes with ferrocene phosphine-thioether ligands
published pages: 376-380, ISSN: 1381-1169, DOI: 10.1016/j.molcata.2016.08.014
Journal of Molecular Catalysis A: Chemical 426 2019-07-23

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The information about "NONNH" are provided by the European Opendata Portal: CORDIS opendata.

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