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NanoINCAGE

Luminescent Nanocrystals in a Cage for Solar-to-Fuel Conversion

Total Cost €

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EC-Contrib. €

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Partnership

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 NanoINCAGE project word cloud

Explore the words cloud of the NanoINCAGE project. It provides you a very rough idea of what is the project "NanoINCAGE" about.

fabrication    photosynthesis    composition    deriving    tremendously    absorber    extremely    simplified    catalysis    dependent    length    light    absorption    organic    intrinsic    full    directionally    electrolyte    scenario    cqd    multifunctional    gap    absorbing    artificial    lack    leaf    cqds    cage    realize    sites    inspired    tunability    metal    consisting    separate    despite    basic    scales    questions    contact    materials    solar    challenged    multiple    harvested    carrier    progress    funnelled    band    earlier    harvesting    irradiation    scientific    supervisor    voltages    framework    rster    scheme    beneficial    combining    device    appealing    renewable    schemes    successful    located    ouml    huge    skills    advantages    interdisciplinary    antenna    science    oxygen    outcome    size    hybrid    quantum    biologically    unprecedented    engineering    introduction    colloidal    pigments    nanoincage    chemistry    multidisciplinary    catalyst    spectrum    natural    architectures    transfer    clean    mof    hydrogen    synthetic    dots    gained    energy   

Project "NanoINCAGE" data sheet

The following table provides information about the project.

Coordinator
ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE 

Organization address
address: BATIMENT CE 3316 STATION 1
city: LAUSANNE
postcode: 1015
website: www.epfl.ch

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Switzerland [CH]
 Project website https://lnce.epfl.ch/buonsanti/
 Total cost 175˙419 €
 EC max contribution 175˙419 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-RI
 Starting year 2016
 Duration (year-month-day) from 2016-09-01   to  2018-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE CH (LAUSANNE) coordinator 175˙419.00

Map

 Project objective

Artificial photosynthesis, which can produce hydrogen and oxygen from solar irradiation, is one of the possible means to provide clean and renewable energy. Despite the recent progress, this emerging field is challenged by huge technical and scientific questions. In natural photosynthesis light absorption and catalysis occur in different sites of the leaf. In a simplified scenario, the energy harvested by the light absorbing pigments is funnelled towards the oxygen evolving complex. Here, we propose to realize the same biologically-inspired scheme using a novel hybrid system consisting of colloidal quantum dots embedded in a metal organic framework cage (CQD@MOF). In particular, a CQD Förster-transfer based light harvesting antenna will directionally transfer energy to a catalyst located in separate sites of the device. In addition to the rich basic science opportunities behind the introduction of this new concept in artificial photosynthesis, full-solar spectrum harvesting deriving from the characteristic size-dependent band gap tunability of CQDs, the potential for high voltages by combining CQDs of different size and composition, and the lack of contact between the light absorber and the electrolyte, intrinsic to the proposed device architectures, are all advantages that make this CQD@MOF hybrid Förster-based scheme highly appealing. One of the key component of the research will be to develop synthetic schemes to access these multifunctional systems with an unprecedented level of control through multiple length-scales. The experience and the skills gained by the applicant during her earlier carrier in the device fabrication together with the long-standing experience of the supervisor in this field will be extremely beneficial for a successful outcome of the proposal.NanoINCAGE is highly multidisciplinary and interdisciplinary program and its successful outcome will tremendously impact several other research fields in chemistry, materials science and engineering.

 Publications

year authors and title journal last update
List of publications.
2017 Anna Loiudice, Seryio Saris, Emad Oveisi, Duncan T. L. Alexander, Raffaella Buonsanti
CsPbBr 3 QD/AlO x Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat
published pages: 10696-10701, ISSN: 1433-7851, DOI: 10.1002/anie.201703703
Angewandte Chemie International Edition 56/36 2019-04-18

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