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OLE-DIOX

Catalytic reductive carboxylation of unactivated olefins with carbon dioxide

Total Cost €

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EC-Contrib. €

0

Partnership

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Project "OLE-DIOX" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 149˙500 €
 EC max contribution 149˙500 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2015-PoC
 Funding Scheme ERC-POC
 Starting year 2016
 Duration (year-month-day) from 2016-06-01   to  2017-11-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 149˙500.00

Map

 Project objective

Carboxylic acids are building blocks of utmost importance in our chemical industry, as these motifs are extensively used in the manufacture of soaps, detergents, pharmaceuticals, rubber, plastics, dyes, textile, perfumes, and animal feed, among many others. Current industrial protocols for their synthesis rely heavily on toxic reagents, lengthy-step pathways or waste-producing procedures such as hydrolysis of nitriles or two-step techniques based on hydroformylation of olefins with highly toxic carbon monoxide with expensive noble catalysts (Rh) followed by oxidation. Unlike hydroformylation methods, OLE-DIOX offers the opportunity of promoting a carboxylation event using unactivated olefins, products produced in bulk from petroleum processing, with abundant carbon dioxide as C1 source. The protocol is user-friendly, with components that are neither air- nor moisture sensitive, utilizes earth-abundant catalysts and operates under mild conditions. OLE-DIOX represents an important contribution for our circular economy by effectively recycling bulk materials into valuable products in one-step operation. These unique features makes OLE-DIOX technically and economically viable for its implementation at large-scale en route to industrially-valuable carboxylic acids, thus avoiding lengthy and waste-producing protocols in the established oil-to-carboxylic acid process chain.

 Publications

year authors and title journal last update
List of publications.
2017 Morgane Gaydou, Toni Moragas, Francisco Juliá-Hernández, Ruben Martin
Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO 2 and Water
published pages: 12161-12164, ISSN: 0002-7863, DOI: 10.1021/jacs.7b07637
Journal of the American Chemical Society 139/35 2019-06-13
2017 Francisco Juliá-Hernández, Toni Moragas, Josep Cornella, Ruben Martin
Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide
published pages: 84-88, ISSN: 0028-0836, DOI: 10.1038/nature22316
Nature 545/7652 2019-06-13

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