Explore the words cloud of the Tuning COPs project. It provides you a very rough idea of what is the project "Tuning COPs" about.
The following table provides information about the project.
AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS
|Coordinator Country||Spain [ES]|
|Total cost||170˙121 €|
|EC max contribution||170˙121 € (100%)|
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
|Duration (year-month-day)||from 2017-10-01 to 2019-10-15|
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|1||AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS||ES (MADRID)||coordinator||170˙121.00|
The main goal of this proposed project is the synthesis of new hybrid π-conjugated polymers for industrial use, which conductive and optical properties could be fine tuneable by the proper anionic metallacarboranes as doping agents. To achieve our goals two directions were chosen. In the first part we would like to investigate the effect of different boron clusters ([Co(C2B9HnX11-n)2]- X=Cl, Br, I) as doping agents on the conductive and photoluminescence properties of the poly(3,4-ethylenedioxythiophene) (PEDOT). Preliminary results suggest that the earlier used [Co(C2B9H11)2]- doping anion is redoxactive, thus it has a big influence on the formation and the properties of the polymer. Our expectation is that the halogen analogues ([Co(C2B9HnX11-n)2]-=Cl, Br, I) cover a wide range of redoxpotential, thus we can easily modify the properties of the new materials. During the second part we would like to tune both the conductive and photoluminescence properties of the poly(p-phenylene vinylene) (PPV). For this purpose different co-polymer planed to synthetized, which containing different amount of non-doped and self-doped monomer units. (In case of the self-doped polymer the doping anion is covalently linked to the monomer unit). We expect that the ratio of the non-doped and the self-doped has a strong influence both the conductive and photoluminescent properties, moreover the two different properties will be altered by the inclusion of functional side groups.
|year||authors and title||journal||last update|
Zsolt Kelemen, Ariadna Pepiol, Marius Lupu, Reijo SillanpÃ¤Ã¤, Mikko M. HÃ¤nninen, Francesc Teixidor, Clara ViÃ±as
Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of Câ€“C and its antipodal Bâ€“B
published pages: 8927-8930, ISSN: 1359-7345, DOI: 10.1039/c9cc04526k
|Chemical Communications 55/61||2020-04-09|
Francesc Teixidor, Isabel Fuentes, MarÃa JosÃ© Mostazo-LÃ³pez, Zsolt Kelemen, Vicente CompaÃ±, Andreu Andrio, Emilia MorallÃ³n, Diego Cazorla-AmorÃ³s, Clara ViÃ±as
Are the Doping Anion Company Cations Influential in the Conducting Organic Polymers? The Case of the Popular PEDOT
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201902708
|Chemistry â€“ A European Journal||2020-04-09|
Mahdi Chaari, Zsolt Kelemen, JosÃ© Giner Planas, Francesc Teixidor, Duane Choquesillo-Lazarte, Abdelhamid Ben Salah, Clara ViÃ±as, Rosario NÃºÃ±ez
Photoluminescence in m -carboraneâ€“anthracene triads: a combined experimental and computational study
published pages: 11336-11347, ISSN: 2050-7534, DOI: 10.1039/c8tc03741h
|Journal of Materials Chemistry C 6/42||2020-04-09|
Mahdi Chaari, Zsolt Kelemen, Duane Choquesillo-Lazarte, Nerea Gaztelumendi, Francesc Teixidor, Clara Vinas, Carme Nogues, Rosario Nunez
Efficient blue light emitting materials based on m-carborane-anthracene dyads. Structure, photophysics and bioimaging studies.
published pages: , ISSN: 2047-4830, DOI: 10.1039/c9bm00903e
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