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Tuning COPs SIGNED

Tuning both the photoluminescence and conductive properties of new COP materials

Total Cost €

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EC-Contrib. €

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Partnership

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Project "Tuning COPs" data sheet

The following table provides information about the project.

Coordinator
AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS 

Organization address
address: CALLE SERRANO 117
city: MADRID
postcode: 28006
website: http://www.csic.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Project website https://departments.icmab.es/lmi/dr-zsolt-kelemen/
 Total cost 170˙121 €
 EC max contribution 170˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-10-01   to  2019-10-15

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS ES (MADRID) coordinator 170˙121.00

Map

 Project objective

The main goal of this proposed project is the synthesis of new hybrid π-conjugated polymers for industrial use, which conductive and optical properties could be fine tuneable by the proper anionic metallacarboranes as doping agents. To achieve our goals two directions were chosen. In the first part we would like to investigate the effect of different boron clusters ([Co(C2B9HnX11-n)2]- X=Cl, Br, I) as doping agents on the conductive and photoluminescence properties of the poly(3,4-ethylenedioxythiophene) (PEDOT). Preliminary results suggest that the earlier used [Co(C2B9H11)2]- doping anion is redoxactive, thus it has a big influence on the formation and the properties of the polymer. Our expectation is that the halogen analogues ([Co(C2B9HnX11-n)2]-=Cl, Br, I) cover a wide range of redoxpotential, thus we can easily modify the properties of the new materials. During the second part we would like to tune both the conductive and photoluminescence properties of the poly(p-phenylene vinylene) (PPV). For this purpose different co-polymer planed to synthetized, which containing different amount of non-doped and self-doped monomer units. (In case of the self-doped polymer the doping anion is covalently linked to the monomer unit). We expect that the ratio of the non-doped and the self-doped has a strong influence both the conductive and photoluminescent properties, moreover the two different properties will be altered by the inclusion of functional side groups.

 Publications

year authors and title journal last update
List of publications.
2019 Zsolt Kelemen, Ariadna Pepiol, Marius Lupu, Reijo Sillanpää, Mikko M. Hänninen, Francesc Teixidor, Clara Viñas
Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C–C and its antipodal B–B
published pages: 8927-8930, ISSN: 1359-7345, DOI: 10.1039/c9cc04526k
Chemical Communications 55/61 2020-04-09
2019 Francesc Teixidor, Isabel Fuentes, María José Mostazo-López, Zsolt Kelemen, Vicente Compañ, Andreu Andrio, Emilia Morallón, Diego Cazorla-Amorós, Clara Viñas
Are the Doping Anion Company Cations Influential in the Conducting Organic Polymers? The Case of the Popular PEDOT
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201902708
Chemistry – A European Journal 2020-04-09
2018 Mahdi Chaari, Zsolt Kelemen, José Giner Planas, Francesc Teixidor, Duane Choquesillo-Lazarte, Abdelhamid Ben Salah, Clara Viñas, Rosario Núñez
Photoluminescence in m -carborane–anthracene triads: a combined experimental and computational study
published pages: 11336-11347, ISSN: 2050-7534, DOI: 10.1039/c8tc03741h
Journal of Materials Chemistry C 6/42 2020-04-09
2019 Mahdi Chaari, Zsolt Kelemen, Duane Choquesillo-Lazarte, Nerea Gaztelumendi, Francesc Teixidor, Clara Vinas, Carme Nogues, Rosario Nunez
Efficient blue light emitting materials based on m-carborane-anthracene dyads. Structure, photophysics and bioimaging studies.
published pages: , ISSN: 2047-4830, DOI: 10.1039/c9bm00903e
Biomaterials Science 2020-04-09

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