Opendata, web and dolomites

POLY-WITTIG

Tuning mechanical properties of elastomers with stereocontrolled π-bonds using Wittig chemistry

Total Cost €

0

EC-Contrib. €

0

Partnership

0

Views

0

Project "POLY-WITTIG" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF BIRMINGHAM 

Organization address
address: Edgbaston
city: BIRMINGHAM
postcode: B15 2TT
website: www.bham.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Project website https://www.dovegrouplab.com/research/stereochemistry/
 Total cost 195˙454 €
 EC max contribution 195˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-06-26   to  2019-06-25

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF BIRMINGHAM UK (BIRMINGHAM) coordinator 120˙801.00
2    THE UNIVERSITY OF WARWICK UK (COVENTRY) participant 74˙653.00

Map

 Project objective

Elastomer materials (or rubbers) are hugely important and widely used as a result of their ability to be deformed yet return to their original size and shape upon removal of stress. Owing to these properties and their wide-ranging applicability, a significant body of research has been, and continues to be directed towards the discovery of new materials with specific properties for a wide array of application areas. The properties of elastomers are dependent on a number of factors such as chain length, topology, tacticity, pendant functionality, or cross-linking density. Specifically, the mechanical characteristics of natural elastomers, e.g., those based on polyisoprene, are known to be highly dependent upon the stereochemistry of the double bond in the isoprene unit. However, this concept is seldom exploited to modulate properties of synthetic elastomers despite the potential clear advantages to create materials in which the control over their mechanical properties can be decoupled from their functionality. This is primarily a consequence of the inherent challenges associated with metal-catalyzed stereocontrolled polymerisations. The POLY-WITTIG project proposes to utilize the highly practical Wittig reaction to modulate the stereochemistry of the π-bond in the elastomer backbone to inturn allow the modulation of materials properties to be controlled. Additionally, heteroatom-modified Wittig variants will be used to synthesize and analyze mechanical properties of elastomers with heteroatom–carbon π-bonds (e.g., N=C or P=C). Thus, the versatility of Wittig chemistry will provide the unprecedented opportunity to systematically study a library of isolobally substituted elastomers.

 Publications

year authors and title journal last update
List of publications.
2019 Joshua C. Worch, Hannah Prydderch, Sètuhn Jimaja, Panagiotis Bexis, Matthew L. Becker, Andrew P. Dove
Stereochemical enhancement of polymer properties
published pages: 514-535, ISSN: 2397-3358, DOI: 10.1038/s41570-019-0117-z
Nature Reviews Chemistry 3/9 2020-01-29

Are you the coordinator (or a participant) of this project? Plaese send me more information about the "POLY-WITTIG" project.

For instance: the website url (it has not provided by EU-opendata yet), the logo, a more detailed description of the project (in plain text as a rtf file or a word file), some pictures (as picture files, not embedded into any word file), twitter account, linkedin page, etc.

Send me an  email (fabio@fabiodisconzi.com) and I put them in your project's page as son as possible.

Thanks. And then put a link of this page into your project's website.

The information about "POLY-WITTIG" are provided by the European Opendata Portal: CORDIS opendata.

More projects from the same programme (H2020-EU.1.3.2.)

POMOC (2019)

Charles IV and the power of marvellous objects

Read More  

IPG_CORE (2019)

Looking for the Impersonal Core -- Impersonal Pronouns across Germanic languages

Read More  

NaWaTL (2020)

Narrative, Writing, and the Teotihuacan Language: Exploring Language History Through Phylogenetics, Epigraphy and Iconography

Read More