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ElectroNick SIGNED

The Combination of Electrochemistry and Nickel Catalysis: New Bond-Forming Reactions on a Sustainable Platform

Total Cost €

0

EC-Contrib. €

0

Partnership

0

Views

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 ElectroNick project word cloud

Explore the words cloud of the ElectroNick project. It provides you a very rough idea of what is the project "ElectroNick" about.

carbon    nickel    intermediates    synthetic    generate    sustainable    reactions    cross    catalysis    reactive    bonds    coupling    combination    sp3    electrochemistry   

Project "ElectroNick" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 239˙191 €
 EC max contribution 239˙191 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme /MSCA-IF-GF
 Starting year 2018
 Duration (year-month-day) from 2018-05-01   to  2021-04-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 239˙191.00
2    UNIVERSITY OF UTAH US (SALT LAKE CITY UTAH) partner 0.00

Mappa

 Project objective

Sustainable routes towards the formation of key synthetic carbon–carbon bonds by cross-coupling remains a challenge in organic chemistry. Realization of this goal will enable the combination of simple building blocks to rapidly assimilate synthetic complexity with only a minimum level of stoichiometric waste. Electrochemistry provides a new platform to conduct reactions through in situ generation of reactive intermediates under mild conditions, with broad applications to industrial synthesis. Herein, we seek to combine the fields of electrochemistry and cross-coupling reactions, using an electric current to catalytically generate alkylzinc reagents and reactive alkyl radicals. These intermediates will then undergo coupling, facilitated by nickel catalysis, to generate key carbon–carbon bonds, including challenging C(sp3)–C(sp3) bonds. Furthermore, the powerful combination of electrochemistry and nickel catalysis will enable the simplest feedstock chemicals – alkanes – to be utilized for the first time in cross-coupling through a nickel chain-walking process, providing facile access to fatty acids and alternative coupled products. These projects will enable the emergence of new reaction strategies for exploitation in a sustainable manner. Additionally, this ambitious and innovative proposal will succeed through considerable two-way transfer of knowledge between the participating organizations and the ER, developing the fellow into a leading international researcher.

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The information about "ELECTRONICK" are provided by the European Opendata Portal: CORDIS opendata.

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