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CUBE SIGNED

Unravelling the secrets of Cu-based catalysts for C-H activation

Total Cost €

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EC-Contrib. €

0

Partnership

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 CUBE project word cloud

Explore the words cloud of the CUBE project. It provides you a very rough idea of what is the project "CUBE" about.

pursued    capitalize    conceived    frameworks    players    complementary    gap    rationally    scarce    interface    plan    center    heterogeneous    selective    engineering    o2    evolve    catalysts    n2o    bridge    cu    abundant    biological    vigorously    mofs    zeolites    protein    fertilization    catalyst    elucidate    catalysis    catalytic    activation    activate    generate    cross    flexibility    h2o2    discovery    progress    containing    trans    hybrid    grail    homogeneous    synthetic    organic    insights    maximize    activating    designed    synthesis    brings    metal    uio    engineered    unprecedented    nmbu    investigations    acquired    synergistically    spectroscopy    mpi    mechanistic    polymer    mono    principles    selectivity    uot    team    enzymology    cube    secrets    accessible    bonds    chemistry    materials    harness    translating    turn    spectroscopic    natural    lpmos    efforts    oxidant    holy    disclosing    enzyme    resilient    disciplinary    experimentally    enzymes    computational    tomorrow    zr   

Project "CUBE" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITETET I OSLO 

Organization address
address: PROBLEMVEIEN 5-7
city: OSLO
postcode: 313
website: www.uio.no

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Norway [NO]
 Total cost 9˙885˙989 €
 EC max contribution 9˙885˙988 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2019-SyG
 Funding Scheme ERC-SyG
 Starting year 2020
 Duration (year-month-day) from 2020-04-01   to  2026-03-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITETET I OSLO NO (OSLO) coordinator 2˙906˙039.00
2    NORGES MILJO-OG BIOVITENSKAPLIGE UNIVERSITET NO (AS) participant 2˙796˙408.00
3    MAX-PLANCK-GESELLSCHAFT ZUR FORDERUNG DER WISSENSCHAFTEN EV DE (MUENCHEN) participant 2˙103˙750.00
4    UNIVERSITA DEGLI STUDI DI TORINO IT (TORINO) participant 2˙079˙791.00

Map

 Project objective

The Holy Grail of selective C-H activation has been vigorously pursued for more than 70 years in all areas of catalysis - homogeneous, heterogeneous and biological - yet with scarce cross-fertilization. CUBE will bridge this gap, by synergistically disclosing the secrets of Cu-containing biological and synthetic catalysts and translating the acquired knowledge into rationally designed new catalysts with unprecedented activity, selectivity and turn-over numbers. CUBE will capitalize on the recent discovery of abundant and experimentally accessible natural enzymes (LPMOs) that activate resilient C-H bonds using a mono-Cu catalytic center, thus providing a biological analogue to synthetic Cu-zeolites. CUBE will also harness the potential of metal-organic frameworks (MOFs), which offer unprecedented (“enzyme-like”) flexibility in catalyst development. C-H activating Cu-containing Zr-MOFs have just been described. CUBE will generate trans-disciplinary insights into Cu-based catalysts to progress beyond the state of the art in C-H activation. To this aim, we will elucidate the key mechanistic features of oxidant activation by O2, as well as N2O and H2O2, and then C-H activation. Emerging design principles from these studies will evolve new catalysts, including engineered enzymes, enzyme-polymer hybrid materials, and MOFs. To enable these efforts, we will develop novel methodologies at the interface of spectroscopy and computational chemistry. The project brings together leading players in complementary fields: design, synthesis and testing of catalysts (UiO), enzymology and protein engineering (NMBU), spectroscopic investigations of heterogeneous catalysts (UoT) and spectroscopic/computational studies of homogeneous and biological catalysts (MPI). Through a work-plan conceived to maximize cross-fertilization within the project team, we will design and develop novel catalysts for tomorrow’s C-H activation chemistry.

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The information about "CUBE" are provided by the European Opendata Portal: CORDIS opendata.

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