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CUBE SIGNED

Unravelling the secrets of Cu-based catalysts for C-H activation

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 CUBE project word cloud

Explore the words cloud of the CUBE project. It provides you a very rough idea of what is the project "CUBE" about.

cu    abundant    elucidate    plan    zr    scarce    activate    synergistically    biological    spectroscopy    principles    accessible    catalyst    zeolites    harness    selective    mechanistic    polymer    bonds    turn    nmbu    tomorrow    disclosing    efforts    catalysts    o2    computational    organic    n2o    bridge    players    materials    resilient    homogeneous    selectivity    unprecedented    engineering    catalysis    activating    translating    center    maximize    generate    progress    rationally    uio    trans    engineered    metal    protein    catalytic    holy    vigorously    frameworks    pursued    designed    insights    investigations    synthesis    evolve    chemistry    capitalize    conceived    team    gap    flexibility    hybrid    enzymology    mofs    mono    enzymes    containing    secrets    spectroscopic    activation    experimentally    uot    cross    natural    grail    discovery    heterogeneous    lpmos    brings    enzyme    disciplinary    cube    h2o2    complementary    oxidant    fertilization    acquired    interface    mpi    synthetic   

Project "CUBE" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITETET I OSLO 

Organization address
address: PROBLEMVEIEN 5-7
city: OSLO
postcode: 313
website: www.uio.no

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Norway [NO]
 Total cost 9˙885˙989 €
 EC max contribution 9˙885˙988 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2019-SyG
 Funding Scheme ERC-SyG
 Starting year 2020
 Duration (year-month-day) from 2020-04-01   to  2026-03-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITETET I OSLO NO (OSLO) coordinator 2˙906˙039.00
2    NORGES MILJO-OG BIOVITENSKAPLIGE UNIVERSITET NO (AS) participant 2˙796˙408.00
3    MAX-PLANCK-GESELLSCHAFT ZUR FORDERUNG DER WISSENSCHAFTEN EV DE (MUENCHEN) participant 2˙103˙750.00
4    UNIVERSITA DEGLI STUDI DI TORINO IT (TORINO) participant 2˙079˙791.00

Map

 Project objective

The Holy Grail of selective C-H activation has been vigorously pursued for more than 70 years in all areas of catalysis - homogeneous, heterogeneous and biological - yet with scarce cross-fertilization. CUBE will bridge this gap, by synergistically disclosing the secrets of Cu-containing biological and synthetic catalysts and translating the acquired knowledge into rationally designed new catalysts with unprecedented activity, selectivity and turn-over numbers. CUBE will capitalize on the recent discovery of abundant and experimentally accessible natural enzymes (LPMOs) that activate resilient C-H bonds using a mono-Cu catalytic center, thus providing a biological analogue to synthetic Cu-zeolites. CUBE will also harness the potential of metal-organic frameworks (MOFs), which offer unprecedented (“enzyme-like”) flexibility in catalyst development. C-H activating Cu-containing Zr-MOFs have just been described. CUBE will generate trans-disciplinary insights into Cu-based catalysts to progress beyond the state of the art in C-H activation. To this aim, we will elucidate the key mechanistic features of oxidant activation by O2, as well as N2O and H2O2, and then C-H activation. Emerging design principles from these studies will evolve new catalysts, including engineered enzymes, enzyme-polymer hybrid materials, and MOFs. To enable these efforts, we will develop novel methodologies at the interface of spectroscopy and computational chemistry. The project brings together leading players in complementary fields: design, synthesis and testing of catalysts (UiO), enzymology and protein engineering (NMBU), spectroscopic investigations of heterogeneous catalysts (UoT) and spectroscopic/computational studies of homogeneous and biological catalysts (MPI). Through a work-plan conceived to maximize cross-fertilization within the project team, we will design and develop novel catalysts for tomorrow’s C-H activation chemistry.

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The information about "CUBE" are provided by the European Opendata Portal: CORDIS opendata.

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