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PhenAnOx SIGNED

New Chemical Synthetic Methods for Reacting Phenols Selectively with Different Molecules and With Itself: Use of Electricity as a Sustainable, Economic and Traceless Reagent.

Total Cost €

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EC-Contrib. €

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Partnership

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 PhenAnOx project word cloud

Explore the words cloud of the PhenAnOx project. It provides you a very rough idea of what is the project "PhenAnOx" about.

electron    intermediates    cheap    forces    ease    18    sustainable    first    syntheses    substrates    grids    coupling    chemistry    ways    replace    reactivity    gutenberg    benzoxazoles    action    packages    certain    oxidizers    active    time    extend    cross    agents    organic    electrical    economic    manner    made    humans    inventing    additional    industrial    obtain    sole    diarylethers    currents    ecologic    functionalization    reduce    chemical    siegfried    professor    structures    worldwide    johannes    electrons    selective    bonds    efforts    implementable    electric    contributions    university    phenol    laboratory    reactions    inexpensive    concentrate    building    tolerated    electrochemistry    conversion    holes    mainz    heteroatom    stabilize    electro    performing    easily    later    he    compounds    blocks    earth    fluctuating    waste    synthesis    chemist    waldvogel    analogues    form    electrosynthesis    expense    core    natural    phenols    interestingly    synthetic    green    biologically    reducing    seminal    driving    substances    amount    switched    group    dibenzofurans    off    divided    wll   

Project "PhenAnOx" data sheet

The following table provides information about the project.

Coordinator
JOHANNES GUTENBERG-UNIVERSITAT MAINZ 

Organization address
address: SAARSTRASSE 21
city: MAINZ
postcode: 55122
website: www.uni-mainz.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 162˙806 €
 EC max contribution 162˙806 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2018
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2020
 Duration (year-month-day) from 2020-03-01   to  2022-02-28

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    JOHANNES GUTENBERG-UNIVERSITAT MAINZ DE (MAINZ) coordinator 162˙806.00

Map

 Project objective

Inventing new green and inexpensive synthetic methods for relevant chemical compounds is one of the ways how organic chemist can contribute to the well-being of humans and Earth. One of the most promising chemical method for this is synthetic organic electrochemistry. It can replace chemical reducing agents and oxidizers with sole cheap electrons or electron-holes and, at the same time, reduce both the amount of waste and the expense of chemical synthesis. Syntheses are easily controllable as they can be ‘switched-off’ and they are implementable on a large industrial scale with ease. Interestingly, organic electrosynthesis can be used to stabilize electrical grids as fluctuating electric currents are tolerated in certain reactions.

The aim of this project is to develop new sustainable, selective and economic electro-organic synthetic methods for the functionalization of phenols. Particularly, we will concentrate on our efforts for finding new ways to form C-heteroatom bonds between phenols and different substrates. At first, we will study the conversion of phenols to diarylethers and dibenzofurans that are important building blocks and core structures of natural products and biologically active substances. Later, we will try to extend the reactivity for phenol-analogues as wll. On the next step, we will study the cross-coupling between phenols and benzoxazoles and its analogues. In this way, we also obtain important synthetic intermediates for organic chemistry in a sustainable and ecologic manner. The proposed action is divided in two research and three additional work packages.

The project will be implemented at the Institute of Organic Chemistry of Johannes-Gutenberg-University in Mainz in the research group of Professor Siegfried Waldvogel. He has been one of the driving forces of electro-organic synthesis already for 18 years and made seminal contributions during that time. It is therefore the top laboratory worldwide for performing the proposed action.

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The information about "PHENANOX" are provided by the European Opendata Portal: CORDIS opendata.

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