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MOLMAG

New Spin for Molecular Magnets

Total Cost €

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EC-Contrib. €

0

Partnership

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 MOLMAG project word cloud

Explore the words cloud of the MOLMAG project. It provides you a very rough idea of what is the project "MOLMAG" about.

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Project "MOLMAG" data sheet

The following table provides information about the project.

Coordinator
JYVASKYLAN YLIOPISTO 

Organization address
address: SEMINAARINKATU 15
city: JYVASKYLA
postcode: 40100
website: http://www.jyu.fi

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Finland [FI]
 Project website https://www.jyu.fi/kemia/en/research/main-group-chemistry/personnel/dr-aaron-mailman
 Total cost 191˙325 €
 EC max contribution 191˙325 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2014
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2015
 Duration (year-month-day) from 2015-08-31   to  2017-08-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    JYVASKYLAN YLIOPISTO FI (JYVASKYLA) coordinator 191˙325.00

Map

 Project objective

One of the next great challenges facing Europe is the development of new materials that reduce our dependence on critical metals such as rare earth elements (REEs). REEs have revolutionized both magnets and microelectronic industry, but the lack of economically exploitable deposits combined with geopolitical concerns have led to an impending resource problem. Molecular magnetic materials based on organic radicals represent one attractive alternative to REEs as the use of organic compounds would allow chemical processing rather than metallurgical. The challenge lies in developing radicals that are indefinitely stable under standard ambient conditions but still structurally tunable to attain the desired properties. This research project investigates two families of stable organic radicals and their metal complexes as new components for molecular magnetic materials. The radicals are based on the 1,2,4-triazinyl framework which, despite a long history and extreme stability, has only recently raised interest in materials oriented research. The potential of the investigated radicals will be exploited in two approaches. First, co-crystallization of the triazinyl radicals is studied as a novel design strategy to enhance intermolecular ferromagnetic interactions in organic radicals, and second, coordination of the radicals to paramagnetic metal centres is used as further means to control spin interactions through intramolecular spin coupling. The proposal combines the research ideas and synthetic skills of the experienced researcher with the knowledge and infrastructure of the supervisors and their hosting institutions, creating an interdisciplinary project that spans multiple fields from organic and organometallic synthesis to computational chemistry and condensed matter physics. Through the synthesis of new building blocks for real-world materials, the project will not only enhance the understanding of molecular magnetism but also the career development of the MSC fellow.

 Publications

year authors and title journal last update
List of publications.
2017 Petra Vasko, Juha Hurmalainen, Akseli Mansikkamäki, Anssi Peuronen, Aaron Mailman and Heikki M. Tuononen
Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement
published pages: , ISSN: 1477-9226, DOI: 10.1039/c7dt03243a
Dalton Transactions 2019-07-24

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