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SWITCHCATALYSIS

Switchable catalytic activity of spin crossover materials

Total Cost €

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EC-Contrib. €

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Partnership

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Project "SWITCHCATALYSIS" data sheet

The following table provides information about the project.

Coordinator
JOHANNES GUTENBERG-UNIVERSITAT MAINZ 

Organization address
address: SAARSTRASSE 21
city: MAINZ
postcode: 55122
website: www.uni-mainz.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Project website http://www.ak-tremel.chemie.uni-mainz.de/Dateien/Switch
 Total cost 159˙460 €
 EC max contribution 159˙460 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2014
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2015
 Duration (year-month-day) from 2015-06-01   to  2017-05-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    JOHANNES GUTENBERG-UNIVERSITAT MAINZ DE (MAINZ) coordinator 159˙460.00

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 Project objective

Spin crossover (SCO) is an intensively studied and highly versatile representative of molecular switches. The change of numerous physical properties during the spin transition has provoked a wide inclusion of SCO materials into various electronic, photonic and mechanical experiments. The main question asked in this project is how the drastic electronic and structural reorganizations accompanying spin transition will influence the catalytic activity of SCO complexes and composites. These studies will cover the redox catalytic activity of SCO molecular complexes, nanoparticles and composites, photocatalytic properties of SCO complexes, catalysis by conjugates with enzymes, and other switchable materials with catalytic activity. The expected results will allow the creation of switchable catalysts and will contribute to the fundamental knowledge on the spin-dependent catalytic activity of metallic centres. This project aims to combine the background of an experienced researcher that works in the domain of spin crossover materials, and the competence of a hosting group that deals with functional nanoparticles including their catalytic and photocatalytic activities. This combination of expertise supported by the facilities of Johannes Gutenberg University will create the optimal conditions for the realization of scientific purposes included in this project and will conduce to the efficient knowledge transfer between the experienced researcher and the host laboratory.

 Publications

year authors and title journal last update
List of publications.
2017 Il\'ya A. Gural\'skiy, Sergii I. Shylin, Vadim Ksenofontov, Wolfgang Tremel
Spin-State Dependent Redox Catalytic Activity of a Switchable Iron(II) Complex
published pages: , ISSN: 1434-1948, DOI: 10.1002/ejic.201700454
European Journal of Inorganic Chemistry 2017 2019-07-24
2016 Il\'ya A. Gural\'skiy, Sergii I. Shylin, Bohdan O. Golub, Vadim Ksenofontov, Igor O. Fritsky, Wolfgang Tremel
High temperature spin crossover in [Fe(pyrazine){Ag(CN) 2 } 2 ] and its solvate
published pages: 9012-9016, ISSN: 1144-0546, DOI: 10.1039/C6NJ01472K
New J. Chem. 40/11 2019-07-24
2016 Il\'ya A. Gural\'skiy, Bohdan O. Golub, Sergii I. Shylin, Vadim Ksenofontov, Helena J. Shepherd, Paul R. Raithby, Wolfgang Tremel, Igor O. Fritsky
Cooperative High-Temperature Spin Crossover Accompanied by a Highly Anisotropic Structural Distortion
published pages: 3191-3195, ISSN: 1434-1948, DOI: 10.1002/ejic.201600406
European Journal of Inorganic Chemistry 2016/19 2019-07-24

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