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SElySOs SIGNED

Development of new electrode materials and understanding of degradation mechanisms on Solid Oxide High Temperature Electrolysis Cells.

Total Cost €

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EC-Contrib. €

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Partnership

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Project "SElySOs" data sheet

The following table provides information about the project.

Coordinator
IDRYMA TECHNOLOGIAS KAI EREVNAS 

Organization address
address: N PLASTIRA STR 100
city: IRAKLEIO
postcode: 70013
website: www.forth.gr

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Greece [EL]
 Project website http://selysos.iceht.forth.gr/
 Total cost 2˙939˙655 €
 EC max contribution 2˙939˙655 € (100%)
 Programme 1. H2020-EU.3.3.8.2. (Increase the energy efficiency of production of hydrogen mainly from water electrolysis and renewable sources while reducing operating and capital costs, so that the combined system of the hydrogen production and the conversion using the fuel cell system...)
 Code Call H2020-JTI-FCH-2014-1
 Funding Scheme FCH2-RIA
 Starting year 2015
 Duration (year-month-day) from 2015-11-02   to  2020-05-01

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    IDRYMA TECHNOLOGIAS KAI EREVNAS EL (IRAKLEIO) coordinator 498˙550.00
2    FORSCHUNGSZENTRUM JULICH GMBH DE (JULICH) participant 594˙627.00
3    ETHNIKO KENTRO EREVNAS KAI TECHNOLOGIKIS ANAPTYXIS EL (THERMI THESSALONIKI) participant 450˙000.00
4    VYSOKA SKOLA CHEMICKO-TECHNOLOGICKA V PRAZE CZ (PRAHA) participant 396˙750.00
5    Prototech AS NO (Bergen) participant 350˙000.00
6    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS FR (PARIS) participant 349˙727.00
7    PYROGENESIS SA EL (LAVRION) participant 300˙000.00

Map

 Project objective

The high temperature Solid Oxide Electrolysis (SOEC) technology has a huge potential for future mass production of hydrogen and shows great dynamics to become commercially competitive against other electrolysis technologies (AEL, PEMEL), which are better established but more expensive and less efficient. On the downside, up to now SOECs are less mature and performance plus durability are currently the most important issues that need to be tackled, while the technological progress is still below the typically accepted standard requirements. Indicatively, the latest studies on State-of-the-Art (SoA) cells with Ni/YSZ and LSM as cathode and anode electrodes, respectively, show that the performance decreases about 2-5% after 1000h of operation for the H2O electrolysis reaction, whereas for the co-electrolysis process the situation is even worse and the technology level is much more behind the commercialization thresholds. In this respect, SElySOs is taking advantage of the opportunity for a 4-years duration project and focuses on understanding of the degradation and lifetime fundamentals on both of the SOEC electrodes, for minimization of their degradation and improvement of their performance and stability mainly under H2O electrolysis and in a certain extent under H2O/CO2 co-electrolysis conditions. Specifically, the main efforts will be addressed on the study of both water and O2 electrodes, where there will be investigation on: (i) Modified SoA Ni-based cermets, (ii) Alternative perovskite-type materials, (iii) Thorough investigation on the O2 electrode, where new more efficient O2 evolving electrodes are going to be examined and proposed. An additional strong point of the proposed project is the development of a theoretical model for description of the performance and degradation of the SOEC fuel electrode. Overall, SElySOs adopts a holistic approach for coping with SOECs degradation and performance, having a strong orientation on the market requirements.

 Deliverables

List of deliverables.
SOEC manufacture and test report, 2nd stack test Documents, reports 2020-03-17 11:42:58
Definition of the solid oxide steam electrolysis cathode mathematical model Documents, reports 2020-03-17 11:42:58
Established business blog Websites, patent fillings, videos etc. 2020-03-17 11:42:58
Internet (web) site dedicated to the scientific community Websites, patent fillings, videos etc. 2020-03-17 11:42:58
Complete single cells for SOEC measurements, comprising the best performing developed electrodes Documents, reports 2020-03-17 11:42:58
SOEC manufacture and test report, 1st stack test Documents, reports 2020-03-17 11:42:58
Report on the preparation activities of single cells with Thermal spraying Documents, reports 2020-03-17 11:42:58

Take a look to the deliverables list in detail:  detailed list of SElySOs deliverables.

 Publications

year authors and title journal last update
List of publications.
2019 V. Vibhu, I.C. Vinke, R.-A. Eichel, J.-M. Bassat, L.G.J. de Haart
La2Ni1−Co O4+δ (x = 0.0, 0.1 and 0.2) based efficient oxygen electrode materials for solid oxide electrolysis cells
published pages: 227292, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2019.227292
Journal of Power Sources 444 2020-03-17
2017 Vasiliki Papaefthimiou, Dimitris K. Niakolas, Fotios Paloukis, Thierry Dintzer, Spyridon Zafeiratos
Is Steam an Oxidant or a Reductant for Nickel/Doped-Ceria Cermets?
published pages: 164-170, ISSN: 1439-4235, DOI: 10.1002/cphc.201600948
ChemPhysChem 18/1 2020-03-17
2019 V. Vibhu, S. Yildiz, I. C. Vinke, R.-A. Eichel, J.-M. Bassat, L. G. J. de Haart
High Performance LSC Infiltrated LSCF Oxygen Electrode for High Temperature Steam Electrolysis Application
published pages: F102-F108, ISSN: 0013-4651, DOI: 10.1149/2.0741902jes
Journal of The Electrochemical Society 166/2 2020-03-17
2019 Evangelia Ioannidou, Stylianos Neophytides, Dimitrios Niakolas
Experimental Clarification of the RWGS Reaction Effect in H2O/CO2 SOEC Co-Electrolysis Conditions
published pages: 151, ISSN: 2073-4344, DOI: 10.3390/catal9020151
Catalysts 9/2 2020-03-17
2019 Ch. Neofytidis, E. Ioannidou, L. Sygellou, M. Kollia, D.K. Niakolas
Affecting the H2O electrolysis process in SOECs through modification of NiO/GDC; experimental case of Au-Mo-Ni synergy
published pages: 260-275, ISSN: 0021-9517, DOI: 10.1016/j.jcat.2019.04.002
Journal of Catalysis 373 2020-03-17
2018 E. Ioannidou, Ch. Neofytidis, L. Sygellou, D.K. Niakolas
Au-doped Ni/GDC as an Improved Cathode Electrocatalyst for H 2 O Electrolysis in SOECs
published pages: 253-264, ISSN: 0926-3373, DOI: 10.1016/j.apcatb.2018.05.017
Applied Catalysis B: Environmental 236 2020-03-17
2018 K.M. Papazisi, M.E. Farmaki, D. Tsiplakides, S. Balomenou
High temperature electrolysis cells with the use of solid oxide fuel cell state-of-the-art electrode materials
published pages: 27536-27542, ISSN: 2214-7853, DOI: 10.1016/j.matpr.2018.09.073
Materials Today: Proceedings 5/14 2020-03-17
2019 Petr Vágner, Clemens Guhlke, Vojtěch Miloš, Rüdiger Müller, Jürgen Fuhrmann
A continuum model for yttria-stabilized zirconia incorporating triple phase boundary, lattice structure and immobile oxide ions
published pages: , ISSN: 1432-8488, DOI: 10.1007/s10008-019-04356-9
Journal of Solid State Electrochemistry 2020-03-17
2019 Petr Vágner, Roman Kodým, Karel Bouzek
Thermodynamic analysis of high temperature steam and carbon dioxide systems in solid oxide cells
published pages: 2076-2086, ISSN: 2398-4902, DOI: 10.1039/c9se00030e
Sustainable Energy & Fuels 3/8 2020-03-17

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