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CyclAr SIGNED

Cyclic Arylenevinylene Polymers

Total Cost €

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EC-Contrib. €

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Partnership

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Project "CyclAr" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF MANCHESTER 

Organization address
address: OXFORD ROAD
city: MANCHESTER
postcode: M13 9PL
website: www.manchester.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Project website http://www.functionalmaterials.org.uk
 Total cost 195˙454 €
 EC max contribution 195˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2016
 Duration (year-month-day) from 2016-03-01   to  2018-02-28

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF MANCHESTER UK (MANCHESTER) coordinator 195˙454.00

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 Project objective

Research work at the University of Manchester (UNIMAN) has developed an efficient synthetic method to prepare arylenevinylene polymers with control of molecular weight and end-group functionality by the ring-opening metathesis polymerization (ROMP) of strained 1,9-cyclophanedienes. The CyclAr project will use this methodology to deliver conjugated polymers of novel topologies, including rings, 8-shapes, trefoils and others. Macromolecular rings will be prepared by ring expansion metathesis polymerization (REMP) using a tethered ruthenium carbene complex and more complex topologies from telechelic polymers prepared from a bifunctional ruthenium carbene complex. Electron rich (p-type) and electron poor (n-type) polymer topologies will be prepared from the appropriate functionalised cyclophanedienes and topological heterojunctions examined. These molecules will be screened for their photovoltaic performance as the novel molecular topologies can lead to an enhanced charge separation and fewer loss mechanisms - key factors in achieving higher power conversion efficiency in OPVs. The synthetic methodology to be adopted is novel and application of these topological arylenevinylene polymers as semiconducting materials in device fabrication is unprecedented.

The overall aim of the project is to develop novel topologies for arylenevinylene polymers and to investigate the influence of the molecular shape on the physical, optical and electronic properties.

 Publications

year authors and title journal last update
List of publications.
2018 Benjamin John Lidster, Shuzo Hirata, Shoki Matsuda, Takuya Yamamoto, Venukrishnan Komanduri, Dharam Raj Kumar, Yasuyuki Tezuka, Martin Vacha, Michael L. Turner
Macrocyclic poly( p -phenylenevinylene)s by ring expansion metathesis polymerisation and their characterisation by single-molecule spectroscopy
published pages: 2934-2941, ISSN: 2041-6520, DOI: 10.1039/c7sc03945j
Chemical Science 9/11 2019-06-13

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