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HYBOCOMIX SIGNED

Hydrogen bonds in diblock copolymer/ homopolymer melt

Total Cost €

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EC-Contrib. €

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Partnership

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Project "HYBOCOMIX" data sheet

The following table provides information about the project.

Coordinator
ASTON UNIVERSITY 

Organization address
address: ASTON TRIANGLE
city: BIRMINGHAM
postcode: B4 7ET
website: www.aston.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Project website http://www.aston.ac.uk/eas/staff/a-z/prof-paul-topham/
 Total cost 195˙454 €
 EC max contribution 195˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-CAR
 Starting year 2016
 Duration (year-month-day) from 2016-09-01   to  2018-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    ASTON UNIVERSITY UK (BIRMINGHAM) coordinator 195˙454.00

Map

 Project objective

HYBOCOMIX is focused on a combined theoretical and experimental study of the phase behavior of a blend of an AB diblock copolymer with homopolymer A. where polymer A repeat units can form hydrogen bonds with each other. A completely new self-consistent field theory (SCFT) model will be developed to describe the influence (in such block copolymer systems) of hydrogen bond formation on the block copolymer self-assembly of ordered phases. This model will be exploited to study, both theoretically and experimentally, the phase behavior of an exemplar system; a mixture of polyacrylamide-b-polystyrene (PAM-b-PS) with polyacrylamide (PAM), where polyacrylamide is the hydrogen bonding polymer. The key feature of this interdisciplinary project is in close connection between experiment and theory which will; (i) allow the study of a system that is completely new both from experimental and theoretical points of view and (ii) access model parameters directly from experiment in the framework of a project to provide unequivocal quality for the verification of the new HYBOCOMIX theory. Potential applications of block copolymers with hydrogen bonds are really abundant and include drug delivery applications, self-healing materials, nanolithography and patterning for microelectronics. The success of this project will open the room for future application developments and research of more complex block copolymer systems with hydrogen bonds providing a new widely applicable theoretical method to predict the structure of block copolymers with hydrogen bonds.

 Publications

year authors and title journal last update
List of publications.
2018 Elena Patyukova, Taylor Rottreau, Robert Evans, Paul D. Topham, Martin J. Greenall
Hydrogen Bonding Aggregation in Acrylamide: Theory and Experiment
published pages: , ISSN: 0024-9297, DOI: 10.1021/acs.macromol.8b01118
Macromolecules 2019-06-13
2017 Junliang Zhang, Robert Deubler, Matthias Hartlieb, Liam Martin, Joji Tanaka, Elena Patyukova, Paul D. Topham, Felix H. Schacher, Sébastien Perrier
Evolution of Microphase Separation with Variations of Segments of Sequence-Controlled Multiblock Copolymers
published pages: 7380-7387, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.7b01831
Macromolecules 50/18 2019-04-14

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