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Terpy2DMat SIGNED

Tuning of 2D materials properties through controlled functionalization with opto-electroactive complexes

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 Terpy2DMat project word cloud

Explore the words cloud of the Terpy2DMat project. It provides you a very rough idea of what is the project "Terpy2DMat" about.

complexes    monolayers    gates    modes    self    magnetic    solid    dimensional    electronics       apposite    modify    deeply    coverage    soft    layered    storage    conversion    ligand    world    functional    crystal    interaction    transfer    materials    spintronic    circuits    chemical    spin    sensing    of    redox    pi    tmdcs    electroactive    sams    transition    tpy    back    extremely    degree    charge    action    light    tuning    assembled    contribution    catalysis    metal    organic    proper    spintronics    effect    functionalized    2d    lack    band    optical    herein    exploring    packed    covalent    name    ligands    depending    switchable    crystals    advantages    bonding    few    attached    dichalcogenides    visible    tunable    opto    tune    huge    logic    energy    versatile    robustness    functionalization    terpyridyl    reversible    giving    ultrathin    fascinating    mlct    region    modification    electronic    electrostatic    strength    nanosheets   

Project "Terpy2DMat" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITAT DE VALENCIA 

Organization address
address: AVENIDA BLASCO IBANEZ 13
city: VALENCIA
postcode: 46010
website: www.uv.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 170˙121 €
 EC max contribution 170˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-11-01   to  2020-10-03

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAT DE VALENCIA ES (VALENCIA) coordinator 170˙121.00

Map

 Project objective

Ultrathin two-dimensional nanosheets of layered transition metal dichalcogenides (TMDCs) are the fascinating materials for several applications in electronics, opto-electronics, spintronics, sensing, catalysis, energy storage and conversion, to name a few. The fields have witnessed huge attention world-wide in recent years. In spite of advancement of the 2D materials, there is a lack of proper chemical functionalization. Therefore, apposite functionalization of TMDCs to tune electronic charge and spin properties beyond current systems is extremely crucial. Herein, we propose chemical functionalization of 2D-TMDCs by optical and electroactive functional terpyridyl (tpy) complexes. The functional terpyridyl complexes offer numerous advantages including (i) much more robustness due to strong metal-to-ligand back bonding through [dπ(M)-pπ(L)] as compared to the organic ligands, (ii) versatile coordination modes, (iii) tunable, and reversible redox properties, and (iv) switchable metal-to-ligand charge-transfer (MLCT) band in the visible region. Through this functionalization we will be able to: I-Modify 2D materials properties at different level depending on: (i) The strength of the new interaction between complex and 2D crystal, from soft modification by electrostatic interaction to strong modification by covalent one; and (ii) the degree of functionalization, from low coverage of the 2D crystal to highly packed coverage giving rise to self-assembled monolayers (SAMs) formation. II-Tuning of the 2D crystals properties through the effect of light on the opto-electroactive complexes attached on them. The contribution from light-driven action to the electronic and magnetic properties will be deeply studied by the implementation of functionalized 2D-TMDCs into solid state devices, exploring their potential as logic gates and circuits or spintronic devices.

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The information about "TERPY2DMAT" are provided by the European Opendata Portal: CORDIS opendata.

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