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Tuning of 2D materials properties through controlled functionalization with opto-electroactive complexes

Total Cost €


EC-Contrib. €






 Terpy2DMat project word cloud

Explore the words cloud of the Terpy2DMat project. It provides you a very rough idea of what is the project "Terpy2DMat" about.

of    redox    name    circuits    metal    world    deeply    crystal    ligand    sams    mlct    robustness    strength    modification    nanosheets    light    effect    apposite    few    attached    crystals    transition    modes    gates    back    magnetic    region    electronic    monolayers    storage    versatile    logic    spin    bonding    visible    charge       electrostatic    covalent    electroactive    catalysis    tune    electronics    sensing    herein    organic    chemical    proper    dichalcogenides    reversible    coverage    pi    ligands    interaction    modify    functionalization    layered    conversion    tpy    dimensional    functional    transfer    packed    advantages    optical    fascinating    solid    degree    assembled    giving    energy    tunable    complexes    switchable    band    2d    exploring    huge    depending    extremely    tmdcs    opto    terpyridyl    ultrathin    lack    self    soft    functionalized    tuning    action    spintronic    contribution    materials    spintronics   

Project "Terpy2DMat" data sheet

The following table provides information about the project.


Organization address
postcode: 46010

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 170˙121 €
 EC max contribution 170˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-11-01   to  2020-10-03


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAT DE VALENCIA ES (VALENCIA) coordinator 170˙121.00


 Project objective

Ultrathin two-dimensional nanosheets of layered transition metal dichalcogenides (TMDCs) are the fascinating materials for several applications in electronics, opto-electronics, spintronics, sensing, catalysis, energy storage and conversion, to name a few. The fields have witnessed huge attention world-wide in recent years. In spite of advancement of the 2D materials, there is a lack of proper chemical functionalization. Therefore, apposite functionalization of TMDCs to tune electronic charge and spin properties beyond current systems is extremely crucial. Herein, we propose chemical functionalization of 2D-TMDCs by optical and electroactive functional terpyridyl (tpy) complexes. The functional terpyridyl complexes offer numerous advantages including (i) much more robustness due to strong metal-to-ligand back bonding through [dπ(M)-pπ(L)] as compared to the organic ligands, (ii) versatile coordination modes, (iii) tunable, and reversible redox properties, and (iv) switchable metal-to-ligand charge-transfer (MLCT) band in the visible region. Through this functionalization we will be able to: I-Modify 2D materials properties at different level depending on: (i) The strength of the new interaction between complex and 2D crystal, from soft modification by electrostatic interaction to strong modification by covalent one; and (ii) the degree of functionalization, from low coverage of the 2D crystal to highly packed coverage giving rise to self-assembled monolayers (SAMs) formation. II-Tuning of the 2D crystals properties through the effect of light on the opto-electroactive complexes attached on them. The contribution from light-driven action to the electronic and magnetic properties will be deeply studied by the implementation of functionalized 2D-TMDCs into solid state devices, exploring their potential as logic gates and circuits or spintronic devices.

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The information about "TERPY2DMAT" are provided by the European Opendata Portal: CORDIS opendata.

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