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Terpy2DMat SIGNED

Tuning of 2D materials properties through controlled functionalization with opto-electroactive complexes

Total Cost €

EC-Contrib. €

Partnership

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Terpy2DMat project word cloud

Explore the words cloud of the Terpy2DMat project. It provides you a very rough idea of what is the project "Terpy2DMat" about.

modes huge electrostatic robustness back region gates ligands modification transfer ultrathin interaction giving advantages world nanosheets p 2d electroactive attached electronic transition assembled ligand logic apposite tuning of extremely opto depending redox self complexes storage functionalization mlct solid circuits tunable conversion band fascinating soft tmdcs crystals deeply name energy modify versatile strength contribution electronics spin covalent light lack materials terpyridyl pi herein dimensional exploring functional magnetic tpy degree tune effect catalysis crystal dichalcogenides charge coverage reversible sensing monolayers spintronic proper functionalized few bonding spintronics packed chemical action switchable organic visible optical sams layered metal

Project "Terpy2DMat" data sheet

The following table provides information about the project.

Coordinator	UNIVERSITAT DE VALENCIA Organization address address: AVENIDA BLASCO IBANEZ 13 city: VALENCIA postcode: 46010 website: www.uv.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Spain [ES]
Total cost	170˙121 €
EC max contribution	170˙121 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2015
Funding Scheme	MSCA-IF-EF-ST
Starting year	2017
Duration (year-month-day)	from 2017-11-01 to 2020-10-03

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	UNIVERSITAT DE VALENCIA UNIVERSITAT DE VALENCIA Organization address address: AVENIDA BLASCO IBANEZ 13 city: VALENCIA postcode: 46010 website: www.uv.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	ES (VALENCIA)	coordinator	170˙121.00

Map

Project objective

Ultrathin two-dimensional nanosheets of layered transition metal dichalcogenides (TMDCs) are the fascinating materials for several applications in electronics, opto-electronics, spintronics, sensing, catalysis, energy storage and conversion, to name a few. The fields have witnessed huge attention world-wide in recent years. In spite of advancement of the 2D materials, there is a lack of proper chemical functionalization. Therefore, apposite functionalization of TMDCs to tune electronic charge and spin properties beyond current systems is extremely crucial. Herein, we propose chemical functionalization of 2D-TMDCs by optical and electroactive functional terpyridyl (tpy) complexes. The functional terpyridyl complexes offer numerous advantages including (i) much more robustness due to strong metal-to-ligand back bonding through [dπ(M)-pπ(L)] as compared to the organic ligands, (ii) versatile coordination modes, (iii) tunable, and reversible redox properties, and (iv) switchable metal-to-ligand charge-transfer (MLCT) band in the visible region. Through this functionalization we will be able to: I-Modify 2D materials properties at different level depending on: (i) The strength of the new interaction between complex and 2D crystal, from soft modification by electrostatic interaction to strong modification by covalent one; and (ii) the degree of functionalization, from low coverage of the 2D crystal to highly packed coverage giving rise to self-assembled monolayers (SAMs) formation. II-Tuning of the 2D crystals properties through the effect of light on the opto-electroactive complexes attached on them. The contribution from light-driven action to the electronic and magnetic properties will be deeply studied by the implementation of functionalized 2D-TMDCs into solid state devices, exploring their potential as logic gates and circuits or spintronic devices.

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The information about "TERPY2DMAT" are provided by the European Opendata Portal: CORDIS opendata.