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FeCHACT TERMINATED

Catalytic Csp3-H functionalization via carbene insertion meets sustainability: Developing an unprecedented Iron methodology

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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0

 FeCHACT project word cloud

Explore the words cloud of the FeCHACT project. It provides you a very rough idea of what is the project "FeCHACT" about.

group    forwards    wealth    characterization    transference    benefit    reactive    dr    chemicals    hazardous    academic    oacute    senior    frontiers    line    saturated    confines    functionalization    hern    ylide    costas    chemistry    accumulated    diazocompounds    feedstock    identification    cutting    steric    benign    zinc    break    precious    sources    additionally    progress    sustainable    prof    position    toxicity    leader    metals    evaluation    vast    stone    supervisor    rational    methodology    active    carbene    mez    iron    hydrocarbons    valuable    reagents    insights    refined    spanning    successfully    catalysed    catalytic    aacute    strategies    candidate    internationally    designed    push    environmental    transition    proposed    stepping    sulfur    unequivocal    of    mechanistic    organic    electronic    organometallic    compounds    edge    species    equipped    recognised    synthesis    fragments    ground    instilled    transfer    employed    complexes    kinetic    carbenoid    synthetic    csp3   

Project "FeCHACT" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITAT DE GIRONA 

Organization address
address: PLACA SANT DOMENEC 3
city: GIRONA
postcode: 17004
website: www.udg.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Project website http://iqcc.udg.edu/wordpress/former-members-list/
 Total cost 170˙121 €
 EC max contribution 170˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2019
 Duration (year-month-day) from 2019-01-01   to  2020-12-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAT DE GIRONA ES (GIRONA) coordinator 170˙121.00

Map

 Project objective

Proposed to break new ground quickly and to establish new frontiers in cutting-edge Csp3-H functionalization chemistry, this proposal focuses on the development and exploitation of iron catalysed carbene transfer towards saturated hydrocarbons, a vast and low cost feedstock for the synthesis of more valuable chemicals. By rational design and evaluation of low toxicity and low cost iron complexes equipped with different electronic and steric properties, new environmental benign and sustainable catalytic strategies will be instilled into this promising synthetic methodology. Extending beyond the confines of traditional precious metals catalysed carbene transference, new non-hazardous sources for these fragments, compared with the currently employed diazocompounds, will be designed and refined in sulfur ylide compounds and zinc carbenoid reagents. The project will benefit from the accumulated wealth of experience of the candidate Dr. Hernán-Gómez in synthesis, characterization and kinetic studies of highly reactive organometallic reagents, spanning from transition metals to main group elements. This will offer valuable mechanistic insights into the investigated processes, including unequivocal identification of the catalytic active species, key aspects to progress the proposed project. Additionally, through collaboration with supervisor Prof. Costas, an internationally recognised leader in the chemistry of iron compounds applied to organic synthesis, Dr. Hernán-Gómez will be provided with the required support to successfully push forwards the frontiers of the proposed research line in the field of iron chemistry, a stepping stone towards achieving a senior academic position.

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The information about "FECHACT" are provided by the European Opendata Portal: CORDIS opendata.

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