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FeCHACT TERMINATED

Catalytic Csp3-H functionalization via carbene insertion meets sustainability: Developing an unprecedented Iron methodology

Total Cost €

0

EC-Contrib. €

0

Partnership

0

Views

0

 FeCHACT project word cloud

Explore the words cloud of the FeCHACT project. It provides you a very rough idea of what is the project "FeCHACT" about.

synthesis    functionalization    of    fragments    academic    toxicity    synthetic    chemicals    internationally    electronic    hern    rational    mechanistic    designed    break    position    candidate    organic    vast    aacute    hazardous    reactive    confines    carbene    benefit    characterization    wealth    ground    sulfur    csp3    stone    transfer    feedstock    prof    environmental    carbenoid    spanning    diazocompounds    supervisor    successfully    progress    benign    metals    additionally    compounds    costas    transference    recognised    steric    species    employed    cutting    senior    kinetic    catalytic    valuable    active    accumulated    methodology    stepping    line    evaluation    sustainable    edge    reagents    refined    group    strategies    precious    forwards    zinc    insights    catalysed    complexes    chemistry    oacute    hydrocarbons    transition    mez    sources    frontiers    dr    instilled    organometallic    unequivocal    ylide    identification    equipped    iron    saturated    push    proposed    leader   

Project "FeCHACT" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITAT DE GIRONA 

Organization address
address: PLACA SANT DOMENEC 3
city: GIRONA
postcode: 17004
website: www.udg.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Project website http://iqcc.udg.edu/wordpress/former-members-list/
 Total cost 170˙121 €
 EC max contribution 170˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2019
 Duration (year-month-day) from 2019-01-01   to  2020-12-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAT DE GIRONA ES (GIRONA) coordinator 170˙121.00

Map

 Project objective

Proposed to break new ground quickly and to establish new frontiers in cutting-edge Csp3-H functionalization chemistry, this proposal focuses on the development and exploitation of iron catalysed carbene transfer towards saturated hydrocarbons, a vast and low cost feedstock for the synthesis of more valuable chemicals. By rational design and evaluation of low toxicity and low cost iron complexes equipped with different electronic and steric properties, new environmental benign and sustainable catalytic strategies will be instilled into this promising synthetic methodology. Extending beyond the confines of traditional precious metals catalysed carbene transference, new non-hazardous sources for these fragments, compared with the currently employed diazocompounds, will be designed and refined in sulfur ylide compounds and zinc carbenoid reagents. The project will benefit from the accumulated wealth of experience of the candidate Dr. Hernán-Gómez in synthesis, characterization and kinetic studies of highly reactive organometallic reagents, spanning from transition metals to main group elements. This will offer valuable mechanistic insights into the investigated processes, including unequivocal identification of the catalytic active species, key aspects to progress the proposed project. Additionally, through collaboration with supervisor Prof. Costas, an internationally recognised leader in the chemistry of iron compounds applied to organic synthesis, Dr. Hernán-Gómez will be provided with the required support to successfully push forwards the frontiers of the proposed research line in the field of iron chemistry, a stepping stone towards achieving a senior academic position.

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The information about "FECHACT" are provided by the European Opendata Portal: CORDIS opendata.

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