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VSHER SIGNED

Mechanistic Understanding of Heterogenised Hydrogen Evolution Catalysts Through Vibrational Spectroelectrochemistry

Total Cost €

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EC-Contrib. €

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Partnership

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Project "VSHER" data sheet

The following table provides information about the project.

Coordinator
THE CHANCELLOR MASTERS AND SCHOLARSOF THE UNIVERSITY OF CAMBRIDGE 

Organization address
address: TRINITY LANE THE OLD SCHOOLS
city: CAMBRIDGE
postcode: CB2 1TN
website: www.cam.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Project website http://www-reisner.ch.cam.ac.uk/index.html
 Total cost 183˙454 €
 EC max contribution 183˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2016
 Duration (year-month-day) from 2016-04-01   to  2018-03-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE CHANCELLOR MASTERS AND SCHOLARSOF THE UNIVERSITY OF CAMBRIDGE UK (CAMBRIDGE) coordinator 183˙454.00

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 Project objective

Hydrogen (H2) will play a central role in the future global energy economy. It is therefore of utmost importance to develop economic routes for the production of H2 to make it more attractive as energy carrier medium in the future. Particularly, Co and Ni based compounds have gained attention for molecular H2 catalysis lately. Co glyoxime and pentapyridine coordinative complexes as well as Ni phosphine compounds are promising candidates exhibiting high catalytic activity in both electro- and light driven H2 catalysis in water. Nevertheless, for technological application the catalysts have to be immobilized on electrode surfaces. The adsorption strongly alters the catalytic reactions, which is still not clearly understood. To investigate the adsorbed catalysts, advanced spectroscopic methods are required that are able to provide sensitive information on the catalytic reaction at a molecular level. The aim of this proposed research is to investigate the heterogeneous catalytic reaction mechanism of Co and Ni mediated catalysis using an innovative combination of potential controlled confocal resonance Raman and ATR FT infrared absorption spectroscopy assisted by electrocatalytic methods and DFT calculations. For this, the three mentioned types of catalysts will be adsorbed on metal oxide surfaces and their catalytic reactions spectroelectrochemically and electrochemically investigated. Special emphasis is led on the role of heterogeneous electron and proton transfer steps on the overall heterogeneous catalytic activity compared to the homogeneous case. Through variation of the electrode material, the modulating material/catalyst interaction is aimed to be investigated in detail. In the outcome, the results will afford a comprehensive picture of the mechanism of metal catalysed HER.

 Publications

year authors and title journal last update
List of publications.
2018 David Wakerley, Khoa Ly, Nikolay Kornienko, Katherine Orchard, Moritz Kuehnel, Erwin Reisner
Aerobic conditions enhance the photocatalytic stability of CdS/CdOx quantum dots
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201802353
Chemistry - A European Journal 2019-06-13
2017 Bertrand Reuillard, Khoa H. Ly, Timothy E. Rosser, Moritz F. Kuehnel, Ingo Zebger, Erwin Reisner
Tuning Product Selectivity for Aqueous CO 2 Reduction with a Mn(bipyridine)-pyrene Catalyst Immobilized on a Carbon Nanotube Electrode
published pages: 14425-14435, ISSN: 0002-7863, DOI: 10.1021/jacs.7b06269
Journal of the American Chemical Society 139/41 2019-06-13
2017 Reuillard, Bertrand Gauthier; Ly, Khoa H; Hildebrandt, Peter; Jeuken, Lars JC; Butt, Julea N; Reisner, Erwin
High Performance Reduction of H2O2 with an Electron Transport Decaheme Cytochrome on a Porous ITO Electrode.
published pages: 3324-3327, ISSN: 0002-7863, DOI: 10.17863/CAM.8140
Journal of the American Chemical Society 139/9 2019-06-13
2017 David W. Wakerley, Moritz F. Kuehnel, Katherine L. Orchard, Khoa H. Ly, Timothy E. Rosser, Erwin Reisner
Solar-driven reforming of lignocellulose to H2 with a CdS/CdOx photocatalyst
published pages: 17021, ISSN: 2058-7546, DOI: 10.1038/nenergy.2017.21
Nature Energy 2/4 2019-06-13

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