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SUPRACOP SIGNED

Systems Chemistry Approach towards Semiconductive Supramolecular Copolymers with Homo- and Heterometallophilic Interactions

Total Cost €

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EC-Contrib. €

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Partnership

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 SUPRACOP project word cloud

Explore the words cloud of the SUPRACOP project. It provides you a very rough idea of what is the project "SUPRACOP" about.

complementarity    suitable    create    bonding    complementary    reversibility    excellent    units    geometry    charged    optimization    attracted    summarized    semiconductive    metallic    electron    successful    au    strategy    chemistry    stacking    copolymers    water    surface    pt2    pi    equivalent    light    ag    pd    science    implications    introduction    metal    insulators    conductivities    electrical    positively    soluble    aromatic    perturbation    optical    ligands    dimensional    pt    unprecedented    gels    negatively    anticipated    poor    covalent    decomposition    melting    structures    materials    solvents    chain    photophysical    suffer    geometrically    switchable    proximity    groups    remarkable    exhibit    ultimately    considerable    organic    electrostatic    ordered    conductivity    solubility    prior    proved    ions    contacts    dissimilar    processability    close    nature    hydrogen    price    geometrical    chains    bulk    either    centres    supramolecular    decades    semi    infinite    alkyl    introducing    stability    weak    dichroism    interactions    extended    interacting    optoelectronics   

Project "SUPRACOP" data sheet

The following table provides information about the project.

Coordinator
WESTFAELISCHE WILHELMS-UNIVERSITAET MUENSTER 

Organization address
address: SCHLOSSPLATZ 2
city: Munster
postcode: 48149
website: www.uni-muenster.de/en/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 1˙493˙750 €
 EC max contribution 1˙493˙750 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2016-STG
 Funding Scheme ERC-STG
 Starting year 2017
 Duration (year-month-day) from 2017-05-01   to  2022-04-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    WESTFAELISCHE WILHELMS-UNIVERSITAET MUENSTER DE (Munster) coordinator 1˙493˙750.00

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 Project objective

Infinite one-dimensional structures with a metallic main chain of short metal-metal contacts have attracted considerable attention in the field of materials science for many decades due to their excellent optical properties and remarkable dichroism and electrical (semi)conductivity. These materials suffer, however, from decomposition prior to melting and low solubility and processability. The strategy of introducing alkyl side chains of different nature in the past two decades proved to be particularly successful towards better soluble materials or gels with implications in optoelectronics. However, this comes at the price of reduced bulk conductivities leading in some cases to electrical insulators due to the perturbation of the metal-metal contacts.

In this proposal, a Systems Chemistry approach will be introduced to create unprecedented supramolecular copolymers that are anticipated to exhibit: a) high solubility, reversibility and stability in organic solvents and water and, b) short metal contacts involving either positively and negatively charged metal ions of the same nature (Pt2/Pt2-) or dissimilar metal centres (Pd(II)/Pt(II) and Ag(I)/Au(I)) with equivalent coordination geometry. To achieve this goal, ligands with an extended aromatic surface for pi-stacking supported by complementary non-covalent interactions have been selected to bring suitable metal ions in close proximity. This can be summarized in three approaches. 1) Optimization of the geometrical complementarity between the interacting ligands; 2) Introduction of hydrogen bonding and electrostatic complementarity between side groups, and 3) Exploiting weak interactions between geometrically equivalent electron rich and electron poor units. The extent of metal-metal interactions can be ultimately controlled by introducing suitable light switchable groups.

This concept is expected to provide access to novel, highly-ordered materials with rich photophysical and semiconductive properties.

 Publications

year authors and title journal last update
List of publications.
2019 Anja Langenstroer, Kalathil K. Kartha, Yeray Dorca, Jörn Droste, Vladimir Stepanenko, Rodrigo Q. Albuquerque, Michael Ryan Hansen, Luis Sánchez, Gustavo Fernández
Unraveling Concomitant Packing Polymorphism in Metallosupramolecular Polymers
published pages: 5192-5200, ISSN: 0002-7863, DOI: 10.1021/jacs.8b11011
Journal of the American Chemical Society 141/13 2020-01-30
2019 Kalathil K. Kartha, Naveen Kumar Allampally, Antiope T. Politi, Deepak D. Prabhu, Hayato Ouchi, Rodrigo Q. Albuquerque, Shiki Yagai, Gustavo Fernández
Influence of metal coordination and light irradiation on hierarchical self-assembly processes
published pages: , ISSN: 2041-6520, DOI: 10.1039/C8SC03875A
Chemical Science 2019-05-23

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