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CATLIGCAR SIGNED

Designing Novel Efficient Catalytic Strategies for the Transformation of Lignocellulose into Lignin-derived Chemicals and Valorisable Carbohydrates

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 CATLIGCAR project word cloud

Explore the words cloud of the CATLIGCAR project. It provides you a very rough idea of what is the project "CATLIGCAR" about.

relationships    social    planes    metals    alternative    multifunctional    effect    dispersed    palladium    class    fuels    structure    zno    strength    catalytic    enriched    enhanced    proper    mechanistic    catalyst    fractionation    donor    biomass    paper    simultaneously    reactive    crystal    acid    redox    fossil    h2    acidic    abundant    nickel    ru    tremendous    efficient    lignocellulose    chemicals    solid    pot    oxide    aid    tuned    crlf    nanoparticles    polyhedra    ing    received    catalysts    context    renewable    strategy    size    particles    ni    conversion    zinc    exposure    rods    sites    lewis    ruthenium    solvent    reusability    varying    economic    retaining    tested    shape    integration    lignin    hemicellulose    kinetic    efficiency    spheres    reductive    interactions    family    selective    cellulose    superior    techniques    noble    synergistic    hemi    analytical    heterogeneous    ethanol    minimizing    stability    understand    fraction    pd    nanoscale   

Project "CATLIGCAR" data sheet

The following table provides information about the project.

Coordinator
KATHOLIEKE UNIVERSITEIT LEUVEN 

Organization address
address: OUDE MARKT 13
city: LEUVEN
postcode: 3000
website: www.kuleuven.be

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Belgium [BE]
 Total cost 172˙800 €
 EC max contribution 172˙800 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-10-01   to  2019-09-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    KATHOLIEKE UNIVERSITEIT LEUVEN BE (LEUVEN) coordinator 172˙800.00

Map

 Project objective

The utilization of renewable lignocellulose biomass (composed of cellulose, hemicellulose and lignin) alternative to fossil fuels is crucial for long-term economic and social stability. In this context, the catalytic reductive lignocellulose fractionation (CRLF) process has received tremendous research interest as this strategy enables one-pot conversion of lignocellulose into useful lignin-derived chemicals, while retaining a solid (hemi)cellulose fraction that can be used for the production of fuels, chemicals or paper. The development of promising heterogeneous catalysts having abundant redox and acid properties, along with the application of a proper solvent is a great challenge for efficient CRLF process.

Nanoscale palladium-nickel (Pd-Ni) and ruthenium-nickel (Ru-Ni) particles dispersed on shape-controlled zinc oxide (ZnO) are considered to be a unique class of heterogeneous catalysts due to the size- and shape-tuned catalytic properties. The integration of Ni with Pd and Ru can provide new, enriched, selective redox sites and simultaneously minimizing the use of noble metals. As well, controlling the shape of ZnO particles allows a selective exposure of reactive crystal planes, resulting in enhanced Lewis acidic strength. Thus, the synergistic interactions of Pd-Ni and Ru-Ni nanoparticles with the shape-controlled ZnO will provide superior redox and acid properties that can show a promising effect in CRLF process. Therefore, this project aims to develop a family of novel multifunctional M-Ni/ZnO (M = Pd, Ru) catalysts by varying the ZnO shape (spheres, rods and polyhedra). A range of analytical techniques will be used to understand the catalysts’ properties and aid catalyst design. The efficiency of developed catalysts will be tested for one-pot CRLF process using ethanol as both the solvent and the H2-donor. In-depth catalysts’ reusability and kinetic/mechanistic studies will be conducted to determine structure-activity relationships in the CRLF process.

 Publications

year authors and title journal last update
List of publications.
2019 Putla Sudarsanam, Elise Peeters, Ekaterina V. Makshina, Vasile I. Parvulescu, Bert F. Sels
Advances in porous and nanoscale catalysts for viable biomass conversion
published pages: 2366-2421, ISSN: 0306-0012, DOI: 10.1039/c8cs00452h
Chemical Society Reviews 48/8 2019-12-17
2018 Putla Sudarsanam, Ruyi Zhong, Sander Van den Bosch, Simona M. Coman, Vasile I. Parvulescu, Bert F. Sels
Functionalised heterogeneous catalysts for sustainable biomass valorisation
published pages: , ISSN: 0306-0012, DOI: 10.1039/C8CS00410B
Chemical Society Reviews 2019-04-18

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The information about "CATLIGCAR" are provided by the European Opendata Portal: CORDIS opendata.

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