Explore the words cloud of the FunctionalP4 project. It provides you a very rough idea of what is the project "FunctionalP4" about.
The following table provides information about the project.
|Coordinator Country||Germany [DE]|
|Total cost||1˙955˙846 €|
|EC max contribution||1˙955˙846 € (100%)|
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
|Duration (year-month-day)||from 2018-09-01 to 2023-08-31|
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|1||UNIVERSITAET REGENSBURG||DE (REGENSBURG)||coordinator||1˙955˙846.00|
Organophosphorus compounds are an important and industrially relevant class of molecules with numerous uses, e.g. as reagents in organic synthesis, ligands in catalytically active metal complexes, and in pest control. State-of-the-art synthesis methods for all these valuable and useful compounds rely on an atom inefficient and hazardous multi-step procedure involving the oxidation of white phosphorus (P4) with toxic chlorine gas. Less wasteful and more environmentally benign methods are highly desirable, but transformations of white phosphorus directly into organophosphorus compounds are hardly developed. This project explores new methods for the activation and functionalization of white phosphorus. The metal-mediated stepwise transformation of P4 into organophosphorus compounds is a key objective. Novel transition metal compounds are designed and synthesized, which can generate reactive phosphorus units. The concept of heterobimetallic P4 activation, where two electronically different metal complexes interact with P4 cooperatively, is introduced for this purpose. Reactions of the phosphorus fragments in these new, reactive complexes with electrophiles will produce novel, fundamentally interesting organophosphorus compounds avoiding chlorinated intermediates. Catalytic methods for P4 functionalization are currently unknown, and developing such methods using transition metal and photoredox catalysts is an additional objective of this proposal. By providing novel synthetically useful and even catalytic procedures for converting P4 into organophosphorus compounds, this project will significantly contribute to the development of phosphorus chemistry and more sustainable synthesis methods.
|year||authors and title||journal||last update|
Ulrich Lennert, Percia Beatrice Arockiam, Verena Streitferdt, Daniel J. Scott, Christian RÃ¶dl, Ruth M. Gschwind, Robert Wolf
Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts
published pages: 1101-1106, ISSN: 2520-1158, DOI: 10.1038/s41929-019-0378-4
|Nature Catalysis 2/12||2020-04-03|
Gabriele Hierlmeier, Peter Coburger, Michael Bodensteiner, Robert Wolf
Diâ€ tert â€butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer
published pages: 16918-16922, ISSN: 1433-7851, DOI: 10.1002/anie.201910505
|Angewandte Chemie International Edition 58/47||2020-04-03|
Christoph G. P. Ziegler, Felix Hennersdorf, Jan J. Weigand, Robert Wolf
Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes
published pages: , ISSN: 0044-2313, DOI: 10.1002/zaac.201900351
|Zeitschrift fÃ¼r anorganische und allgemeine Chemie||2020-04-03|
Anup K. Adhikari, Christoph G. P. Ziegler, Kai Schwedtmann, Clemens Taube, Jan. J. Weigand, Robert Wolf
Functionalization of Pentaphosphorus Cations by Complexation
published pages: 18584-18590, ISSN: 1433-7851, DOI: 10.1002/anie.201908998
|Angewandte Chemie International Edition 58/51||2020-04-03|
Christoph G. P. Ziegler, Thomas M. Maier, Stefan Pelties, Clemens Taube, Felix Hennersdorf, Andreas W. Ehlers, Jan J. Weigand, Robert Wolf
Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt
published pages: 1302-1308, ISSN: 2041-6520, DOI: 10.1039/c8sc04745f
|Chemical Science 10/5||2020-04-03|
Christian M. Hoidn, Christian RÃ¶dl, Madison L. McCrea-Hendrick, Theresa Block, Rainer PÃ¶ttgen, Andreas W. Ehlers, Philip P. Power, Robert Wolf
Synthesis of a Cyclic Co 2 Sn 2 Cluster Using a Co â€“ Synthon
published pages: 13195-13199, ISSN: 0002-7863, DOI: 10.1021/jacs.8b08517
|Journal of the American Chemical Society 140/41||2019-04-16|
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