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MOSPhotocat SIGNED

Application of Metal Oxide Semiconductors in Photocatalysis

Total Cost €

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EC-Contrib. €

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Partnership

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 MOSPhotocat project word cloud

Explore the words cloud of the MOSPhotocat project. It provides you a very rough idea of what is the project "MOSPhotocat" about.

focal    linked    reports    regime    bonds    oxide    molecules    linkages    luminescent    optimize    point    synthesis    network    synthetic    irradiation    mechanistic    strengthen    times    reaction    batch    academia    collaborations    continuous    strategy    covalently    techniques    slurry    cheap    transition    industry    experts    adsorbates    photocatalyst    expand    photomicroflow    lsc    career    abundant    starting    mos    solar    chemical    charge    reactions    transformation    valuable    aid    ligand    transfer    pm    extend    photocatalytic    recycling    expensive    linkers    surface    absorption    curie    energy    photoredox    rare    concentrator    holds    light    start    promise    flow    forming    hereto    spectroscopic    complexes    taylor    organic    ligands    marie    efficiency    catalysis    discovery    recently    iridium    effect    ruthenium    photocatalysts    solvents    independent    lmct    photomicroreactors    soft    metal    visible    researcher    semiconductors    reactors    concentrations    scientific    reuse    intend    skills    fellowship   

Project "MOSPhotocat" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITEIT EINDHOVEN 

Organization address
address: GROENE LOPER 3
city: EINDHOVEN
postcode: 5612 AE
website: www.tue.nl/en

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Netherlands [NL]
 Total cost 177˙598 €
 EC max contribution 177˙598 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-07-16   to  2020-07-15

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITEIT EINDHOVEN NL (EINDHOVEN) coordinator 177˙598.00

Map

 Project objective

Recently, visible light photoredox catalysis has come to the focal point of the organic synthetic field and holds promise to use solar irradiation to establish important chemical bonds in the synthesis of complex organic molecules. However, most reports thus far use transition metal complexes based on rare and expensive iridium and ruthenium. In this Marie Curie proposal, metal oxide semiconductors (MOS) will be applied as abundant and cheap visible light photocatalysts to establish C-C and C-N linkages in organic molecules in batch and photomicroflow reactors. To extend their absorption to the visible light range, I will study the formation of so-called ligand-to-metal charge transfer (LMCT) complexes with different adsorbates/ligands covalently linked to the surface of the MOS. The effect of linkers, ligands, different organic solvents, concentrations, as well as reaction times will be studied in the formation of these complexes. The LMCT complexes will be fully characterized with spectroscopic techniques. Next, these new photocatalysts will be evaluated in valuable C-C and C-N forming organic reactions. Furthermore, mechanistic studies will be carried out to aid the discovery process and to further optimize the photocatalysts. Finally, the reactions will be carried out in continuous-flow reactors to increase the efficiency of the photocatalytic transformation. Hereto, a slurry Taylor flow regime will be used and a recycling strategy will be developed to efficiently reuse the photocatalyst. We will also use so-called Luminescent Solar Concentrator PhotoMicroreactors (LSC-PM) to enable the use of solar energy. During this fellowship, I aim to strengthen both my scientific and soft skills required to start an independent researcher career. In addition, I intend to expand my scientific network by starting collaborations with leading experts in both academia and industry.

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The information about "MOSPHOTOCAT" are provided by the European Opendata Portal: CORDIS opendata.

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