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MOSPhotocat SIGNED

Application of Metal Oxide Semiconductors in Photocatalysis

Total Cost €

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EC-Contrib. €

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Partnership

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 MOSPhotocat project word cloud

Explore the words cloud of the MOSPhotocat project. It provides you a very rough idea of what is the project "MOSPhotocat" about.

collaborations    synthetic    techniques    ruthenium    valuable    lsc    network    ligands    continuous    efficiency    adsorbates    hereto    visible    transformation    linkages    photomicroreactors    pm    transition    expensive    expand    catalysis    complexes    batch    forming    industry    linked    optimize    strategy    solar    skills    chemical    reactors    iridium    photoredox    point    organic    bonds    effect    intend    ligand    abundant    energy    curie    reactions    reuse    researcher    surface    mechanistic    photocatalytic    reaction    charge    photocatalysts    scientific    extend    focal    transfer    marie    taylor    academia    fellowship    reports    concentrator    strengthen    aid    independent    times    semiconductors    slurry    spectroscopic    rare    photomicroflow    promise    metal    flow    concentrations    experts    irradiation    recently    discovery    mos    soft    solvents    cheap    absorption    recycling    starting    oxide    covalently    luminescent    synthesis    start    photocatalyst    molecules    career    light    lmct    regime    linkers    holds   

Project "MOSPhotocat" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITEIT EINDHOVEN 

Organization address
address: GROENE LOPER 3
city: EINDHOVEN
postcode: 5612 AE
website: www.tue.nl/en

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Netherlands [NL]
 Total cost 177˙598 €
 EC max contribution 177˙598 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-07-16   to  2020-07-15

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITEIT EINDHOVEN NL (EINDHOVEN) coordinator 177˙598.00

Map

 Project objective

Recently, visible light photoredox catalysis has come to the focal point of the organic synthetic field and holds promise to use solar irradiation to establish important chemical bonds in the synthesis of complex organic molecules. However, most reports thus far use transition metal complexes based on rare and expensive iridium and ruthenium. In this Marie Curie proposal, metal oxide semiconductors (MOS) will be applied as abundant and cheap visible light photocatalysts to establish C-C and C-N linkages in organic molecules in batch and photomicroflow reactors. To extend their absorption to the visible light range, I will study the formation of so-called ligand-to-metal charge transfer (LMCT) complexes with different adsorbates/ligands covalently linked to the surface of the MOS. The effect of linkers, ligands, different organic solvents, concentrations, as well as reaction times will be studied in the formation of these complexes. The LMCT complexes will be fully characterized with spectroscopic techniques. Next, these new photocatalysts will be evaluated in valuable C-C and C-N forming organic reactions. Furthermore, mechanistic studies will be carried out to aid the discovery process and to further optimize the photocatalysts. Finally, the reactions will be carried out in continuous-flow reactors to increase the efficiency of the photocatalytic transformation. Hereto, a slurry Taylor flow regime will be used and a recycling strategy will be developed to efficiently reuse the photocatalyst. We will also use so-called Luminescent Solar Concentrator PhotoMicroreactors (LSC-PM) to enable the use of solar energy. During this fellowship, I aim to strengthen both my scientific and soft skills required to start an independent researcher career. In addition, I intend to expand my scientific network by starting collaborations with leading experts in both academia and industry.

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The information about "MOSPHOTOCAT" are provided by the European Opendata Portal: CORDIS opendata.

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