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MOSPhotocat SIGNED

Application of Metal Oxide Semiconductors in Photocatalysis

Total Cost €

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EC-Contrib. €

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Partnership

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 MOSPhotocat project word cloud

Explore the words cloud of the MOSPhotocat project. It provides you a very rough idea of what is the project "MOSPhotocat" about.

concentrator    valuable    intend    efficiency    transfer    slurry    marie    absorption    industry    reactions    transition    linkers    curie    mechanistic    photomicroflow    techniques    bonds    abundant    extend    adsorbates    strategy    hereto    reports    aid    taylor    fellowship    recently    ligands    linked    recycling    reuse    scientific    optimize    iridium    forming    focal    solvents    synthesis    ligand    start    synthetic    visible    photocatalysts    regime    career    semiconductors    batch    lmct    times    strengthen    energy    luminescent    point    charge    oxide    skills    molecules    concentrations    effect    surface    independent    promise    photomicroreactors    photoredox    flow    expensive    pm    academia    researcher    discovery    catalysis    reaction    photocatalytic    expand    chemical    complexes    organic    ruthenium    cheap    holds    soft    metal    reactors    network    continuous    rare    experts    light    solar    mos    irradiation    linkages    lsc    covalently    collaborations    transformation    starting    photocatalyst    spectroscopic   

Project "MOSPhotocat" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITEIT EINDHOVEN 

Organization address
address: GROENE LOPER 3
city: EINDHOVEN
postcode: 5612 AE
website: www.tue.nl/en

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Netherlands [NL]
 Total cost 177˙598 €
 EC max contribution 177˙598 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-07-16   to  2020-07-15

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITEIT EINDHOVEN NL (EINDHOVEN) coordinator 177˙598.00

Map

 Project objective

Recently, visible light photoredox catalysis has come to the focal point of the organic synthetic field and holds promise to use solar irradiation to establish important chemical bonds in the synthesis of complex organic molecules. However, most reports thus far use transition metal complexes based on rare and expensive iridium and ruthenium. In this Marie Curie proposal, metal oxide semiconductors (MOS) will be applied as abundant and cheap visible light photocatalysts to establish C-C and C-N linkages in organic molecules in batch and photomicroflow reactors. To extend their absorption to the visible light range, I will study the formation of so-called ligand-to-metal charge transfer (LMCT) complexes with different adsorbates/ligands covalently linked to the surface of the MOS. The effect of linkers, ligands, different organic solvents, concentrations, as well as reaction times will be studied in the formation of these complexes. The LMCT complexes will be fully characterized with spectroscopic techniques. Next, these new photocatalysts will be evaluated in valuable C-C and C-N forming organic reactions. Furthermore, mechanistic studies will be carried out to aid the discovery process and to further optimize the photocatalysts. Finally, the reactions will be carried out in continuous-flow reactors to increase the efficiency of the photocatalytic transformation. Hereto, a slurry Taylor flow regime will be used and a recycling strategy will be developed to efficiently reuse the photocatalyst. We will also use so-called Luminescent Solar Concentrator PhotoMicroreactors (LSC-PM) to enable the use of solar energy. During this fellowship, I aim to strengthen both my scientific and soft skills required to start an independent researcher career. In addition, I intend to expand my scientific network by starting collaborations with leading experts in both academia and industry.

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The information about "MOSPHOTOCAT" are provided by the European Opendata Portal: CORDIS opendata.

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