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MOCCA SIGNED

Metal-Organic Cages for Catalysis Applications

Total Cost €

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EC-Contrib. €

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Partnership

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 MOCCA project word cloud

Explore the words cloud of the MOCCA project. It provides you a very rough idea of what is the project "MOCCA" about.

strategies    ligand    investigation    deeply    binding    dioxide    construction    reported    urgent    contrast    linkers    discrete    site    substrate    hydroformylation    supramolecular    carbon    first    tunable    double    fixation    environment    pro    efficiency    catalysis    prepared    protein    reaction    molecular    contain    resource    catalysts    featuring    wrapping    encapsulated    inside    chemical    insertion    dependent    reactions    olefins    fulfill    fuels    limited    industry    divided    buried    principles    self    activation    environments    mocca    metals    nature    alternative    mimics    drastically    outer    toolbox    enzymes    generation    sites    mainly    active    keeping    co2    compete    transformation    natural    plays    evident    metal    starts    functionalize    assembly    simplified    nowadays    organic    fossil    bond    materials    containing    complexes    compounds    cages    feedstock    incorporation    infancy    centers    catalytic    clear    cavity    reduce    shell    enabled    paradigms    easily    direct    fine   

Project "MOCCA" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAT DORTMUND 

Organization address
address: AUGUST SCHMIDT STRASSE 4
city: DORTMUND
postcode: 44227
website: www.tu-dortmund.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 171˙460 €
 EC max contribution 171˙460 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-05-01   to  2020-04-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAT DORTMUND DE (DORTMUND) coordinator 171˙460.00

Map

 Project objective

The formation of all carbon-based materials in nature starts with fixation and transformation of carbon dioxide (CO2) into useful chemical compounds. Such reactions are enabled by enzymes which often contain highly active metals as reaction centers that are deeply buried in a protein. In contrast, fine chemical production in industry is nowadays still mainly dependent on fossil fuels as carbon feedstock. Since fossil fuels are a limited resource there is an urgent need for alternative strategies. MOCCA (= Metal Organic Cages for Catalysis Applications) aims for the direct use of CO2 to functionalize olefins and produce higher carbon compounds. Principles from nature will be applied such as incorporation of metal catalysts inside a discrete cavity that allows specific substrate binding and activation. The process is divided into two steps: (1) CO2 reduction and (2) insertion of reaction products into the double bond of olefins, for example by hydroformylation. Both reactions are of high interest in chemical research and industry; several metal complexes have been reported as catalysts. Metal complexes are easily tunable via ligand design and molecular catalysts featuring active site mimics have been prepared. However, the current generation of these systems cannot compete with the efficiency of enzymes. Today it is clear that drastically simplified active site mimics do not fulfill all necessary conditions for keeping up with their natural paradigms, but also the outer shell plays an important role. Thus, the need for wrapping catalytic sites in a tunable chemical environment is evident. The nowadays available toolbox of design-driven supramolecular self-assembly allows the construction of such tailored environments, while investigation of encapsulated catalysts is still in its infancy. MOCCA will demonstrate the first example of molecular coordination cages containing catalysts as linkers that efficiently reduce CO2 and use the reaction products directly for the pro

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The information about "MOCCA" are provided by the European Opendata Portal: CORDIS opendata.

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