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MOCCA SIGNED

Metal-Organic Cages for Catalysis Applications

Total Cost €

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EC-Contrib. €

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Partnership

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 MOCCA project word cloud

Explore the words cloud of the MOCCA project. It provides you a very rough idea of what is the project "MOCCA" about.

catalytic    fixation    catalysis    strategies    containing    evident    mainly    fine    buried    linkers    inside    outer    prepared    simplified    environments    reported    deeply    efficiency    shell    protein    substrate    contain    olefins    materials    dioxide    natural    enabled    insertion    nowadays    organic    cages    catalysts    direct    metal    fuels    chemical    complexes    alternative    incorporation    limited    molecular    feedstock    drastically    paradigms    hydroformylation    self    double    environment    sites    resource    compete    starts    divided    plays    carbon    mimics    compounds    cavity    functionalize    metals    bond    dependent    mocca    reactions    active    contrast    generation    encapsulated    transformation    clear    discrete    site    keeping    pro    assembly    fossil    activation    supramolecular    nature    industry    urgent    reaction    investigation    ligand    co2    first    toolbox    infancy    enzymes    tunable    wrapping    principles    fulfill    construction    binding    easily    featuring    reduce    centers   

Project "MOCCA" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAT DORTMUND 

Organization address
address: AUGUST SCHMIDT STRASSE 4
city: DORTMUND
postcode: 44227
website: www.tu-dortmund.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 171˙460 €
 EC max contribution 171˙460 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-05-01   to  2020-04-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAT DORTMUND DE (DORTMUND) coordinator 171˙460.00

Map

 Project objective

The formation of all carbon-based materials in nature starts with fixation and transformation of carbon dioxide (CO2) into useful chemical compounds. Such reactions are enabled by enzymes which often contain highly active metals as reaction centers that are deeply buried in a protein. In contrast, fine chemical production in industry is nowadays still mainly dependent on fossil fuels as carbon feedstock. Since fossil fuels are a limited resource there is an urgent need for alternative strategies. MOCCA (= Metal Organic Cages for Catalysis Applications) aims for the direct use of CO2 to functionalize olefins and produce higher carbon compounds. Principles from nature will be applied such as incorporation of metal catalysts inside a discrete cavity that allows specific substrate binding and activation. The process is divided into two steps: (1) CO2 reduction and (2) insertion of reaction products into the double bond of olefins, for example by hydroformylation. Both reactions are of high interest in chemical research and industry; several metal complexes have been reported as catalysts. Metal complexes are easily tunable via ligand design and molecular catalysts featuring active site mimics have been prepared. However, the current generation of these systems cannot compete with the efficiency of enzymes. Today it is clear that drastically simplified active site mimics do not fulfill all necessary conditions for keeping up with their natural paradigms, but also the outer shell plays an important role. Thus, the need for wrapping catalytic sites in a tunable chemical environment is evident. The nowadays available toolbox of design-driven supramolecular self-assembly allows the construction of such tailored environments, while investigation of encapsulated catalysts is still in its infancy. MOCCA will demonstrate the first example of molecular coordination cages containing catalysts as linkers that efficiently reduce CO2 and use the reaction products directly for the pro

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The information about "MOCCA" are provided by the European Opendata Portal: CORDIS opendata.

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