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MOF-reactors SIGNED

Metal-Organic Frameworks as Chemical Reactors for the Synthesis of Well-Defined Sub-Nanometer Metal Clusters

Total Cost €

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EC-Contrib. €

0

Partnership

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 MOF-reactors project word cloud

Explore the words cloud of the MOF-reactors project. It provides you a very rough idea of what is the project "MOF-reactors" about.

mofs    scenario    firstly    humankind    preparation    prices    synthetic    metal    reactors    definitive    cheap    mechanisms    secondly    centre    solid    ground    striking    aforementioned    weakness    heterometallic    biocompatibility    routes    frameworks    families    catalytic    gram    manufacture    achievement    small    works    successful    atoms    situates    antitumoral    situ    chemical    ultimate    ultrasmall    multigram    diffraction    functional    unveiled    unprecedented    snmcs    published    exceptional    characterisation    outside    breakthrough    luminescence    clusters    crystal    tool    ray    breaking    competitive    made    single    species    fabrication    structurally    crystalline    homo    tailor    inedited    structures    drive    synthesis    sub    channels    assisted    foundations    mof    atomic    stable    last    least    superlative    post    despite    industrial    stabilised    strategy    snapshots    electronically    preliminary    ligand    aggregations    nanometer    connected    upscaling    difficult    organic    free    forms   

Project "MOF-reactors" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITAT DE VALENCIA 

Organization address
address: AVENIDA BLASCO IBANEZ 13
city: VALENCIA
postcode: 46010
website: www.uv.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 1˙886˙000 €
 EC max contribution 1˙886˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2018-COG
 Funding Scheme ERC-COG
 Starting year 2019
 Duration (year-month-day) from 2019-03-01   to  2024-02-29

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAT DE VALENCIA ES (VALENCIA) coordinator 1˙886˙000.00

Map

 Project objective

Humankind advancement is connected to the use and development of metal forms. Recent works have unveiled exceptional properties –such as luminescence, biocompatibility, antitumoral activity or a superlative catalytic activity– for small aggregations of metal atoms, so–called sub–nanometer metal clusters (SNMCs). Despite this importance, the gram-scale synthesis of structurally and electronically well–defined SNMCs is still far from being a reality. The present proposal situates at the centre of such weakness and aims at making a breakthrough step-change on the use of metal-organic frameworks (MOFs) as chemical reactors for the in–situ synthesis of stable ligand-free SNMCs with such unique properties. This challenging synthetic strategy, which is assisted by striking published and inedited preliminary results, has solid foundations. Firstly, the design and large-scale preparation of cheap and novel families of highly robust and crystalline MOFs with tailor-made functional channels to be used as chemical reactors. Secondly, the application of solid-state post-synthetic methods to drive the multigram-scale preparation of unique ligand-free homo- and heterometallic SNMCs, which are, in the best-case scenario, very difficult to be obtained and stabilised outside the channels. Last but not least, single-crystal X-Ray diffraction will be used as the definitive tool for the characterisation, at the atomic level, of such ultrasmall species offering unprecedented snapshots about their real structures and formation mechanisms. The ultimate goal will be upscaling this synthetic strategy aiming at the large-scale fabrication of SNMCs and their industrial application will be then evaluated. A successful achievement of all the aforementioned objectives of this ground-breaking project would open new routes for the use of MOFs as chemical reactors to manufacture, at competitive prices, MOF-driven, structurally and electronically well–defined, ligand–free SNMCs in a multigram-scale.

 Publications

year authors and title journal last update
List of publications.
2019 Alejandro Pascual-Álvarez, Joan Cano, Francesc Lloret, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo
Magnetic order in a CuII–DyIII oxamato-based two-dimensional coordination polymer
published pages: 466-475, ISSN: 1631-0748, DOI: 10.1016/j.crci.2019.05.006
Comptes Rendus Chimie 22/6-7 2020-04-01
2019 Marta Mon, Rosaria Bruno, Estefania Tiburcio, Marta Viciano-Chumillas, Lucas H. G. Kalinke, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo
Multivariate Metal–Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water
published pages: 13601-13609, ISSN: 0002-7863, DOI: 10.1021/jacs.9b06250
Journal of the American Chemical Society 141/34 2020-04-01
2020 Marta Viciano-Chumillas, Marta Mon, Jesus Ferrando-Soria, Avelino Corma, Antonio Leyva-Pérez, Donatella Armentano, Emilio Pardo
Metal–Organic Frameworks as Chemical Nanoreactors: Synthesis and Stabilization of Catalytically Active Metal Species in Confined Spaces
published pages: 520-531, ISSN: 0001-4842, DOI: 10.1021/acs.accounts.9b00609
Accounts of Chemical Research 53/2 2020-04-01
2019 Rosa Adam, Marta Mon, Rossella Greco, Lucas H. G. Kalinke, Alejandro Vidal-Moya, Antonio Fernandez, Richard E. P. Winpenny, Antonio Doménech-Carbó, Antonio Leyva-Pérez, Donatella Armentano, Emilio Pardo, Jesús Ferrando-Soria
Self-Assembly of Catalytically Active Supramolecular Coordination Compounds within Metal–Organic Frameworks
published pages: 10350-10360, ISSN: 0002-7863, DOI: 10.1021/jacs.9b03914
Journal of the American Chemical Society 141/26 2020-04-01
2020 Héctor Martínez Pérez-Cejuela, Marta Mon, Jesús Ferrando-Soria, Emilio Pardo, Donatella Armentano, Ernesto F. Simó-Alfonso, José Manuel Herrero-Martínez
Bio-metal-organic frameworks for molecular recognition and sorbent extraction of hydrophilic vitamins followed by their determination using HPLC-UV
published pages: , ISSN: 0026-3672, DOI: 10.1007/s00604-020-4185-z
Microchimica Acta 187/4 2020-04-01
2020 Elisa Esposito, Rosaria Bruno, Marcello Monteleone, Alessio Fuoco, Jesús Ferrando Soria, Emilio Pardo, Donatella Armentano, Johannes Carolus Jansen
Glassy PEEK-WC vs. Rubbery Pebax®1657 Polymers: Effect on the Gas Transport in CuNi-MOF Based Mixed Matrix Membranes
published pages: 1310, ISSN: 2076-3417, DOI: 10.3390/app10041310
Applied Sciences 10/4 2020-04-01
2020 Christian J Doonan, Christopher J Sumby, Michael Huxley, Rosemary Young, Neil R. Champness, Emilio Pardo
Isolating Reactive Metal-based Species in Metal-organic Frameworks – Viable Strategies and Opportunities  
published pages: , ISSN: 2041-6520, DOI: 10.1039/d0sc00485e
Chemical Science 2020-04-01
2019 Marta Mon, Rosaria Bruno, Estefanía Tiburcio, Aida Grau-Atienza, Antonio Sepúlveda-Escribano, Enrique V. Ramos-Fernandez, Alessio Fuoco, Elisa Esposito, Marcello Monteleone, Johannes C. Jansen, Joan Cano, Jesús Ferrando-Soria, Donatella Armentano, Emilio Pardo
Efficient Gas Separation and Transport Mechanism in Rare Hemilabile Metal–Organic Framework
published pages: 5856-5866, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.9b01995
Chemistry of Materials 31/15 2020-04-01
2019 Lucas H. G. Kalinke, Danielle Cangussu, Marta Mon, Rosaria Bruno, Estefania Tiburcio, Francesc Lloret, Donatella Armentano, Emilio Pardo, Jesus Ferrando-Soria
Metal–Organic Frameworks as Playgrounds for Reticulate Single-Molecule Magnets
published pages: 14498-14506, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.9b02086
Inorganic Chemistry 58/21 2020-04-01

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