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NANOSPHERE

NANOStructure Photochemistry via Hot Electron driven REactions

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EC-Contrib. €

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Project "NANOSPHERE" data sheet

The following table provides information about the project.

Coordinator
THE CHANCELLOR MASTERS AND SCHOLARSOF THE UNIVERSITY OF CAMBRIDGE 

Organization address
address: TRINITY LANE THE OLD SCHOOLS
city: CAMBRIDGE
postcode: CB2 1TN
website: www.cam.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Project website http://www.ch.cam.ac.uk/person/sjb303
 Total cost 183˙454 €
 EC max contribution 183˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2014
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2015
 Duration (year-month-day) from 2015-03-15   to  2017-03-14

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE CHANCELLOR MASTERS AND SCHOLARSOF THE UNIVERSITY OF CAMBRIDGE UK (CAMBRIDGE) coordinator 183˙454.00

Map

 Project objective

The current research proposal aims utilise the unique macrocyclic host guest chemistry of cucurbiturils in conjunction with metal nanoparticles to demonstrate a novel and malleable approach to nanoparticle self-assembly, resulting in structures that will be used in light driven chemical reactions and advanced molecular sensing. This represents an important area of research, for whilst nanoparticles and assembled nanostructures show promise in a wide variety of applications, their uptake into current technologies has stalled due to the difficulty of their production, post-assembly manipulation and chemical loading. This project will demonstrate a new paradigm of functionality and versatility in nanoarchitectures. This will be achieved by assembling nanoparticle structures with a unique group of rigid macrocycle assembly agents, cucurbiturils. Cucurbiturils, with their versatile host-guest complexation chemistry, will allow for post assembly control of nanostructures via multiple external stimuli, while also giving flexibility in terms of application, with many kinds of molecules able to be loaded into the inner cavity of the cucurbiturils, yielding chemical sensing and reactor constructs on the nanoscale. Fundamental insights will be gained into the assembly and manipulation of nanoparticle superstructures, with an eye for application. To this end, Dr. Steven Barrow, the applicant, will work with Dr. Oren Scherman, in collaboration with Prof. Jeremy Baumberg. This linkage represents a unique opportunity to explore nanoscale systems at the University of Cambridge. This project will be highly supported in both the Chemistry department with Dr. Scherman, as well as the Physics department with Prof. Baumberg, at the University of Cambridge. The University of Cambridge is world renowned for its high impact research in the fields of chemistry and physics and this project represents a unique opportunity for collaboration between the two departments.

 Publications

year authors and title journal last update
List of publications.
2016 Rohit Chikkaraddy, Bart de Nijs, Felix Benz, Steven J. Barrow, Oren A. Scherman, Edina Rosta, Angela Demetriadou, Peter Fox, Ortwin Hess, Jeremy J. Baumberg
Single-molecule strong coupling at room temperature in plasmonic nanocavities
published pages: 127-130, ISSN: 0028-0836, DOI: 10.1038/nature17974
Nature 535/7610 2019-07-24
2015 Steven J. Barrow, Setu Kasera, Matthew J. Rowland, Jesús del Barrio, Oren A. Scherman
Cucurbituril-Based Molecular Recognition
published pages: 12320-12406, ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.5b00341
Chemical Reviews 115/22 2019-07-24
2016 Chenyan Liu,a Guolei Xiang, Yuchao Wu, Steven J. Barrow, Matthew J. Rowland, David E. Clarke, Guanglu Wu and Oren A. Scherman
Hybrid organic–inorganic supramolecular hydrogel reinforced with CePO4 nanowires
published pages: , ISSN: 1759-9954, DOI: 10.1039/C6PY01127F
Polymer Chemistry 2019-07-24
2016 Samuel T. Jones, Zarah Walsh-Korb, Steven J. Barrow, Sarah L. Henderson, Jesús del Barrio, and Oren A. Scherman
The Importance of Excess Poly(N-isopropylacrylamide) for the Aggregation of Poly(N-isopropylacrylamide)-Coated Gold Nanoparticles
published pages: , ISSN: 1936-086X, DOI: 10.1021/acsnano.5b04083
ACS Nano 2019-07-24
2016 Steven J. Barrow, Setu Kasera, Matthew J. Rowland, Jesús del Barrio, Oren A. Scherman
Correction to Cucurbituril-Based Molecular Recognition
published pages: 12651-12652, ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.6b00577
Chemical Reviews 116/19 2019-07-24

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