Explore the words cloud of the CoopClickCat project. It provides you a very rough idea of what is the project "CoopClickCat" about.
The following table provides information about the project.
UNIVERSITY COLLEGE DUBLIN, NATIONAL UNIVERSITY OF IRELAND, DUBLIN
|Coordinator Country||Ireland [IE]|
|Total cost||175˙866 €|
|EC max contribution||175˙866 € (100%)|
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
|Duration (year-month-day)||from 2015-04-01 to 2017-03-31|
Take a look of project's partnership.
|1||UNIVERSITY COLLEGE DUBLIN, NATIONAL UNIVERSITY OF IRELAND, DUBLIN||IE (DUBLIN)||coordinator||175˙866.00|
The CoopClickCat project features Cooperatively operating Click-derived ruthenium Catalysts for the efficient oxidation of organic and inorganic substrates with high rates and turnover numbers. For this purpose, triazolylidene ligands, which are readily available through click-chemistry, will be functionalized with a cooperative donor site for improving the catalytic activity of the bound ruthenium center. The ligand design involves a sterically constraint position of the donor site, thus preventing this group from coordination to the metal center. The availability of a Lewis acid (ruthenium center) and base in a confined arrangement will enable the two sites to act cooperatively, thus providing access to concerted proton and electron transfer processes. This synergistic behavior lowers activation barriers and hence leads to a smoother potential energy surface for reduction and oxidation reactions. This unique arrangement will lead to new oxidative coupling processes and reduction pathways for the activation of abundant starting materials such as alcohols and amines, and eventually also water to reach unprecedented activity in ruthenium-catalyzed water oxidation catalysis. This project efficiently combines expertise of the researcher (Dr. Marta Valencia; hydride chemistry, alcohol oxidation) with core competences of the host lab (Professor Martin Albrecht, University College Dublin; triazolylidene chemistry, water oxidation).
|year||authors and title||journal||last update|
Marta Valencia, Helge M?ller-Bunz, Robert A. Gossage, Martin Albrecht
Enhanced product selectivity promoted by remote metal coordination in acceptor-free alcohol dehydrogenation catalysis
published pages: 3344-3347, ISSN: 1359-7345, DOI: 10.1039/C6CC00267F
|Chem. Commun. 52/16||2019-07-24|
Marta Valencia, Ana Pereira, Helge M?ller-Bunz, Tom?s R. Belderra?n, Pedro J. P?rez, Martin Albrecht
Triazolylidene-Iridium Complexes with a Pendant Pyridyl Group for Cooperative Metal-Ligand Induced Catalytic Dehydrogenation of Amines
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201700676
|Chemistry - A European Journal||2019-07-24|
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The information about "COOPCLICKCAT" are provided by the European Opendata Portal: CORDIS opendata.
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