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SUPRACOPHS TERMINATED

Design and synthesis of supramolecular copolymers for responsive self-assembled photonic structures.

Total Cost €

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EC-Contrib. €

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Partnership

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Project "SUPRACOPHS" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITE DE FRIBOURG 

Organization address
address: AVENUE DE L EUROPE 20
city: FRIBOURG
postcode: 1700
website: www.unifr.ch

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Switzerland [CH]
 Project website http://ami.swiss
 Total cost 175˙419 €
 EC max contribution 175˙419 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2016
 Duration (year-month-day) from 2016-09-01   to  2018-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITE DE FRIBOURG CH (FRIBOURG) coordinator 175˙419.00

Map

 Project objective

Based on the reversible bonds that hold the structural units together, supramolecular polymers gain technological relevance from the simplicity of their synthesis, while a constantly increasing amount of research is dedicated to the study of the unique solution, electronic, mechanical and rheological properties of these materials. An interesting aspect of these properties may arise when the use of such polymers in photonic structures is considered. Optical properties, such as reflectivity, polarization, iridescence, and transmission, rely on the spatial arrangement of the components of nano- and micro- structures and are a direct result of their refractive index mismatch and their wavelength scale periodicity that constructively or destructively interacts with the incident light. While the use of traditional block copolymers has been extensively reported in the literature, a leap forward in the accessible properties requires high molecular weight polymers that add complexity and significantly increase processing timescales due to chain entanglements. Herein we propose the use of supramolecular block (co)polymers with highly dynamic interactions that can circumvent such constraints. We intend to study the effect of polymer composition, molecular weight, and architecture on the periodic structure scale in order to achieve a fine balance between interaction and segregation of the polymer chains and obtain the desired periodic structures, such as double gyroids.

 Publications

year authors and title journal last update
List of publications.
2017 Lucas Montero de Espinosa, Worarin Meesorn, Dafni Moatsou, Christoph Weder
Bioinspired Polymer Systems with Stimuli-Responsive Mechanical Properties
published pages: 12851-12892, ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.7b00168
Chemical Reviews 117/20 2019-06-13

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