Opendata, web and dolomites


Low Coordinate Transition Metal Single Molecule Magnets

Total Cost €


EC-Contrib. €






 LoCo project word cloud

Explore the words cloud of the LoCo project. It provides you a very rough idea of what is the project "LoCo" about.

stabilise    utilise    quantum    alongside    mike    ring    coordinate    electronic    molecule    probe    bath    mkw    prof    fellow    computing    multidisciplinary    rationale    environments    considerable    geometry    storage    until    synthetic    fe    benefits    mev    exposure    murphy    2013    opportunity    periods    germany    size    resonance    nhc    powell    mevs    stuart    university    sam    influence    whittlesey    group    outlines    ni    organotransition    uk    macgregor    paramagnetic    molecular    carbene    compounds    heterocyclic    internationally    espinal    focussed    skills    dmm    progression    host    electron    cationic    co    mode    laboratories    annie    magnetic    techniques    akp    paramagnetism    ligands    secondment    smm    watt    density    smms    exhibited    realisation    maialen    substituents    complexes    career    damien    geometries    karlsruhe    report    behavior    metal    ing    mkws    mononuclear    computational    investigations    lanthanides    single    cardiff    first    heriot    magnets    chemistry    magnetism   

Project "LoCo" data sheet

The following table provides information about the project.


Organization address
city: BATH
postcode: BA2 7AY

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Project website
 Total cost 183˙454 €
 EC max contribution 183˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2015
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-02-13   to  2019-08-27


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITY OF BATH UK (BATH) coordinator 183˙454.00


 Project objective

The Fellow, Maialen Espinal (MEV) from the University of Bath, outlines a case for support to work alongside the Host, Prof Mike Whittlesey (MKW: University of Bath, UK), on the design of novel two-coordinate complexes of Ni, Co and Fe as single molecule magnets (SMMs).The rationale for the work is the 2013 report by the MKWs group of a cationic Ni(I) N-heterocyclic carbene complex that exhibited the first example of SMM behavior observed in a mononuclear Ni complex. SMMs are the focus of considerable multidisciplinary investigations because of their potential for high-density information storage and quantum computing. Most work until now has focussed on lanthanides, but there has been an increasing realisation that organotransition metal derived SMMs may offer significant benefits in terms of their ability to stabilise different electronic environments as a result of being able to adopt unique coordination geometries. MEVs approach will be to use large ring NHC ligands and probe the influence of ring size, substituents, coordination mode and resulting molecular geometry on magnetic behaviour. The project will utilise the research experience of the applicant in synthetic chemistry to make new compounds in Bath, but most importantly, provide her a unique opportunity to develop new skills for progression of her career by exposure to new techniques and methodologies through periods of secondment to internationally leading laboratories for studies of magnetism (Prof Annie Powell (AKP), Karlsruhe, Germany), paramagnetism via Electron Paramagnetic Resonance (Prof Damien Murphy (DMM), Cardiff, UK) and computational chemistry (Prof Stuart Macgregor (SAM), Heriot-Watt, UK).


year authors and title journal last update
List of publications.
2019 Maialen Espinal-Viguri, Victor Varela-Izquierdo, Fedor M. Miloserdov, Ian M. Riddlestone, Mary F. Mahon, Michael K. Whittlesey
Heterobimetallic ruthenium–zinc complexes with bulky N-heterocyclic carbenes: syntheses, structures and reactivity
published pages: 4176-4189, ISSN: 1477-9226, DOI: 10.1039/c8dt05023f
Dalton Transactions 48/13 2020-01-29

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The information about "LOCO" are provided by the European Opendata Portal: CORDIS opendata.

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