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MULTIPROSMM SIGNED

MULtiple PROperties Single Molecule Magnets

Total Cost €

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EC-Contrib. €

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Partnership

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Project "MULTIPROSMM" data sheet

The following table provides information about the project.

Coordinator
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS 

Organization address
address: RUE MICHEL ANGE 3
city: PARIS
postcode: 75794
website: www.cnrs.fr

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country France [FR]
 Total cost 1˙505˙000 €
 EC max contribution 1˙505˙000 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2016-COG
 Funding Scheme ERC-COG
 Starting year 2017
 Duration (year-month-day) from 2017-08-01   to  2022-07-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS FR (PARIS) coordinator 1˙382˙500.00
2    EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZUERICH CH (ZUERICH) participant 122˙500.00

Map

 Project objective

The goal of the MULTIPROSMM project is to design systems able to present magnetic bistabilities under different stimuli (temperature, magnetic field or light) on an unprecedented large temperature range, i.e. very low temperature with Single Molecule Magnet (SMM) behaviour, intermediate temperature with Light Induced Excited State Trapping (LIESST) and high temperature with SpinCrossOver (SCO). On one hand, as a photography of the energy-splitting of the spectroscopic states, the lanthanide luminescence will be used as a key tool for the understanding of the magnetic properties of lanthanide ions. On the other hand, Circularly Polarized Luminescence (CPL) combines the sensitivity of the luminescence with crucial information on the chiral environment. A step by step synthetic strategy will be used to elaborate molecular systems in which the coexistence of i) SMM and SCO; ii) SMM and CPL and iii) SMM, SCO and CPL are operating. The enhancement of the magnetic properties is needed to step forward towards applications. To reach such optimizations, the quantum regime of the SMM and the internal magnetic field must be vanished playing with the hyperfine coupling and magnetic dilutions. Both isotopic enrichment and shaping (i.e. decoration of both mesoporous silica and nanoparticle surfaces) of the designed systems could allow high magnetic performance in multiple properties SMM. The final result could be a system suitable for very high density data storage on a wide temperature range (from cryogenic to room temperature).

 Publications

year authors and title journal last update
List of publications.
2019 Guglielmo Fernandez Garcia, Vincent Montigaud, Lucie Norel, Olivier Cador, Boris Le Guennic, Federico Totti, Fabrice Pointillart
Redox-Active Dysprosium Single-Molecule Magnet: Spectro-Electrochemistry and Theoretical Investigations
published pages: 46, ISSN: 2312-7481, DOI: 10.3390/magnetochemistry5030046
Magnetochemistry 5/3 2020-02-13
2020 Bertrand Lefeuvre, Jessica Flores Gonzalez, Frédéric Gendron, Vincent Dorcet, François Riobé, Vladimir Cherkasov, Olivier Maury, Boris Le Guennic, Olivier Cador, Viacheslav Kuropatov, Fabrice Pointillart
Redox-Modulations of Photophysical and Single-molecule Magnet Properties in Ytterbium Complexes Involving Extended-TTF Triads
published pages: 492, ISSN: 1420-3049, DOI: 10.3390/molecules25030492
Molecules 25/3 2020-02-13
2019 Olivier Cador, Boris Le Guennic, Fabrice Pointillart
Electro-activity and magnetic switching in lanthanide-based single-molecule magnets
published pages: 3398-3417, ISSN: 2052-1553, DOI: 10.1039/c9qi00875f
Inorganic Chemistry Frontiers 6/12 2020-02-13
2020 Olivier Cador, Boris Le Guennic, Lahcène Ouahab, Fabrice Pointillart
Decorated Tetrathiafulvalene-Based Ligands: Powerful Chemical Tools for the Design of Single-Molecule Magnets
published pages: 148-164, ISSN: 1434-1948, DOI: 10.1002/ejic.201900981
European Journal of Inorganic Chemistry 2020/2 2020-02-13
2018 Bertrand Lefeuvre, Olivier Galangau, Jessica Flores Gonzalez, Vincent Montigaud, Vincent Dorcet, Lahcène Ouahab, Boris Le Guennic, Olivier Cador, Fabrice Pointillart
Field-Induced Dysprosium Single-Molecule Magnet Based on a Redox-Active Fused 1,10-Phenanthroline-Tetrathiafulvalene-1,10-Phenanthroline Bridging Triad
published pages: , ISSN: 2296-2646, DOI: 10.3389/fchem.2018.00552
Frontiers in Chemistry 6 2019-10-08
2018 Haiet Douib, Louis Cornet, Jessica Flores Gonzalez, Elzbieta Trzop, Vincent Dorcet, Abdelkrim Gouasmia, Lahcène Ouahab, Olivier Cador, Fabrice Pointillart
Spin-Crossover and Field-Induced Single-Molecule Magnet Behaviour in Metal(II)-Dipyrazolylpyridine Complexes
published pages: 4452-4457, ISSN: 1434-1948, DOI: 10.1002/ejic.201800819
European Journal of Inorganic Chemistry 2018/40 2019-10-08
2019 Balkaran Singh Sran, Jessica Flores Gonzalez, Vincent Montigaud, Boris Le Guennic, Fabrice Pointillart, Olivier Cador, Geeta Hundal
Structural and magnetic investigations of a binuclear coordination compound of dysprosium( iii ) dinitrobenzoate
published pages: , ISSN: 1477-9226, DOI: 10.1039/c8dt04253e
Dalton Transactions 2019-10-08
2019 Frédéric Gendron, Barry Moore II, Olivier Cador, Fabrice Pointillart, Jochen Autschbach, Boris Le Guennic
Ab Initio Study of Circular Dichroism and Circularly Polarized Luminescence of Spin-Allowed and Spin-Forbidden Transitions: From Organic Ketones to Lanthanide Complexes
published pages: 4140-4155, ISSN: 1549-9618, DOI: 10.1021/acs.jctc.9b00286
Journal of Chemical Theory and Computation 15/7 2019-09-02
2018 Jessica Flores Gonzalez, Vincent Montigaud, Nidal Saleh, Olivier Cador, Jeanne Crassous, Boris le Guennic, Fabrice Pointillart
Slow Relaxation of the Magnetization in Bis-Decorated Chiral Helicene-Based Coordination Complexes of Lanthanides
published pages: 39, ISSN: 2312-7481, DOI: 10.3390/magnetochemistry4030039
Magnetochemistry 4/3 2019-06-12
2018 Jessica Flores Gonzalez, Olivier Cador, Lahcène Ouahab, Sergey Norkov, Viacheslav Kuropatov, Fabrice Pointillart
Field-Induced Dysprosium Single-Molecule Magnet Involving a Fused o-Semiquinone-Extended-Tetrathiafulvalene-o-Semiquinone Bridging Triad
published pages: 45, ISSN: 2304-6740, DOI: 10.3390/inorganics6020045
Inorganics 6/2 2019-06-12
2019 Olivier Galangau, Vincent Montigaud, Jessica Flores Gonzalez, Bertrand Lefeuvre, Vincent Dorcet, Boris Le Guennic, Olivier Cador, Lahcène Ouahab, Fabrice Pointillart
N3O6 versus N2O6 Coordinated Dysprosium Slow Magnetic Relaxation in a Tetrathiafulvalene-Based Dinuclear Complex
published pages: , ISSN: 0277-5387, DOI: 10.1016/j.poly.2019.04.029
Polyhedron 2019-06-06
2019 Jessica Flores Gonzalez, Fabrice Pointillart, Olivier Cador
Hyperfine coupling and slow magnetic relaxation in isotopically enriched Dy III mononuclear single-molecule magnets
published pages: 1081-1086, ISSN: 2052-1553, DOI: 10.1039/c8qi01209a
Inorganic Chemistry Frontiers 6/4 2019-06-06
2018 Fabrice Pointillart, Jiang-Kun Ou-Yang, Guglielmo Fernandez Garcia, Vincent Montigaud, Jessica Flores Gonzalez, Rémi Marchal, Ludovic Favereau, Federico Totti, Jeanne Crassous, Olivier Cador, Lahcène Ouahab, Boris Le Guennic
Tetrathiafulvalene-Based Helicene Ligand in the Design of a Dysprosium Field-Induced Single-Molecule Magnet
published pages: , ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.8b02830
Inorganic Chemistry 2019-04-25

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