Explore the words cloud of the TWOSENS project. It provides you a very rough idea of what is the project "TWOSENS" about.
The following table provides information about the project.
UNIVERZITA KOMENSKEHO V BRATISLAVE
|Coordinator Country||Slovakia [SK]|
|Total cost||153˙381 €|
|EC max contribution||153˙381 € (100%)|
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
|Duration (year-month-day)||from 2018-01-01 to 2019-12-31|
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|1||UNIVERZITA KOMENSKEHO V BRATISLAVE||SK (BRATISLAVA)||coordinator||153˙381.00|
Materials exhibiting large two-photon absorption (TPA) are in great demand to meet the needs of emerging laser technologies and applications in medicine and biomedical engineering (bioimaging, photodynamic therapy, microfabrication). Most design strategies to enhance TPA activity rely on construction of extremely large pi-conjugated molecules, which are not appreciated in practice due to difficulties connected with their synthesis or low cell permeability. The fellow recently demonstrated that significant TPA enhancement can be achieved by small perturbations in the heteroaromatic unit, but these effects are often hardly predictable or chemically counter-intuitive. The objective of this action is to provide material chemists with general guidelines for construction of heteroaromatic-based sensitizers and their metal complexes displaying very high TPA within a confined chromophore space. This will allow to avoid trial-and-error experimentation done so far. A systematic computational study of TPA cross-sections using state-of-the-art quantum-chemical methods for a large set of different heteroarene platforms and substitution patterns will furnish essential structure-property relationships and their understanding based on extensive analysis will bring new knowledge for boosting the TPA efficiency. The most promising candidates will be synthesized and their efficiency will be demonstrated in real applications. The HI and International Laser Center offer excellent multidisciplinary research environment and enable the fellow an access to their unique expertise in highly accurate electronic structure methods and instrumentation. In return, the fellow will bring his unique combined experience in computer simulations and synthesis of nonlinear optical materials as well as new collaborators from Germany, Switzerland, Belgium and Greece. The project boosts the fellow’s research skills in materials chemistry and enables him to start his independent research career in Slovakia.
|year||authors and title||journal||last update|
Kimberly C. Mullane, Peter HrobÃ¡rik, Thibault Cheisson, Brian C. Manor, Patrick J. Carroll, Eric J. Schelter
13 C NMR Shifts as an Indicator of Uâ€“C Bond Covalency in Uranium(VI) Acetylide Complexes: An Experimental and Computational Study
published pages: 4152-4163, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.8b03175
|Inorganic Chemistry 58/7||2020-02-13|
Andrew W. Cook, Peter HrobÃ¡rik, Peter L. Damon, Guang Wu, Trevor W. Hayton
A Ketimide-Stabilized Palladium Nanocluster with a Hexagonal Aromatic Pd 7 Core
published pages: 1471-1480, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.9b03276
|Inorganic Chemistry 59/2||2020-02-13|
Luca Rocchigiani, Julio Fernandez-Cestau, Isabelle Chambrier, Peter HrobÃ¡rik, Manfred Bochmann
Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis / trans -Influence on Stability, Insertion Chemistry, and NMR Chemical Shifts
published pages: 8287-8302, ISSN: 0002-7863, DOI: 10.1021/jacs.8b04478
|Journal of the American Chemical Society 140/26||2020-02-13|
Marissa Ringgold, David Rehe, Peter HrobÃ¡rik, Anna Y. Kornienko, Thomas J. Emge, John G. Brennan
Thorium Cubanesâ€“Synthesis, Solid-State and Solution Structures, Thermolysis, and Chalcogen Exchange Reactions
published pages: 7129-7141, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.8b00836
|Inorganic Chemistry 57/12||2020-02-13|
Kostas Seintis, Ã‡iÇ§dem Åžahin, Ivica SigmundovÃ¡, Elias Stathatos, Peter HrobÃ¡rik, Mihalis Fakis
Solvent-Acidity-Driven Change in Photophysics and Significant Efficiency Improvement in Dye-Sensitized Solar Cells of a Benzothiazole-Derived Organic Sensitizer
published pages: 20122-20134, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.8b05686
|The Journal of Physical Chemistry C 122/35||2020-02-13|
Andrew W. Cook, Peter HrobÃ¡rik, Peter L. Damon, Daniel Najera, Branislav HorvÃ¡th, Guang Wu, Trevor W. Hayton
Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex
published pages: 15927-15935, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.9b02443
|Inorganic Chemistry 58/23||2020-02-13|
Julien Fuchs, Elisabeth Irran, Peter HrobÃ¡rik, Hendrik F. T. Klare, Martin Oestreich
Siâ€“H Bond Activation with Bullockâ€™s Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand
published pages: 18845-18850, ISSN: 0002-7863, DOI: 10.1021/jacs.9b10304
|Journal of the American Chemical Society 141/47||2020-02-13|
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