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WHIPCAT SIGNED

van der Waals Heterostructures for Innovative PhotoCATalysts

Total Cost €

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EC-Contrib. €

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Partnership

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 WHIPCAT project word cloud

Explore the words cloud of the WHIPCAT project. It provides you a very rough idea of what is the project "WHIPCAT" about.

der    kinetics    deposition    physico    optical    magnetron    fabrication    absorption    dichalcogenides    pristine    sweep    sputtering    indirect    combinatorial    gas    immense    onto    combinations    scientific    reaction    crystals    waals    oer    bandgap    possibilities    visible    vdw    tms    layered    termination    variety    mo    deposit    evolution    clusters    light    basic    photoluminescence    drastic    atomic    metal    contrasts    cyclic    pl    catalysis    van    mechanical    photophysical    chemical    heterogeneous    pec    te    se    engineering    substrates    electrochemical    community    cs    electro    solids    orr    candidates    oxygen    dependent    transition    chalcogenide    layer    stmd    2d    dimensional    linear    contrast    cluster    photo    photocatalysis    acidic    source    largely    dual    size    materials    electronic    environmental    stacked    spectroscopy    tm    receiving    electrolytes    efficient    direct    nanoclusters    energy    raman    voltammetry    semiconducting    stark    layers    tuning    edge    photocatatlytic    atomically    stacking    beam    condensation    dark    photoconductivity    bulk   

Project "WHIPCAT" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF BIRMINGHAM 

Organization address
address: Edgbaston
city: BIRMINGHAM
postcode: B15 2TT
website: www.bham.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Total cost 183˙454 €
 EC max contribution 183˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-09-01   to  2019-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF BIRMINGHAM UK (BIRMINGHAM) coordinator 183˙454.00

Map

 Project objective

Engineering of atomic (two-dimensional (2D)) layered solids is receiving immense attention from the scientific community due to the possibilities of tuning the optical, mechanical, electronic and electrochemical properties by combinatorial stacking of different atomic layers as novel candidates for energy and environmental applications. Van der Waals solids (vdW) of Semiconducting Transition Metal Dichalcogenides (STMD) have been largely investigating 2D materials, where its physico-chemical properties show a drastic contrast in comparison to its bulk. Visible light absorption, indirect to direct bandgap transition, layer dependent photoluminescence (PL) etc. are some of the stark contrasts in atomically layered STMD vdW crystals from bulk, making them unique for photocatalysis and photo-(electro) catalysis (PEC) applications. In this work, Fabrication of variety of novel heterogeneous STMD clusters with combinations of different transition metal (TM): Mo, W and V and chalcogenide (C): S, Se and Te by cluster beam deposition will be carried out for the efficient visible light photocatalysis and PEC applications. Size and edge termination dependent photophysical properties will be investigated and further implemented for the efficient visible light PEC from this kind of vdW solids. A dual-target, magnetron-sputtering gas condensation cluster source will be used to deposit pristine combinatorial stacked nanoclusters of TMs and Cs onto various substrates. The photocatatlytic reaction kinetics will be estimated from the visible light absorption, Raman/PL spectroscopy and photoconductivity studies. Further PEC activity towards HER/oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) from the STMD vdW nanoclusters will be evaluated from linear sweep voltammetry and cyclic voltammetry in acidic and basic electrolytes in dark and light conditions.

 Publications

year authors and title journal last update
List of publications.
2018 Kamal Kumar Paul, N. Sreekanth, Ravi K. Biroju, Alexander J. Pattison, Daniel Escalera-López, Anku Guha, Tharangattu N. Narayanan, Neil Vaughan Rees, Wolfgang Theis, P. K. Giri
Strongly enhanced visible light photoelectrocatalytic hydrogen evolution reaction in an n-doped MoS 2 /TiO 2 (B) heterojunction by selective decoration of platinum nanoparticles at the MoS 2 edge sites
published pages: 22681-22696, ISSN: 2050-7488, DOI: 10.1039/c8ta06783j
Journal of Materials Chemistry A 6/45 2019-11-08

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