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WHIPCAT SIGNED

van der Waals Heterostructures for Innovative PhotoCATalysts

Total Cost €

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EC-Contrib. €

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Partnership

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 WHIPCAT project word cloud

Explore the words cloud of the WHIPCAT project. It provides you a very rough idea of what is the project "WHIPCAT" about.

linear    electrochemical    van    tms    dark    photocatalysis    bulk    atomic    waals    drastic    possibilities    electronic    dimensional    onto    fabrication    te    stacking    termination    deposition    physico    combinations    tuning    chemical    scientific    layer    deposit    tm    sputtering    immense    catalysis    variety    photoluminescence    substrates    largely    size    beam    atomically    photophysical    magnetron    layers    crystals    candidates    mechanical    layered    transition    electro    visible    kinetics    contrast    mo    metal    indirect    pristine    environmental    raman    nanoclusters    acidic    energy    dual    oxygen    community    photoconductivity    photocatatlytic    se    orr    spectroscopy    dependent    vdw    basic    dichalcogenides    chalcogenide    clusters    stacked    sweep    direct    semiconducting    evolution    engineering    condensation    source    2d    cyclic    electrolytes    optical    cs    cluster    absorption    materials    edge    stmd    bandgap    voltammetry    der    solids    combinatorial    pl    efficient    photo    reaction    oer    light    contrasts    gas    pec    heterogeneous    stark    receiving   

Project "WHIPCAT" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF BIRMINGHAM 

Organization address
address: Edgbaston
city: BIRMINGHAM
postcode: B15 2TT
website: www.bham.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Total cost 183˙454 €
 EC max contribution 183˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-09-01   to  2019-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF BIRMINGHAM UK (BIRMINGHAM) coordinator 183˙454.00

Map

 Project objective

Engineering of atomic (two-dimensional (2D)) layered solids is receiving immense attention from the scientific community due to the possibilities of tuning the optical, mechanical, electronic and electrochemical properties by combinatorial stacking of different atomic layers as novel candidates for energy and environmental applications. Van der Waals solids (vdW) of Semiconducting Transition Metal Dichalcogenides (STMD) have been largely investigating 2D materials, where its physico-chemical properties show a drastic contrast in comparison to its bulk. Visible light absorption, indirect to direct bandgap transition, layer dependent photoluminescence (PL) etc. are some of the stark contrasts in atomically layered STMD vdW crystals from bulk, making them unique for photocatalysis and photo-(electro) catalysis (PEC) applications. In this work, Fabrication of variety of novel heterogeneous STMD clusters with combinations of different transition metal (TM): Mo, W and V and chalcogenide (C): S, Se and Te by cluster beam deposition will be carried out for the efficient visible light photocatalysis and PEC applications. Size and edge termination dependent photophysical properties will be investigated and further implemented for the efficient visible light PEC from this kind of vdW solids. A dual-target, magnetron-sputtering gas condensation cluster source will be used to deposit pristine combinatorial stacked nanoclusters of TMs and Cs onto various substrates. The photocatatlytic reaction kinetics will be estimated from the visible light absorption, Raman/PL spectroscopy and photoconductivity studies. Further PEC activity towards HER/oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) from the STMD vdW nanoclusters will be evaluated from linear sweep voltammetry and cyclic voltammetry in acidic and basic electrolytes in dark and light conditions.

 Publications

year authors and title journal last update
List of publications.
2018 Kamal Kumar Paul, N. Sreekanth, Ravi K. Biroju, Alexander J. Pattison, Daniel Escalera-López, Anku Guha, Tharangattu N. Narayanan, Neil Vaughan Rees, Wolfgang Theis, P. K. Giri
Strongly enhanced visible light photoelectrocatalytic hydrogen evolution reaction in an n-doped MoS 2 /TiO 2 (B) heterojunction by selective decoration of platinum nanoparticles at the MoS 2 edge sites
published pages: 22681-22696, ISSN: 2050-7488, DOI: 10.1039/c8ta06783j
Journal of Materials Chemistry A 6/45 2019-11-08

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