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WHIPCAT SIGNED

van der Waals Heterostructures for Innovative PhotoCATalysts

Total Cost €

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EC-Contrib. €

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Partnership

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 WHIPCAT project word cloud

Explore the words cloud of the WHIPCAT project. It provides you a very rough idea of what is the project "WHIPCAT" about.

van    stacked    crystals    immense    atomic    indirect    chemical    waals    acidic    raman    layer    photocatalysis    largely    chalcogenide    candidates    catalysis    te    tm    dimensional    scientific    semiconducting    pec    oer    clusters    stacking    cs    magnetron    combinations    physico    mechanical    atomically    electrochemical    voltammetry    dual    photoconductivity    bandgap    orr    materials    spectroscopy    vdw    deposit    size    kinetics    electronic    photo    sweep    der    dark    gas    tuning    possibilities    fabrication    drastic    cluster    bulk    efficient    tms    photoluminescence    variety    stark    pristine    community    cyclic    absorption    optical    direct    engineering    se    dichalcogenides    linear    solids    environmental    oxygen    energy    dependent    evolution    layers    receiving    visible    contrasts    reaction    metal    light    nanoclusters    photophysical    pl    deposition    electro    basic    combinatorial    layered    onto    mo    contrast    transition    sputtering    electrolytes    2d    substrates    photocatatlytic    edge    beam    stmd    condensation    termination    heterogeneous    source   

Project "WHIPCAT" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF BIRMINGHAM 

Organization address
address: Edgbaston
city: BIRMINGHAM
postcode: B15 2TT
website: www.bham.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Total cost 183˙454 €
 EC max contribution 183˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-09-01   to  2019-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF BIRMINGHAM UK (BIRMINGHAM) coordinator 183˙454.00

Map

 Project objective

Engineering of atomic (two-dimensional (2D)) layered solids is receiving immense attention from the scientific community due to the possibilities of tuning the optical, mechanical, electronic and electrochemical properties by combinatorial stacking of different atomic layers as novel candidates for energy and environmental applications. Van der Waals solids (vdW) of Semiconducting Transition Metal Dichalcogenides (STMD) have been largely investigating 2D materials, where its physico-chemical properties show a drastic contrast in comparison to its bulk. Visible light absorption, indirect to direct bandgap transition, layer dependent photoluminescence (PL) etc. are some of the stark contrasts in atomically layered STMD vdW crystals from bulk, making them unique for photocatalysis and photo-(electro) catalysis (PEC) applications. In this work, Fabrication of variety of novel heterogeneous STMD clusters with combinations of different transition metal (TM): Mo, W and V and chalcogenide (C): S, Se and Te by cluster beam deposition will be carried out for the efficient visible light photocatalysis and PEC applications. Size and edge termination dependent photophysical properties will be investigated and further implemented for the efficient visible light PEC from this kind of vdW solids. A dual-target, magnetron-sputtering gas condensation cluster source will be used to deposit pristine combinatorial stacked nanoclusters of TMs and Cs onto various substrates. The photocatatlytic reaction kinetics will be estimated from the visible light absorption, Raman/PL spectroscopy and photoconductivity studies. Further PEC activity towards HER/oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) from the STMD vdW nanoclusters will be evaluated from linear sweep voltammetry and cyclic voltammetry in acidic and basic electrolytes in dark and light conditions.

 Publications

year authors and title journal last update
List of publications.
2018 Kamal Kumar Paul, N. Sreekanth, Ravi K. Biroju, Alexander J. Pattison, Daniel Escalera-López, Anku Guha, Tharangattu N. Narayanan, Neil Vaughan Rees, Wolfgang Theis, P. K. Giri
Strongly enhanced visible light photoelectrocatalytic hydrogen evolution reaction in an n-doped MoS 2 /TiO 2 (B) heterojunction by selective decoration of platinum nanoparticles at the MoS 2 edge sites
published pages: 22681-22696, ISSN: 2050-7488, DOI: 10.1039/c8ta06783j
Journal of Materials Chemistry A 6/45 2019-11-08

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