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CASCADE-X

CO2 to light olefins conversion by cascade reactions over bifunctional nanocatalysts: an ‘all X-ray’ approach

Total Cost €

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EC-Contrib. €

0

Partnership

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 CASCADE-X project word cloud

Explore the words cloud of the CASCADE-X project. It provides you a very rough idea of what is the project "CASCADE-X" about.

ultimate    deactivation    perspective    conversion    building    zeotype    onto    catalysts    stability    physico    diversify    olefins    optimization    ray    structural    platform    dynamics    reactor    mechanisms    fundamental    trans    individual    resolved    proposes    diffraction    bi    situ    molecular    simplified    company    modal    synchrotron    rational    sectoral    selective    restructuring    private    phenomena    petrochemical    space    operando    overcoming    alloy    generate    action    competences    sustainable    representing    scattering    sequential    industry    spectroscopy    host    combined    confinement    elucidate    selectivity    metal    light    integrating    relationships    nano    hydrogenation    performances    source    secondment    absorption    catalyst    convert    thermodynamic    synthesis    reaction    transfer    integration    chemistry    co2    particles    single    scheme    manufacturing    waste    descriptors    synergizing    provides    precious    complementary    methanol    functional    pursued    goals    carbon    facility    industrial    recycling    laboratory    cascade    chemical    bifunctional    restrictions    combination    excellence    active    proponent    blocks    mapping    reactions   

Project "CASCADE-X" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITETET I OSLO 

Organization address
address: PROBLEMVEIEN 5-7
city: OSLO
postcode: 313
website: www.uio.no

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Norway [NO]
 Project website https://www.mn.uio.no/kjemi/english/research/groups/catalysis/research/cascade-x.html
 Total cost 196˙400 €
 EC max contribution 196˙400 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-07-01   to  2020-06-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITETET I OSLO NO (OSLO) coordinator 196˙400.00

Map

 Project objective

In a waste-to-value perspective, CO2 can represent a sustainable carbon source to produce light olefins, representing key building blocks for petrochemical industry. CASCADE-X proposes an ultimate approach to directly convert CO2 to light olefins through cascade reactions over a bi-functional catalyst, obtained by molecular scale integration of an active metal alloy for the CO2-to-methanol reaction onto a zeotype catalyst for selective methanol-to-olefins conversion. Such a single-reactor cascade approach enables a simplified process scheme while overcoming the thermodynamic restrictions of the methanol synthesis by its sequential conversion. The action will generate fundamental knowledge on properties-performances relationships for the combined system, providing a rational for the optimization of catalyst and process conditions, as well as an improved understanding of key fundamental issues in both hydrogenation and methanol-to-olefins chemistry (restructuring, deactivation mechanisms, confinement effects). These goals will be pursued by an ‘all-X-ray’ approach, synergizing in situ and operando X-ray absorption spectroscopy and diffraction/scattering at the laboratory and large-scale facility level in combination with complementary physico-chemical methods, to identify activity/selectivity/stability descriptors for the bifunctional catalyst. Multi-modal synchrotron nano-mapping of individual catalyst particles will elucidate the space-resolved dynamics of restructuring and deactivation phenomena. Integrating the applicant’s experience in X-ray spectroscopy, the Host’s excellence in structural analysis, testing and rational optimization of zeotype catalysts, as well as the industrial know-how of the private sector partner (a leading Company in recycling and manufacturing precious metal catalysts, where a Secondment is planned), CASCADE-X provides a unique platform to diversify the proponent’s individual competences and to promote trans-sectoral knowledge transfer.

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