Opendata, web and dolomites

Gold3Cat SIGNED

(P,C) and (O,O) well-defined gold(III) complexes for the development of new gold(III) catalytic processes

Total Cost €

0

EC-Contrib. €

0

Partnership

0

Views

0

 Gold3Cat project word cloud

Explore the words cloud of the Gold3Cat project. It provides you a very rough idea of what is the project "Gold3Cat" about.

advantage    wp3    stable    construction    enhanced    carbene    complexes    career    activation    leads    chelate    unprecedented    gold3cat    electrophilicity    dynamism    conceptually    facet    personal    judicious    wp4    consist    selectivity    transformations    induction    preparing    limitations    versions    species    optimization    efforts    independent    wp2    reactivity    plan    featuring    impart    library    scientific    hydroarylation    thoroughly    comparatively    broad    catechol    switching    elaborate    researcher    combines    wp1    over    synthetically    molecules    training    foundations    completely    poorly    limited    pi    last    rational    organometallic    reactive    electronic    chelated    solid    ideal    pincer    functionalized    asymmetric    host    efficient    start    rapid    group    envisions    planar    offers    catalysis    thanks    geometry    rarity    chiral    stabilize    showed    mainly    au    square    prepare    concentrate    catalytic    moiety    ligands    ligand    first    gold   

Project "Gold3Cat" data sheet

The following table provides information about the project.

Coordinator
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS 

Organization address
address: RUE MICHEL ANGE 3
city: PARIS
postcode: 75794
website: www.cnrs.fr

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country France [FR]
 Total cost 173˙076 €
 EC max contribution 173˙076 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-10-01   to  2020-09-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS FR (PARIS) coordinator 173˙076.00

Map

 Project objective

Over the last 20 years, gold catalysis has become a very efficient method for the rapid construction of complex and highly functionalized molecules. However, gold catalysis is mainly limited to the activation of π-systems by Au(I) complexes. Comparatively, Au(III) catalysis is poorly developed due to the rarity of stable but reactive Au(III) complexes. But recent studies showed that judicious ligand design enables to stabilize Au(III) complexes and that switching from Au(I) to Au(III) leads to completely different reactivity and selectivity.

The Gold3Cat project envisions to elaborate a library of well-defined Au(III) complexes and to develop a new facet of gold catalysis thanks to the unique properties of these Au(III) complexes. The first step will consist in preparing a range of stable Au(III) complexes relevant to catalysis (WP1). P-Based chelate and pincer complexes are proposed, as well as (O,O) chelated complexes featuring a catechol moiety. The electronic properties of the new Au(III) complexes will be thoroughly studied to enable rational catalytic development and optimization. Given its importance but current limitations, efforts will concentrate on hydroarylation (WP2). This includes asymmetric versions in which the square-planar geometry of Au(III) should impart enhanced chiral induction (WP3). The ability of P-based pincer ligands to stabilize Au(III) carbene complexes will also be studied, and catalytic transformations taking advantage of the high electrophilicity of these unprecedented species are targeted (WP4).

The Gold3Cat project is very ambitious both synthetically and conceptually, but it is built on solid foundations. It combines ligand design, advanced organometallic studies and important catalytic applications. Given the dynamism of the host group and the training plan involving broad scientific and personal development, it offers ideal conditions for the researcher to enhance its potential and prepare to start her independent career.

 Publications

year authors and title journal last update
List of publications.
2020 Rodriguez, Jessica; Adet, Nicolas; Saffon-Merceron, Nathalie; Bourissou, Didier
Au(I)/Au(III)-Catalyzed C-N Coupling
published pages: , ISSN: 1364-548X, DOI:
Chemical Communications 1 2020-03-24
2019 Jessica Rodriguez, Abdallah Zeineddine, E. Daiann Sosa Carrizo, Karinne Miqueu, Nathalie Saffon-Merceron, Abderrahmane Amgoune, Didier Bourissou
Catalytic Au( i )/Au( iii ) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles
published pages: 7183-7192, ISSN: 2041-6520, DOI: 10.1039/c9sc01954e
Chemical Science 10/30 2020-03-24
2020 Jessica Rodriguez, György Szalóki, E. Daiann Sosa Carrizo, Nathalie Saffon-Merceron, Karinne Miqueu, Didier Bourissou
Gold(III) π-Allyl Complexes
published pages: 1511-1515, ISSN: 1433-7851, DOI: 10.1002/anie.201912314
Angewandte Chemie International Edition 59/4 2020-03-24

Are you the coordinator (or a participant) of this project? Plaese send me more information about the "GOLD3CAT" project.

For instance: the website url (it has not provided by EU-opendata yet), the logo, a more detailed description of the project (in plain text as a rtf file or a word file), some pictures (as picture files, not embedded into any word file), twitter account, linkedin page, etc.

Send me an  email (fabio@fabiodisconzi.com) and I put them in your project's page as son as possible.

Thanks. And then put a link of this page into your project's website.

The information about "GOLD3CAT" are provided by the European Opendata Portal: CORDIS opendata.

More projects from the same programme (H2020-EU.1.3.2.)

PNAIC (2018)

Positive and Negative Asymmetry in Intergroup Contact: Its Impact on Linguistic Forms of Communication and Physiological Responses

Read More  

miR-IBD (2019)

Fecal miRNAs, new mediators of host-microbiota interaction in Inflammatory Bowel Disease

Read More  

EPIC (2019)

Evolution of Planktonic Gastropod Calcification

Read More