QUCC

Chemistry of the Quantum Kind

 Coordinatore WEIZMANN INSTITUTE OF SCIENCE 

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 Nazionalità Coordinatore Israel [IL]
 Totale costo 1˙982˙908 €
 EC contributo 1˙982˙908 €
 Programma FP7-IDEAS-ERC
Specific programme: "Ideas" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
 Code Call ERC-2013-CoG
 Funding Scheme ERC-CG
 Anno di inizio 2014
 Periodo (anno-mese-giorno) 2014-01-01   -   2018-12-31

 Partecipanti

# participant  country  role  EC contrib. [€] 
1    WEIZMANN INSTITUTE OF SCIENCE

 Organization address address: HERZL STREET 234
city: REHOVOT
postcode: 7610001

contact info
Titolo: Dr.
Nome: Edvardas
Cognome: Narevicius
Email: send email
Telefono: +972 8 934 2121
Fax: +972 8 934 4123

IL (REHOVOT) hostInstitution 1˙982˙908.00
2    WEIZMANN INSTITUTE OF SCIENCE

 Organization address address: HERZL STREET 234
city: REHOVOT
postcode: 7610001

contact info
Titolo: Ms.
Nome: Gabi
Cognome: Bernstein
Email: send email
Telefono: +972 8 934 6728
Fax: +972 8 934 4165

IL (REHOVOT) hostInstitution 1˙982˙908.00

Mappa


 Word cloud

Esplora la "nuvola delle parole (Word Cloud) per avere un'idea di massima del progetto.

reactive    chemical    reactions    temperature    quantum    cold    collision    magnitude    scattering    chemistry    neutral    energies    temperatures    orders    reactants       resonances   

 Obiettivo del progetto (Objective)

'There has been a long-standing quest to observe chemical reactions at low temperatures where reaction rates and pathways are governed by quantum mechanical effects. So far this field of Quantum Chemistry has been dominated by theory. The difficulty has been to realize in the laboratory low enough collisional velocities between neutral reactants, such that the quantum wave nature could be observed. Recently we have demonstrated a new way of studying cold reactive collisions by magnetically merging two fast neutral supersonic beams. After 40 years where the reactive scattering temperature was limited to above 5 K we were able to continuously tune collision energies from hundreds of Kelvin down to 10 mK temperature, a reduction of almost three orders of magnitude [A. B. Henson et. al, Science 338, 234, 2012]. Importantly, we were able to show that at low temperatures quantum effects start dominating reactive dynamics with the first observation of orbiting resonances in a reactive collision. We propose to extend our novel method to study chemical reactions in the regime of Cold Chemistry where the reactants’s de Broglie wavelength becomes larger compared to the characteristic interaction range. Theoretical predictions at low temperatures are extremely sensitive to the parameters used, routinely differing by orders of magnitude leading to contradictions waiting to be settled by experiment. Our ability to reach low enough collision energies and resolve scattering resonances will be used to bring a radical change to transient species spectroscopy. We believe that our work will not only test the central tenets of Quantum Chemistry, but will also provide valuable information to other fields, such as Astrochemistry helping to understand the synthesis of various molecules in interstellar space at temperatures 10 K and below.'

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