HEXANE

Heavy Elements X-ray Absorption Spectroscopies Network

Coordinatore	COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES    more  Organization address address: RUE LEBLANC 25 city: PARIS 15 postcode: 75015 contact info Titolo: Mrs. Nome: Isabelle Cognome: Guez-Grignon Email: send email Telefono: +33 466 796 616 Fax: +33 466 796 133
Nazionalità Coordinatore	France [FR]
Totale costo	63˙000 €
EC contributo	61˙200 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-IRSES-2008
Funding Scheme	MC-IRSES
Anno di inizio	2010
Periodo (anno-mese-giorno)	2010-01-01   -   2013-12-31

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES  Organization address address: RUE LEBLANC 25 city: PARIS 15 postcode: 75015 contact info Titolo: Mrs. Nome: Isabelle Cognome: Guez-Grignon Email: send email Telefono: +33 466 796 616 Fax: +33 466 796 133	FR (PARIS 15)	coordinator	61˙200.00

Mappa

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 Obiettivo del progetto (Objective)

'The hexacyanometallate family is well known in transition metal chemistry because the remarkable electronic delocalization along the metal-cyano-metal bond can be tuned in order to design systems that undergo a controlled change of their physical properties. Heavy elements, and particularly f-transition elements, have a very rich chemistry and their behaviour is still a matter of debate. Actinide elementss are often compared to transition metal elements in the sense that their valence 5f orbitals are partially available for chemical bonding, in contrast with lanthanide elements that mainly form pure ionic bonds. Hexacyanometallate derivatives of heavy cations have been reported, although to a much smaller extent than transition metal derivatives. The goal of this network is to develop a joint experimental and theoretical approach for the full characterization and interpretation of the intramolecular interactions in hexacyanometallate systems of heavy elements. This network will gather experimentalists and theoreticians from France, Germany, Mexico, Spain and the United States, all interested in structural and electronic X-ray absorption spectroscopies of heavy elements. It will also involve three synchrotron facilities, two in Europe and one in the United States, giving access to a wide range of photon energies. The project will involve Master and PhD students and post-doctoral fellows, as well as young and experienced permanent staff from each team. It will reach a balance between exchanges among experimentalists and theoreticians and stays at the synchrotron facilities.'