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GREENLIGHT_REDCAT SIGNED

Towards a Greener Reduction Chemistry by Using Cobalt Coordination Complexes as Catalysts and Light-driven Water Reduction as a Source of Reductive Equivalents

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EC-Contrib. €

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 GREENLIGHT_REDCAT project word cloud

Explore the words cloud of the GREENLIGHT_REDCAT project. It provides you a very rough idea of what is the project "GREENLIGHT_REDCAT" about.

initially    operative    electrocatalysed    expedite    conjugated    water    reaction    kinetics    alcohols    organic    electrophile    substrates    region    proof    merges    immobilization    apolar    source    computational    bonds    entails    reductions    noncovalent    carbon    intermediates    electronics    force    mediated    greener    labelling    sterics    self    atom    chemical    ligands    chiral    electrode    transition    ketones    regard    cavities    structures    hydrides    driving    elaborated    feedstocks    reductive    pockets    1st    interactions    proper    photosensitizer    materials    active    reactivity    mechanisms    homo    inter    supramolecular    complexes    synthesis    photoredox    visible    transform    breaking    ground    catalytic    catalysis    selectivity    row    selective    pi    heterocouplings    enantioselective    renewable    characterizing    alternative    umpolung    couplings    hydrogen    chemicals    intramolecular    catalysts    assembling    protons    aminopyridine    synthetic    aldehydes    electrons    light    catalysed    catalyst    avenue    cobalt    shown    solar    likewise    nature    basic    methodology    fundamental    prerequisite    society    sustainable    performance    performing   

Project "GREENLIGHT_REDCAT" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 1˙999˙063 €
 EC max contribution 1˙999˙063 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2014-CoG
 Funding Scheme ERC-COG
 Starting year 2015
 Duration (year-month-day) from 2015-07-01   to  2020-06-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 1˙999˙063.00

Map

 Project objective

The development of alternative greener synthetic methods to transform renewable feedstocks into elaborated chemical structures mediated by solar light is a prerequisite for a future sustainable society. In this regard, this project entails the use of visible light as driving force and water as a source of hydrides for the synthesis of high-value chemicals. The project merges photoredox catalysis with 1st row transition coordination complexes catalysis to open a new avenue for greener selective catalytic reduction processes for organic substrates. The ground-breaking nature of the project is: A) Develop light-driven region- and/or enantioselective catalytic reductions using well-defined cobalt coordination complexes with aminopyridine ligands, initially developed for water reduction. Sterics, electronics and supramolecular interactions (apolar cavities and chiral pockets) will be studied to proper control of the selectivity in the reduction of i) C=E and C=C bonds and ii) in the C-C inter- and intramolecular reductive homo- or heterocouplings. B) Fundamental understanding of the light-driven cobalt catalysed reductions characterizing intermediates that are involved in the reactivity, kinetics and labelling studies as well as performing computational modelling of reaction mechanisms. The basic understanding of operative mechanisms will expedite a new methodology for electrophile-electrophile umpolung couplings. C) Enhance catalytic performance of the light-driven cobalt catalysed reductions by self-assembling of catalyst-photosensitizer into carbon based pi-conjugated materials through noncovalent supramolecular interactions. Likewise, it will allow electrode immobilization for electrocatalysed reductions using water as a source of protons and electrons. As a proof of concept, cobalt catalysts based on aminopyridine ligands have been shown highly active in the light-driven reduction of ketones and aldehydes to alcohols, using water as the source of hydrogen atom.

 Publications

year authors and title journal last update
List of publications.
2019 Sergio Fernández, Federico Franco, Carla Casadevall, Vlad Martin-Diaconescu, Josep M. Luis, Julio Lloret-Fillol
A Unified Electro- and Photocatalytic CO 2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes
published pages: 120-133, ISSN: 0002-7863, DOI: 10.1021/jacs.9b06633
Journal of the American Chemical Society 142/1 2020-03-23
2019 Miguel Claros, Felix Ungeheuer, Federico Franco, Vlad Martin-Diaconescu, Alicia Casitas, Julio Lloret-Fillol
Reductive Cyclization of Unactivated Alkyl Chlorides with Tethered Alkenes under Visible-Light Photoredox Catalysis
published pages: 4869-4874, ISSN: 1433-7851, DOI: 10.1002/anie.201812702
Angewandte Chemie International Edition 58/15 2020-03-23
2018 Arnau Call, Julio Lloret-Fillol
Enhancement and control of the selectivity in light-driven ketone versus water reduction using aminopyridine cobalt complexes
published pages: 9643-9646, ISSN: 1359-7345, DOI: 10.1039/c8cc04239j
Chemical Communications 54/69 2020-03-23
2019 Arnau Call, Carla Casadevall, Adrian Romero-Rivera, Vlad Martin-Diaconescu, Dayn J. Sommer, Sílvia Osuna, Giovanna Ghirlanda, Julio Lloret-Fillol
Improved Electro- and Photocatalytic Water Reduction by Confined Cobalt Catalysts in Streptavidin
published pages: 5837-5846, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b04981
ACS Catalysis 9/7 2020-03-23
2018 Zoel Codolà, Ilaria Gamba, Ferran Acuña-Parés, Carla Casadevall, Martin Clémancey, Jean-Marc Latour, Josep M. Luis, Julio Lloret-Fillol, Miquel Costas
Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts by Deuteration of Oxidation-Sensitive Sites
published pages: 323-333, ISSN: 0002-7863, DOI: 10.1021/jacs.8b10211
Journal of the American Chemical Society 141/1 2020-03-23
2019 Alberto Bucci, Suvendu Sekhar Mondal, Vlad Martin-Diaconescu, Alexandr Shafir, Julio Lloret-Fillol
Cobalt Amide Imidate Imidazolate Frameworks as Highly Active Oxygen Evolution Model Materials
published pages: 8930-8938, ISSN: 2574-0962, DOI: 10.1021/acsaem.9b01977
ACS Applied Energy Materials 2/12 2020-03-23
2018 Julio Lloret-Fillol, Federico Franco, Mara F. Pinto, Beatriz Royo
A Highly Active N-heterocyclic Carbene MnI complex for Selective Electrocatalytic CO2 Reduction to CO
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201800705
Angewandte Chemie International Edition 2019-06-06
2017 Arnau Call, Carla Casadevall, Ferran Acuña-Parés, Alicia Casitas, Julio Lloret-Fillol
Dual cobalt–copper light-driven catalytic reduction of aldehydes and aromatic ketones in aqueous media
published pages: 4739-4749, ISSN: 2041-6520, DOI: 10.1039/C7SC01276D
Chem. Sci. 8/7 2019-06-06
2018 Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernández, María González-Béjar, Julia Pérez-Prieto, Josep M. Luis, Julio Lloret-Fillol
Understanding light-driven H 2 evolution through the electronic tuning of aminopyridine cobalt complexes
published pages: , ISSN: 2041-6520, DOI: 10.1039/C7SC04328G
Chemical Science 2019-06-06
2018 Ekaterina S. Smirnova, Ferran Acuña-Parés, Eduardo C. Escudero-Adán, Christian Jelsch, Julio Lloret-Fillol
Synthesis and Reactivity of Copper(I) Complexes Based on C 3 -Symmetric Tripodal HTIM(PR 2 ) 3 Ligands
published pages: 2612-2620, ISSN: 1434-1948, DOI: 10.1002/ejic.201800074
European Journal of Inorganic Chemistry 2018/23 2019-06-06
2018 Octavio González-del Moral, Arnau Call, Federico Franco, Alicia Moya, Jose Antonio Nieto-Rodríguez, María Frias, Jose L. G. Fierro, Miquel Costas, Julio Lloret-Fillol, José Alemán, Rubén Mas-Ballesté
Bioinspired Electro-Organocatalytic Material Efficient for Hydrogen Production
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201705655
Chemistry - A European Journal 2019-06-06

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