Opendata, web and dolomites

GREENLIGHT_REDCAT SIGNED

Towards a Greener Reduction Chemistry by Using Cobalt Coordination Complexes as Catalysts and Light-driven Water Reduction as a Source of Reductive Equivalents

Total Cost €

0

EC-Contrib. €

0

Partnership

0

Views

0

 GREENLIGHT_REDCAT project word cloud

Explore the words cloud of the GREENLIGHT_REDCAT project. It provides you a very rough idea of what is the project "GREENLIGHT_REDCAT" about.

mechanisms    catalytic    regard    characterizing    bonds    chemicals    solar    selectivity    materials    driving    labelling    feedstocks    electronics    complexes    visible    intramolecular    cobalt    pi    likewise    prerequisite    row    renewable    self    assembling    transition    electrode    alternative    aminopyridine    1st    proper    structures    catalysed    elaborated    immobilization    performance    alcohols    atom    catalysts    chiral    merges    shown    reductions    protons    ligands    cavities    light    hydrogen    electrons    reactivity    source    apolar    kinetics    basic    proof    photosensitizer    synthetic    force    electrophile    inter    nature    conjugated    electrocatalysed    fundamental    pockets    water    performing    ground    photoredox    operative    breaking    methodology    homo    expedite    couplings    catalysis    society    avenue    greener    chemical    entails    synthesis    reductive    noncovalent    heterocouplings    ketones    hydrides    substrates    organic    aldehydes    active    catalyst    transform    region    umpolung    selective    sustainable    initially    computational    intermediates    supramolecular    mediated    reaction    interactions    enantioselective    sterics    carbon   

Project "GREENLIGHT_REDCAT" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 1˙999˙063 €
 EC max contribution 1˙999˙063 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2014-CoG
 Funding Scheme ERC-COG
 Starting year 2015
 Duration (year-month-day) from 2015-07-01   to  2020-06-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 1˙999˙063.00

Map

 Project objective

The development of alternative greener synthetic methods to transform renewable feedstocks into elaborated chemical structures mediated by solar light is a prerequisite for a future sustainable society. In this regard, this project entails the use of visible light as driving force and water as a source of hydrides for the synthesis of high-value chemicals. The project merges photoredox catalysis with 1st row transition coordination complexes catalysis to open a new avenue for greener selective catalytic reduction processes for organic substrates. The ground-breaking nature of the project is: A) Develop light-driven region- and/or enantioselective catalytic reductions using well-defined cobalt coordination complexes with aminopyridine ligands, initially developed for water reduction. Sterics, electronics and supramolecular interactions (apolar cavities and chiral pockets) will be studied to proper control of the selectivity in the reduction of i) C=E and C=C bonds and ii) in the C-C inter- and intramolecular reductive homo- or heterocouplings. B) Fundamental understanding of the light-driven cobalt catalysed reductions characterizing intermediates that are involved in the reactivity, kinetics and labelling studies as well as performing computational modelling of reaction mechanisms. The basic understanding of operative mechanisms will expedite a new methodology for electrophile-electrophile umpolung couplings. C) Enhance catalytic performance of the light-driven cobalt catalysed reductions by self-assembling of catalyst-photosensitizer into carbon based pi-conjugated materials through noncovalent supramolecular interactions. Likewise, it will allow electrode immobilization for electrocatalysed reductions using water as a source of protons and electrons. As a proof of concept, cobalt catalysts based on aminopyridine ligands have been shown highly active in the light-driven reduction of ketones and aldehydes to alcohols, using water as the source of hydrogen atom.

 Publications

year authors and title journal last update
List of publications.
2019 Sergio Fernández, Federico Franco, Carla Casadevall, Vlad Martin-Diaconescu, Josep M. Luis, Julio Lloret-Fillol
A Unified Electro- and Photocatalytic CO 2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes
published pages: 120-133, ISSN: 0002-7863, DOI: 10.1021/jacs.9b06633
Journal of the American Chemical Society 142/1 2020-03-23
2019 Miguel Claros, Felix Ungeheuer, Federico Franco, Vlad Martin-Diaconescu, Alicia Casitas, Julio Lloret-Fillol
Reductive Cyclization of Unactivated Alkyl Chlorides with Tethered Alkenes under Visible-Light Photoredox Catalysis
published pages: 4869-4874, ISSN: 1433-7851, DOI: 10.1002/anie.201812702
Angewandte Chemie International Edition 58/15 2020-03-23
2018 Arnau Call, Julio Lloret-Fillol
Enhancement and control of the selectivity in light-driven ketone versus water reduction using aminopyridine cobalt complexes
published pages: 9643-9646, ISSN: 1359-7345, DOI: 10.1039/c8cc04239j
Chemical Communications 54/69 2020-03-23
2019 Arnau Call, Carla Casadevall, Adrian Romero-Rivera, Vlad Martin-Diaconescu, Dayn J. Sommer, Sílvia Osuna, Giovanna Ghirlanda, Julio Lloret-Fillol
Improved Electro- and Photocatalytic Water Reduction by Confined Cobalt Catalysts in Streptavidin
published pages: 5837-5846, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b04981
ACS Catalysis 9/7 2020-03-23
2018 Zoel Codolà, Ilaria Gamba, Ferran Acuña-Parés, Carla Casadevall, Martin Clémancey, Jean-Marc Latour, Josep M. Luis, Julio Lloret-Fillol, Miquel Costas
Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts by Deuteration of Oxidation-Sensitive Sites
published pages: 323-333, ISSN: 0002-7863, DOI: 10.1021/jacs.8b10211
Journal of the American Chemical Society 141/1 2020-03-23
2019 Alberto Bucci, Suvendu Sekhar Mondal, Vlad Martin-Diaconescu, Alexandr Shafir, Julio Lloret-Fillol
Cobalt Amide Imidate Imidazolate Frameworks as Highly Active Oxygen Evolution Model Materials
published pages: 8930-8938, ISSN: 2574-0962, DOI: 10.1021/acsaem.9b01977
ACS Applied Energy Materials 2/12 2020-03-23
2018 Julio Lloret-Fillol, Federico Franco, Mara F. Pinto, Beatriz Royo
A Highly Active N-heterocyclic Carbene MnI complex for Selective Electrocatalytic CO2 Reduction to CO
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201800705
Angewandte Chemie International Edition 2019-06-06
2017 Arnau Call, Carla Casadevall, Ferran Acuña-Parés, Alicia Casitas, Julio Lloret-Fillol
Dual cobalt–copper light-driven catalytic reduction of aldehydes and aromatic ketones in aqueous media
published pages: 4739-4749, ISSN: 2041-6520, DOI: 10.1039/C7SC01276D
Chem. Sci. 8/7 2019-06-06
2018 Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernández, María González-Béjar, Julia Pérez-Prieto, Josep M. Luis, Julio Lloret-Fillol
Understanding light-driven H 2 evolution through the electronic tuning of aminopyridine cobalt complexes
published pages: , ISSN: 2041-6520, DOI: 10.1039/C7SC04328G
Chemical Science 2019-06-06
2018 Ekaterina S. Smirnova, Ferran Acuña-Parés, Eduardo C. Escudero-Adán, Christian Jelsch, Julio Lloret-Fillol
Synthesis and Reactivity of Copper(I) Complexes Based on C 3 -Symmetric Tripodal HTIM(PR 2 ) 3 Ligands
published pages: 2612-2620, ISSN: 1434-1948, DOI: 10.1002/ejic.201800074
European Journal of Inorganic Chemistry 2018/23 2019-06-06
2018 Octavio González-del Moral, Arnau Call, Federico Franco, Alicia Moya, Jose Antonio Nieto-Rodríguez, María Frias, Jose L. G. Fierro, Miquel Costas, Julio Lloret-Fillol, José Alemán, Rubén Mas-Ballesté
Bioinspired Electro-Organocatalytic Material Efficient for Hydrogen Production
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201705655
Chemistry - A European Journal 2019-06-06

Are you the coordinator (or a participant) of this project? Plaese send me more information about the "GREENLIGHT_REDCAT" project.

For instance: the website url (it has not provided by EU-opendata yet), the logo, a more detailed description of the project (in plain text as a rtf file or a word file), some pictures (as picture files, not embedded into any word file), twitter account, linkedin page, etc.

Send me an  email (fabio@fabiodisconzi.com) and I put them in your project's page as son as possible.

Thanks. And then put a link of this page into your project's website.

The information about "GREENLIGHT_REDCAT" are provided by the European Opendata Portal: CORDIS opendata.

More projects from the same programme (H2020-EU.1.1.)

HYPATIA (2019)

Privacy and Utility Allied

Read More  

TechChange (2019)

Technological Change: New Sources, Consequences, and Impact Mitigation

Read More  

E-DIRECT (2020)

Evolution of Direct Reciprocity in Complex Environments

Read More