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Towards a Greener Reduction Chemistry by Using Cobalt Coordination Complexes as Catalysts and Light-driven Water Reduction as a Source of Reductive Equivalents

Total Cost €


EC-Contrib. €






 GREENLIGHT_REDCAT project word cloud

Explore the words cloud of the GREENLIGHT_REDCAT project. It provides you a very rough idea of what is the project "GREENLIGHT_REDCAT" about.

intramolecular    electrode    supramolecular    catalysts    electrocatalysed    shown    feedstocks    electrophile    apolar    society    sterics    hydrogen    likewise    self    enantioselective    atom    avenue    nature    protons    merges    ligands    homo    light    noncovalent    heterocouplings    catalyst    proof    immobilization    aldehydes    elaborated    inter    prerequisite    selectivity    materials    catalysis    synthesis    reductions    basic    bonds    kinetics    source    transition    sustainable    assembling    driving    alcohols    labelling    row    cavities    methodology    region    ketones    intermediates    electrons    breaking    pockets    expedite    aminopyridine    selective    performing    reductive    catalysed    proper    active    electronics    synthetic    interactions    greener    pi    complexes    carbon    cobalt    conjugated    initially    photoredox    chemicals    visible    computational    regard    substrates    structures    reactivity    reaction    force    characterizing    photosensitizer    water    catalytic    entails    operative    transform    fundamental    couplings    renewable    hydrides    mechanisms    chiral    mediated    chemical    performance    organic    solar    alternative    ground    1st    umpolung   

Project "GREENLIGHT_REDCAT" data sheet

The following table provides information about the project.


Organization address
postcode: 43007

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 1˙999˙063 €
 EC max contribution 1˙999˙063 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2014-CoG
 Funding Scheme ERC-COG
 Starting year 2015
 Duration (year-month-day) from 2015-07-01   to  2020-06-30


Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 


 Project objective

The development of alternative greener synthetic methods to transform renewable feedstocks into elaborated chemical structures mediated by solar light is a prerequisite for a future sustainable society. In this regard, this project entails the use of visible light as driving force and water as a source of hydrides for the synthesis of high-value chemicals. The project merges photoredox catalysis with 1st row transition coordination complexes catalysis to open a new avenue for greener selective catalytic reduction processes for organic substrates. The ground-breaking nature of the project is: A) Develop light-driven region- and/or enantioselective catalytic reductions using well-defined cobalt coordination complexes with aminopyridine ligands, initially developed for water reduction. Sterics, electronics and supramolecular interactions (apolar cavities and chiral pockets) will be studied to proper control of the selectivity in the reduction of i) C=E and C=C bonds and ii) in the C-C inter- and intramolecular reductive homo- or heterocouplings. B) Fundamental understanding of the light-driven cobalt catalysed reductions characterizing intermediates that are involved in the reactivity, kinetics and labelling studies as well as performing computational modelling of reaction mechanisms. The basic understanding of operative mechanisms will expedite a new methodology for electrophile-electrophile umpolung couplings. C) Enhance catalytic performance of the light-driven cobalt catalysed reductions by self-assembling of catalyst-photosensitizer into carbon based pi-conjugated materials through noncovalent supramolecular interactions. Likewise, it will allow electrode immobilization for electrocatalysed reductions using water as a source of protons and electrons. As a proof of concept, cobalt catalysts based on aminopyridine ligands have been shown highly active in the light-driven reduction of ketones and aldehydes to alcohols, using water as the source of hydrogen atom.


year authors and title journal last update
List of publications.
2019 Sergio Fernández, Federico Franco, Carla Casadevall, Vlad Martin-Diaconescu, Josep M. Luis, Julio Lloret-Fillol
A Unified Electro- and Photocatalytic CO 2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes
published pages: 120-133, ISSN: 0002-7863, DOI: 10.1021/jacs.9b06633
Journal of the American Chemical Society 142/1 2020-03-23
2019 Miguel Claros, Felix Ungeheuer, Federico Franco, Vlad Martin-Diaconescu, Alicia Casitas, Julio Lloret-Fillol
Reductive Cyclization of Unactivated Alkyl Chlorides with Tethered Alkenes under Visible-Light Photoredox Catalysis
published pages: 4869-4874, ISSN: 1433-7851, DOI: 10.1002/anie.201812702
Angewandte Chemie International Edition 58/15 2020-03-23
2018 Arnau Call, Julio Lloret-Fillol
Enhancement and control of the selectivity in light-driven ketone versus water reduction using aminopyridine cobalt complexes
published pages: 9643-9646, ISSN: 1359-7345, DOI: 10.1039/c8cc04239j
Chemical Communications 54/69 2020-03-23
2019 Arnau Call, Carla Casadevall, Adrian Romero-Rivera, Vlad Martin-Diaconescu, Dayn J. Sommer, Sílvia Osuna, Giovanna Ghirlanda, Julio Lloret-Fillol
Improved Electro- and Photocatalytic Water Reduction by Confined Cobalt Catalysts in Streptavidin
published pages: 5837-5846, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b04981
ACS Catalysis 9/7 2020-03-23
2018 Zoel Codolà, Ilaria Gamba, Ferran Acuña-Parés, Carla Casadevall, Martin Clémancey, Jean-Marc Latour, Josep M. Luis, Julio Lloret-Fillol, Miquel Costas
Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts by Deuteration of Oxidation-Sensitive Sites
published pages: 323-333, ISSN: 0002-7863, DOI: 10.1021/jacs.8b10211
Journal of the American Chemical Society 141/1 2020-03-23
2019 Alberto Bucci, Suvendu Sekhar Mondal, Vlad Martin-Diaconescu, Alexandr Shafir, Julio Lloret-Fillol
Cobalt Amide Imidate Imidazolate Frameworks as Highly Active Oxygen Evolution Model Materials
published pages: 8930-8938, ISSN: 2574-0962, DOI: 10.1021/acsaem.9b01977
ACS Applied Energy Materials 2/12 2020-03-23
2018 Julio Lloret-Fillol, Federico Franco, Mara F. Pinto, Beatriz Royo
A Highly Active N-heterocyclic Carbene MnI complex for Selective Electrocatalytic CO2 Reduction to CO
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201800705
Angewandte Chemie International Edition 2019-06-06
2017 Arnau Call, Carla Casadevall, Ferran Acuña-Parés, Alicia Casitas, Julio Lloret-Fillol
Dual cobalt–copper light-driven catalytic reduction of aldehydes and aromatic ketones in aqueous media
published pages: 4739-4749, ISSN: 2041-6520, DOI: 10.1039/C7SC01276D
Chem. Sci. 8/7 2019-06-06
2018 Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernández, María González-Béjar, Julia Pérez-Prieto, Josep M. Luis, Julio Lloret-Fillol
Understanding light-driven H 2 evolution through the electronic tuning of aminopyridine cobalt complexes
published pages: , ISSN: 2041-6520, DOI: 10.1039/C7SC04328G
Chemical Science 2019-06-06
2018 Ekaterina S. Smirnova, Ferran Acuña-Parés, Eduardo C. Escudero-Adán, Christian Jelsch, Julio Lloret-Fillol
Synthesis and Reactivity of Copper(I) Complexes Based on C 3 -Symmetric Tripodal HTIM(PR 2 ) 3 Ligands
published pages: 2612-2620, ISSN: 1434-1948, DOI: 10.1002/ejic.201800074
European Journal of Inorganic Chemistry 2018/23 2019-06-06
2018 Octavio González-del Moral, Arnau Call, Federico Franco, Alicia Moya, Jose Antonio Nieto-Rodríguez, María Frias, Jose L. G. Fierro, Miquel Costas, Julio Lloret-Fillol, José Alemán, Rubén Mas-Ballesté
Bioinspired Electro-Organocatalytic Material Efficient for Hydrogen Production
published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201705655
Chemistry - A European Journal 2019-06-06

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