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PhotoSMM

Single Molecule Magnets light-switching with photochromic ligands

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

PhotoSMM project word cloud

Explore the words cloud of the PhotoSMM project. It provides you a very rough idea of what is the project "PhotoSMM" about.

mo thanks ligand molecular prominent unprecedented ions consumption speed silicon deal modification photochromic directions energy ultimately photo ing life ligands optical magneto light magnetization anisotropic daily reproduce input smm 3d metal bimetallic maximizing behavior association huge storage interconvert monometallic opposite integration electronics induce designed technologies components circuits single magnets magnetic replacement isomeric environments molecule 4f receive isomerization data

Project "PhotoSMM" data sheet

The following table provides information about the project.

Coordinator	UNIVERSITE DE RENNES I Organization address address: RUE DU THABOR 2 city: RENNES CEDEX postcode: 35065 website: www.univ-rennes1.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	France [FR]
Project website	https://iscr.univ-rennes1.fr/omc/dr-lucie-norel
Total cost	119˙901 €
EC max contribution	119˙901 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2015
Funding Scheme	MSCA-IF-GF
Starting year	2016
Duration (year-month-day)	from 2016-09-01 to 2018-08-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	UNIVERSITE DE RENNES I UNIVERSITE DE RENNES I Organization address address: RUE DU THABOR 2 city: RENNES CEDEX postcode: 35065 website: www.univ-rennes1.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	FR (RENNES CEDEX)	coordinator	119˙901.00
2	THE REGENTS OF THE UNIVERSITY OF CALIFORNIA THE REGENTS OF THE UNIVERSITY OF CALIFORNIA Organization address address: FRANKLIN STREET 1111, 12 FLOOR city: OAKLAND CA postcode: 94607 website: http://www.universityofcalifornia.edu/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	US (OAKLAND CA)	partner	0.00

Map

Project objective

The integration of molecular-scale components in circuits may ultimately allow the replacement of silicon-based electronics by high speed systems with low energy consumption. Because of the prominent use of magnetization-based information storage technologies in our daily life, Single-Molecule-Magnets (SMM), which are able to interconvert between two states with opposite magnetization directions receive a great deal of attention. The potential is huge for SMM systems that would demonstrate magnetic field- and light-driven changes in both their optical and magnetic properties because they could reproduce on a single molecule the same type of magneto-optical (MO) effects which are used for some current data storage technologies. Photo-SMM will demonstrate that a light input can induce a modification of the magnetic and optical properties of monometallic or bimetallic SMM. This will be achieved thanks to the unprecedented association of anisotropic ions with photochromic ligands designed to produce very different coordination environments in their two isomeric states, thus maximizing the impact of photo-isomerization on the ligand field experienced by the 4f or 3d metal ions and on the resulting magnetic behavior.

Publications

List of publications.
year	authors and title	journal	last update
2019	Maher Hojorat, Hassan Al Sabea, Lucie Norel, Kevin Bernot, Thierry Roisnel, Frederic Gendron, Boris Le Guennic, Elzbieta Trzop, Eric Collet, Jeffrey R. Long, StÃ©phane Rigaut Hysteresis Photomodulation via Single-Crystal-to-Single-Crystal Isomerization of a Photochromic Chain of Dysprosium Single-Molecule Magnets published pages: 931-936, ISSN: 0002-7863, DOI: 10.1021/jacs.9b10584	Journal of the American Chemical Society 142/2	2020-02-04
2018	Lucie Norel, Lucy E. Darago, Boris Leâ€…Guennic, Khetpakorn Chakarawet, Miguel I. Gonzalez, Jacob H. Olshansky, StÃ©phane Rigaut, Jeffrey R. Long A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201712139	Angewandte Chemie International Edition	2019-06-13

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The information about "PHOTOSMM" are provided by the European Opendata Portal: CORDIS opendata.