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PGOLDCAT SIGNED

Polynuclear Gold Cluster Catalysis

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 PGOLDCAT project word cloud

Explore the words cloud of the PGOLDCAT project. It provides you a very rough idea of what is the project "PGOLDCAT" about.

analogues    performance    mechanism    catalysis    enantioselective    aui    carbon    catalytic    gold    clusters    pgoldcat    activation    synthesis    silver    catalyzed   

Project "PGOLDCAT" data sheet

The following table provides information about the project.

Coordinator
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA 

Organization address
address: AVENIDA PAISSOS CATALANS 16
city: TARRAGONA
postcode: 43007
website: www.iciq.es

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Spain [ES]
 Total cost 170˙121 €
 EC max contribution 170˙121 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme /MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-03-01   to  2019-02-28

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) coordinator 170˙121.00

Mappa

 Project objective

Gold catalysis has become an extremely attractive research field these last decades as it has been considered one of the most effective methodologies for constructing carbon-carbon or carbon-heteroatom bonds. However, the development of enantioselective catalysis mediated by gold is relatively slow, mainly due to (i) the preferred linear two-coordinated mode of AuI complexes in the activation of alkynes, thus making the π-activation substrates distant from the chiral site, and (ii) the lack of mechanism data for enantioselective gold(I)-catalyzed transformations. In this project, PGOLDCAT, we will focus on the synthesis of novel gold clusters, and silver analogues, for the catalytic activation of small molecules. The project includes the study of their catalytic performance in standard reactions and mechanism investigations by comparing the catalytic performance of gold clusters and silver analogues, together with kinetic studies and intermediates optimization by theoretical calculation. Finally, PGOLDCAT will study the application of these new architectures on developing a general asymmetric synthesis of 1,4-enynes. Overall, this research project will expand enantioselective AuI catalysis, giving insights into the gold-catalyzed mechanisms, and applying these catalysts to organic synthetic methodologies. The fellowship will also allow the experienced researcher to increase her network of contacts and follow a personalized career development plan to advance in her path towards an independent academic position.

 Work performed, outcomes and results:  advancements report(s) 

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The information about "PGOLDCAT" are provided by the European Opendata Portal: CORDIS opendata.

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