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AMPLIPORE SIGNED

Understanding negative gas adsorption in highly porous networks for the design of pressure amplifying materials

Total Cost €

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EC-Contrib. €

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Partnership

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 AMPLIPORE project word cloud

Explore the words cloud of the AMPLIPORE project. It provides you a very rough idea of what is the project "AMPLIPORE" about.

combining    micropumps    phenomena    investigations    always    release    explore    point    surrounding    external    networks    certain    outer    counteracts    instrumentation    featuring    paradoxical    inner    tailor    prerequisite    structures    micropore    crystal    instead    give    transformation    time    surface    force    nga    mechanisms    kinetic    solid    react    pressure    elucidate    negative    2016    materials    reservoir    normal    techniques    amplipore    synthetic    elaborate    group    amplifying    innovations    direction    fundamental    adsorption    industrial    mesoscopic    molecular    closed    first    lungs    ranges    phenomenon    signatures    gas    material    pneumatic    transformations    polymers    intrinsic    never    temperature    mesopore    micropneumatic    analytical    area    counterintuitive    thermodynamic    insights    amplification    releasing    boundary    artificial    solely    opposite    microfluidic    macroscopic    physical    selfcompression    tailormade    dynamics    rescue    transportation    reported    actuators    colossal   

Project "AMPLIPORE" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAET DRESDEN 

Organization address
address: HELMHOLTZSTRASSE 10
city: DRESDEN
postcode: 1069
website: http://www.tu-dresden.de/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 2˙363˙125 €
 EC max contribution 2˙363˙125 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2016-ADG
 Funding Scheme ERC-ADG
 Starting year 2017
 Duration (year-month-day) from 2017-09-01   to  2022-08-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAET DRESDEN DE (DRESDEN) coordinator 2˙363˙125.00

Map

 Project objective

Negative gas adsorption (NGA) is a new, counterintuitive and paradoxical phenomenon, for the first time reported by my group in 2016: Normal solid materials with significant outer or inner surface area always take up gas when the pressure in the surrounding reservoir is increased (adsorption). NGA networks instead react at a certain point in the opposite direction: They release gas upon external pressure increase, leading to an overall pressure amplification in a closed system. Comparable phenomena have never been reported before. What is so exciting about NGA? We have a unique material in hand, that counteracts to an external force by force amplification. So far NGA has solely been observed in one of our new coordination polymers, featuring a colossal selfcompression associated with a mesopore-to-micropore transformation. Gas pressure amplifying materials could lead to important innovations in gas releasing rescue systems, pneumatic control systems (production, transportation), micropumps, microfluidic devices, pneumatic actuators, and artificial lungs. A fundamental understanding of the physical mechanisms, structures, and thermodynamic boundary conditions is an essential prerequisite for any industrial application of this counterintuitive phenomenon. Combining strong synthetic methodologies with advanced analytical techniques, AMPLIPORE will elucidate the characteristic molecular and mesoscopic materials signatures as well as thermodynamic boundary conditions of NGA phenomena. We will elaborate a generic NGA-materials concept to tailor the pressure amplification and explore temperature and pressure ranges at which NGA can be applied. Developing tailormade instrumentation for kinetic investigations of NGA will give fundamental insights into the intrinsic and macroscopic dynamics of crystal-to-crystal transformations for applications in micropneumatic systems.

 Publications

year authors and title journal last update
List of publications.
2019 Simon Krause, Jack D. Evans, Volodymyr Bon, Irena Senkovska, Paul Iacomi, Felicitas Kolbe, Sebastian Ehrling, Erik Troschke, Jürgen Getzschmann, Daniel D. Többens, Alexandra Franz, Dirk Wallacher, Pascal G. Yot, Guillaume Maurin, Eike Brunner, Philip L. Llewellyn, François-Xavier Coudert, Stefan Kaskel
Towards General Network Architecture Design Criteria for Negative GasAdsorption Transitions in Ultraporous Frameworks
published pages: , ISSN: 2573-2293, DOI: 10.26434/chemrxiv.7796543.v1
ChemRxiv 2019-05-23
2018 Simon Krause, Volodymyr Bon, Irena Senkovska, Daniel M. Többens, Dirk Wallacher, Renjith S. Pillai, Guillaume Maurin, Stefan Kaskel
The effect of crystallite size on pressure amplification in switchable porous solids
published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-018-03979-2
Nature Communications 9/1 2019-05-23
2019 Jack D. Evans, Simon Krause, Stefan Kaskel, Martin B. Sweatman, Lev Sarkisov
Exploring the thermodynamic criteria for responsive adsorption processes
published pages: , ISSN: 2041-6520, DOI: 10.1039/c9sc01299k
Chemical Science 2019-05-23
2018 Simon Krause, Jack D. Evans, Volodymyr Bon, Irena Senkovska, Sebastian Ehrling, Ulrich Stoeck, Pascal Yot, Paul Iacomi, Philip Llewellyn, Guillaume Maurin, François-Xavier Coudert, Stefan Kaskel
Adsorption Contraction Mechanics: Understanding Breathing Energeticsin Isoreticular Metal-Organic Frameworks
published pages: , ISSN: 2573-2293, DOI: 10.26434/chemrxiv.5962240.v1
ChemRxiv 2019-05-27

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