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PhotoCuRiOT SIGNED

Visible Light-Mediated Copper Photoredox-Catalyzed Ring-Opening Transformations of Activated Small Ring Aza-Heterocycles and Carbacycles

Total Cost €

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EC-Contrib. €

0

Partnership

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 PhotoCuRiOT project word cloud

Explore the words cloud of the PhotoCuRiOT project. It provides you a very rough idea of what is the project "PhotoCuRiOT" about.

transformation    screened    functionalizations    cations    compounds    productively    visible    ring    activated    mediated    radical    primarily    photocatalysts    activate    biologically    catalysts    array    ir    generation    considering    medicine    facile    activation    earth    derivatives    suitably    efficiency    cyclic    stage    cationic    photoinduced    intermediates    designed    annulation    skeletons    substrates    gap    light    containing    appropriate    ru    assisted    reactive    synthetic    prescribed    subsequent    opening    reactions    heterocyclic    benign    ciprofloxacin    photocuriot    phenanthroline    mode    species    bridge    synthesis    aminocarbacycles    azacyclobutanes    motifs    organic    azacyclopropanes    sustainable    amino    harnessed    successful    photoactivation    alternative    varieties    envisaged    successive    functional    transformations    expansion    oxidatively    aza    energy    aforementioned    heterocycles    environmentally    source    copper    utilizing    small    antibiotic    acyclic    functionalized    abundance    complexes    photoredox    catalyst    selective    nucleophiles    moieties    efficient    cu    optimizing    nitrogenous    drugs    tactics    cyclopropylamine   

Project "PhotoCuRiOT" data sheet

The following table provides information about the project.

Coordinator
UNIVERSITAET REGENSBURG 

Organization address
address: UNIVERSITATSSTRASSE 31
city: REGENSBURG
postcode: 93053
website: http://www.uni-regensburg.de/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 159˙460 €
 EC max contribution 159˙460 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-04-01   to  2020-03-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    UNIVERSITAET REGENSBURG DE (REGENSBURG) coordinator 159˙460.00

Map

 Project objective

PhotoCuRiOT is envisaged and designed to develop novel synthetic tactics to biologically significant cyclic and acyclic nitrogenous organic compounds via visible light-mediated Cu(I)-based photoredox catalyst-assisted ring-opening transformation of small ring aza-heterocycles and aminocarbacycles. Considering the earth abundance and low cost, Cu(I)-based complexes, especially copper(I) phenanthroline derivatives, are recently being used as efficient photocatalysts and as low-cost alternative to the Ru or Ir-based complexes. A range of Cu(I)-complexes will be screened for optimizing the efficiency of the aforementioned ring-opening transformation processes. The most effective catalyst will oxidatively activate the substrates and the reactions will proceed through the generation of photoinduced reactive species (primarily amino radical cations) that can be productively harnessed for the synthesis of a range of high-value functional motifs after successive ring opening and annulation with suitably functionalized nucleophiles. PhotoCuRiOT will address the long-standing problem of finding an appropriate classical activation mode for different varieties of small ring aza-heterocycles (non-activated and activated) by offering a unique generic activation mode through the formation of amino radical cationic intermediates. PhotoCuRiOT also aims to bridge the gap between the fields of medicine and energy by enabling facile and highly selective synthesis of a wide array of high value heterocyclic moieties by utilizing copper complexes as environmentally benign photoredox catalysts and visible light as a sustainable source of energy. The successful photoactivation and subsequent ring-opening/expansion transformations of azacyclopropanes and azacyclobutanes would also allow late stage functionalizations of many drugs based on these heterocyclic skeletons such as ciprofloxacin which is a widely-prescribed cyclopropylamine-containing antibiotic.

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The information about "PHOTOCURIOT" are provided by the European Opendata Portal: CORDIS opendata.

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