INDEN

New pincer-type complexes derived from 2-indenylidene ligands

Coordinatore	CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE    more  Organization address address: Rue Michel -Ange 3 city: PARIS postcode: 75794 contact info Titolo: Ms. Nome: Armelle Cognome: Barelli Email: send email Telefono: +33 5 61336080 Fax: +33 5 62172901
Nazionalità Coordinatore	France [FR]
Totale costo	165˙645 €
EC contributo	165˙645 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-2009-IEF
Funding Scheme	MC-IEF
Anno di inizio	2011
Periodo (anno-mese-giorno)	2011-03-01   -   2013-02-28

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE  Organization address address: Rue Michel -Ange 3 city: PARIS postcode: 75794 contact info Titolo: Ms. Nome: Armelle Cognome: Barelli Email: send email Telefono: +33 5 61336080 Fax: +33 5 62172901	FR (PARIS)	coordinator	165˙645.60

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 Obiettivo del progetto (Objective)

'The group of D. Bourissou has recently reported a new family of indenyl-type ligands bearing one or two coordinating side-arms. These new ligands have allowed the preparation of several metal complexes (Zr, Rh, Pd) exhibiting original coordination modes: eta-1 indenyl and 2-indenylidene. In this project, we envision to take advantage of the strong sigma-donor character of such original 2-indenylidene pincer ligands (i) to stabilise oxo and peroxo complexes of late transition metals and (ii) to explore their activity in hydroamination reactions.'