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OMICON SIGNED

Organic Mixed Ion and Electron Conductors for High-Energy Batteries

Total Cost €

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EC-Contrib. €

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Partnership

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 OMICON project word cloud

Explore the words cloud of the OMICON project. It provides you a very rough idea of what is the project "OMICON" about.

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Project "OMICON" data sheet

The following table provides information about the project.

Coordinator
TECHNISCHE UNIVERSITAET GRAZ 

Organization address
address: RECHBAUERSTRASSE 12
city: GRAZ
postcode: 8010
website: www.tugraz.at

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Austria [AT]
 Project website http://www.freunberger-lab.com
 Total cost 1˙494˙253 €
 EC max contribution 1˙494˙253 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2014-STG
 Funding Scheme ERC-STG
 Starting year 2015
 Duration (year-month-day) from 2015-04-01   to  2020-03-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNISCHE UNIVERSITAET GRAZ AT (GRAZ) coordinator 1˙494˙253.00

Map

 Project objective

Energy storage is undeniably amongst the greatest societal challenges. Batteries will be key enablers but require major progress. Battery materials that promise a step-change in energy density compared with current Li-ion batteries rely on fundamentally different reactions to store charge, e.g. Si alloying or O2 reduction instead of intercalation. They have in common high volume changes on cycling and poor conductivity. For the active component of a battery electrode to function it must be simultaneously in contact with ionic and electronic pathways to electrolyte and current collector. State-of-the-art conducting additives and binders in the composite electrodes cannot ensure ideal contact for such materials and fail to exploit their full potential.

In this project I directly target these fundamental challenges of high-energy batteries by replacing now used conducting additives and binders with flexible organic mixed ion and electron conductors that follow volume changes to ensure at any stage intimate contact with ions and electrons. This requires progress with the fundamental science of such conductors, for which to achieve we develop and combine synthetic, electroanalytic and spectroscopic methods, aided by theory. Mixed conducting polymer gels, designed for the particular storage material, shall be elaborated for two ultra-high capacity electrodes, the O2 cathode and the Si anode.

The significant advantage, next to intimate contact, is that the packing density of active material can be maximized. This boosts energy stored by total electrode mass and volume by rigorously cutting the amount of non-active materials compared with current approaches. The expected overriding scientific impact includes improved understanding of mixed conductors concerning synthesis, structure, conductivity and their behaviour in the complex battery environment. This opens up new perspectives for the realm of high-capacity battery materials that demand such a breakthrough to succeed.

 Publications

year authors and title journal last update
List of publications.
2020 Won-Jin Kwak, Rosy, Daniel Sharon, Chun Xia, Hun Kim, Lee R. Johnson, Peter G. Bruce, Linda F. Nazar, Yang-Kook Sun, Aryeh A. Frimer, Malachi Noked, Stefan A. Freunberger, Doron Aurbach
Lithium–Oxygen Batteries and Related Systems: Potential, Status, and Future
published pages: , ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.9b00609
Chemical Reviews 2020-04-04
2020 Yann K. Petit
Singlet oxygen in metal-air batteries: origins, consequences, and mitigation
published pages: , ISSN: , DOI:
2020-04-04
2019 Eléonore Mourad, Yann K. Petit, Riccardo Spezia, Aleksej Samojlov, Francesco F. Summa, Christian Prehal, Christian Leypold, Nika Mahne, Christian Slugovc, Olivier Fontaine, Sergio Brutti, Stefan A. Freunberger
Singlet oxygen from cation driven superoxide disproportionation and consequences for aprotic metal–O 2 batteries
published pages: 2559-2568, ISSN: 1754-5692, DOI: 10.1039/c9ee01453e
Energy & Environmental Science 12/8 2019-12-16
2018 Nika Mahne
Singlet Oxygen in Non-Aqueous Battery Chemistries
published pages: , ISSN: , DOI:
2019-12-16
2019 Won-Jin Kwak, Stefan A. Freunberger, Hun Kim, Jiwon Park, Trung Thien Nguyen, Hun-Gi Jung, Hye Ryung Byon, Yang-Kook Sun
Mutual Conservation of Redox Mediator and Singlet Oxygen Quencher in Lithium–Oxygen Batteries
published pages: 9914-9922, ISSN: 2155-5435, DOI: 10.1021/acscatal.9b01337
ACS Catalysis 9/11 2019-12-16
2019 Stefan A. Freunberger
Interphase identity crisis
published pages: 761-763, ISSN: 1755-4330, DOI: 10.1038/s41557-019-0311-0
Nature Chemistry 11/9 2019-12-16
2018 Christian Leypold
Functional Organic Materials for High Energy Batteries: Soft Mixed Electron and Ion Conductors and Organics in Singlet Oxygen Electrochemistry
published pages: , ISSN: , DOI:
2019-12-16
2019 Christian Prehal, Aleksej Samojlov, Manfred Nachtnebel, Manfred Kriechbaum, Heinz Amenitsch, Stefan A. Freunberger
Exclusive solution discharge in Li-O2 batteries as revealed by in situ small angle X-ray scattering
published pages: , ISSN: 1476-4660, DOI:
Nature Materials 2019-12-16
2019 Won-Jin Kwak, Rosy, Daniel Sharon, Chun Xia, Hun Kim, Lee R. Johnson, Peter G. Bruce, Linda F. Nazar, Yang-Kook Sun, Aryeh A. Frimer, Malachi Noked, Stefan A. Freunberger, Doron Aurbach
Lithium-Oxygen Batteries and Related Systems: Potential, Status and Future
published pages: , ISSN: 0009-2665, DOI:
Chemical Reviews 2019-12-16
2019 Eléonore Mourad, Yann K. Petit, Christian Leypold, Andreas Windischbacher, Daniel Mijailovic, Christian Slugovc, Sergey M. Borisov, Egbert Zojer, Sergio Brutti, Olivier Fontaine Stefan A. Freunberger
Mechanism of mediated alkali peroxide oxidation reveals strategies to suppress singlet oxygen formation
published pages: , ISSN: 1755-4349, DOI:
Nature Chemistry 2019-12-16
2019 Won-Jin Kwak, Hun Kim, Yann K. Petit, Christian Leypold, Trung Thien Nguyen, Nika Mahne, Paul Redfern, Larry A. Curtiss, Hun-Gi Jung, Sergey M. Borisov, Stefan A. Freunberger, Yang-Kook Sun
Deactivation of redox mediators in lithium-oxygen batteries by singlet oxygen
published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-019-09399-0
Nature Communications 10/1 2019-12-16
2016 Stefan A. Freunberger
Batteries: Charging ahead rationally
published pages: 16074, ISSN: 2058-7546, DOI: 10.1038/nenergy.2016.74
Nature Energy 1/6 2019-05-24
2017 Lukas Schafzahl, Nika Mahne, Bettina Schafzahl, Martin Wilkening, Christian Slugovc, Sergey M. Borisov, Stefan A. Freunberger
Singulett-Sauerstoff in der aprotischen Natrium-O 2 -Batterie
published pages: , ISSN: 0044-8249, DOI: 10.1002/ange.201709351
Angewandte Chemie 2019-05-24
2017 Lukas Schafzahl, Nika Mahne, Bettina Schafzahl, Martin Wilkening, Christian Slugovc, Sergey M. Borisov, Stefan A. Freunberger
Singlet Oxygen during Cycling of the Aprotic Sodium-O 2 Battery
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201709351
Angewandte Chemie International Edition 2019-05-24
2017 Nika Mahne, Olivier Fontaine, Musthafa Ottakam Thotiyl, Martin Wilkening, Stefan A. Freunberger
Mechanism and performance of lithium–oxygen batteries – a perspective
published pages: 6716-6729, ISSN: 2041-6520, DOI: 10.1039/C7SC02519J
Chemical Science 8/10 2019-05-24
2016 Eléonore Mourad, Laura Coustan, Pierre Lannelongue, Dodzi Zigah, Ahmad Mehdi, André Vioux, Stefan A. Freunberger, Frédéric Favier, Olivier Fontaine
Biredox ionic liquids with solid-like redox density in the liquid state for high-energy supercapacitors
published pages: 446-453, ISSN: 1476-1122, DOI: 10.1038/NMAT4808
Nature Materials 16/4 2019-05-24

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