Explore the words cloud of the SILION project. It provides you a very rough idea of what is the project "SILION" about.
The following table provides information about the project.
TECHNISCHE UNIVERSITAET MUENCHEN
|Coordinator Country||Germany [DE]|
|Total cost||1˙499˙942 €|
|EC max contribution||1˙499˙942 € (100%)|
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
|Duration (year-month-day)||from 2015-12-01 to 2020-11-30|
Take a look of project's partnership.
|1||TECHNISCHE UNIVERSITAET MUENCHEN||DE (MUENCHEN)||coordinator||1˙499˙942.00|
|2||TECHNISCHE UNIVERSITAT BERLIN||DE (BERLIN)||participant||0.00|
This ERC-StG 2014 proposal, SILION, outlines a strategy for the one-pot synthesis, characterization, and reactivity investigation of a positively charged, electron-deficient, highly Lewis acidic, cationic silicon(II) species, denoted “silyliumylidene ions”. Silyliumylidene ion has only four valence electrons, consisting of a lone pair of electrons and two vacant orbitals on the central silicon atom. It will be expected to bear the best combined character of both silylenes as silicon analogue of carbene and silylium ions as silicon analogue of carbenium ions. The program described herein is also aimed at the development of silyliumylidene ion as novel catalysts based on main group elements. The proposed silyliumylidene ions should fulfil the following criteria: a) compounds can be synthesized by a facile one-pot reaction of the corresponding dichlorosilane with two equivalents of N-heterocyclic carbenes, b) silyliumylidene ions will potentially possess three reactive sites including (i) a lone pair at the silicon center, (ii) p-orbital at the silicon center, and (iii) N-heterocyclic carbenes, c) thanks to their strong sigma-donor as well as pi-acceptor ability, the highly reactive silyliumylidene ions are expected to serve as innovative reagents for activation of organic small molecules, excellent catalysts, and strikingly versatile coordination ligands toward transition metals. The target of this proposal is the introduction of facile accessible silyliumylidene ions, which are combined the best properties of silylene and silylium ions, and development of its reactivity and catalytic activity. The synthesis of silyliumylidene ions is straightforward and should allow the investigation of electronic and steric properties of the substituents and N-heterocyclic carbenes. It is anticipated that novel silyliumylidene ions can be used for a promising new building block for low-valent organosilicon compounds and high-performance catalysts.
|year||authors and title||journal||last update|
Tatsumi Ochiai, Tibor SzilvÃ¡si, Daniel Franz, Elisabeth Irran, Shigeyoshi Inoue
Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines
published pages: 11619-11624, ISSN: 1433-7851, DOI: 10.1002/anie.201605636
|Angewandte Chemie International Edition 55/38||2019-05-28|
Amelie Porzelt, Julia Schweizer, Ramona Baierl, Philipp Altmann, Max Holthausen, Shigeyoshi Inoue
Sâ€“H Bond Activation in Hydrogen Sulfide by NHC-Stabilized Silyliumylidene Ions
published pages: 54, ISSN: 2304-6740, DOI: 10.3390/inorganics6020054
Daniel Franz, Lorenz Sirtl, Alexander PÃ¶thig, Shigeyoshi Inoue
Aluminum Hydrides Stabilized by N-Heterocyclic Imines as Catalysts for Hydroborations with Pinacolborane
published pages: 1245-1250, ISSN: 0044-2313, DOI: 10.1002/zaac.201600313
|Zeitschrift fÃ¼r anorganische und allgemeine Chemie 642/22||2019-05-27|
Debotra Sarkar, Daniel Wendel, Syed Usman Ahmad, Tibor SzilvÃ¡si, Alexander PÃ¶thig, Shigeyoshi Inoue
Chalcogen-atom transfer and exchange reactions of NHC-stabilized heavier silaacylium ions
published pages: 16014-16018, ISSN: 1477-9226, DOI: 10.1039/C7DT03998K
|Dalton Transactions 46/46||2019-05-27|
Prasenjit Bag, Syed Usman Ahmad, Shigeyoshi Inoue
Synthesis and Reactivity of Functionalized Silicon(II) Compounds: Iminosilylene, Phosphinosilylene, Hydrosilylene, and Related Compounds
published pages: 255-271, ISSN: 0009-2673, DOI: 10.1246/bcsj.20160284
|Bulletin of the Chemical Society of Japan 90/3||2019-05-27|
Daniel Franz, Tibor SzilvÃ¡si, Alexander PÃ¶thig, Franziska Deiser, Shigeyoshi Inoue
Three-Coordinate Boron(III) and Diboron(II) Dications
published pages: 4283-4288, ISSN: 0947-6539, DOI: 10.1002/chem.201800609
|Chemistry - A European Journal 24/17||2019-05-27|
Daniel Franz, Shigeyoshi Inoue
Advances in the development of complexes that contain a group 13 element chalcogen multiple bond
published pages: 9385-9397, ISSN: 1477-9226, DOI: 10.1039/C6DT01413E
|Dalton Trans. 45/23||2019-05-27|
Tatsumi Ochiai, Tibor SzilvÃ¡si, Shigeyoshi Inoue
Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines
published pages: 1155, ISSN: 1420-3049, DOI: 10.3390/molecules21091155
Tatsumi Ochiai, Daniel Franz, Shigeyoshi Inoue
Applications of N-heterocyclic imines in main group chemistry
published pages: 6327-6344, ISSN: 0306-0012, DOI: 10.1039/C6CS00163G
|Chem. Soc. Rev. 45/22||2019-05-27|
Vitaly Nesterov, Nora C. Breit, Shigeyoshi Inoue
Advances in Phosphasilene Chemistry
published pages: 12014-12039, ISSN: 0947-6539, DOI: 10.1002/chem.201700829
|Chemistry - A European Journal 23/50||2019-05-27|
Catherine Weetman, Shigeyoshi Inoue
The Road Travelled: After Main-Group Elements as Transition Metals
published pages: 4213-4228, ISSN: 1867-3880, DOI: 10.1002/cctc.201800963
Philipp Frisch, Shigeyoshi Inoue
Coinage metal complexes of NHC-stabilized silyliumylidene ions
published pages: 13658-13661, ISSN: 1359-7345, DOI: 10.1039/c8cc07754a
|Chemical Communications 54/97||2019-03-07|
Vitaly Nesterov, Dominik Reiter, Prasenjit Bag, Philipp Frisch, Richard Holzner, Amelie Porzelt, Shigeyoshi Inoue
NHCs in Main Group Chemistry
published pages: 9678-9842, ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.8b00079
|Chemical Reviews 118/19||2019-03-07|
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