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MULTISURF

MULTI-functional metallic SURFaces via active Layered Double Hydroxide treatments

Total Cost €

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EC-Contrib. €

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Partnership

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Project "MULTISURF" data sheet

The following table provides information about the project.

Coordinator
HELMHOLTZ-ZENTRUM GEESTHACHT ZENTRUM FUR MATERIAL- UND KUSTENFORSCHUNG GMBH 

Organization address
address: MAX PLANCK STRASSE 1
city: GEESTHACHT
postcode: 21502
website: www.gkss.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Project website https://www.hzg.de/multisurf
 Total cost 648˙000 €
 EC max contribution 648˙000 € (100%)
 Programme 1. H2020-EU.1.3.3. (Stimulating innovation by means of cross-fertilisation of knowledge)
 Code Call H2020-MSCA-RISE-2014
 Funding Scheme MSCA-RISE
 Starting year 2015
 Duration (year-month-day) from 2015-01-01   to  2018-12-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    HELMHOLTZ-ZENTRUM GEESTHACHT ZENTRUM FUR MATERIAL- UND KUSTENFORSCHUNG GMBH DE (GEESTHACHT) coordinator 238˙500.00
2    SMALLMATEK - SMALL MATERIALS AND TECHNOLOGIES LDA PT (AVEIRO) participant 144˙000.00
3    UNIVERSIDADE DE AVEIRO PT (AVEIRO) participant 135˙000.00
4    AIRBUS DEFENCE AND SPACE GMBH DE (TAUFKIRCHEN) participant 130˙500.00
5    BELARUSIAN STATE UNIVERSITY BY (MINSK) partner 0.00

Map

 Project objective

The main objective of the proposal is development of active multi-functional surfaces with high level of self-healing ability on the basis of Layered Double Hydroxide (LDH) structures formed on different industrially relevant metallic substrates. The main idea of the project is based on “smart” triggered release on demand for functional organic or inorganic anionic compounds intercalated into intergallery spaces of LDHs. The active functionality is achieved via controllable substrate-governed growth of LDH architectures on Al, Mg and Zn based alloys. The functional anions such as corrosion inhibitors, biocides, drugs, or hydrophobic agents are introduced into the intergallery spaces during the growth of LDH or upon a post-treatment stage. The release of the functional agents occurs only on demand when the respective functionality is triggered by the relevant external stimuli such as presence of anions or local pH change. The proposal focuses on two main applications, namely aeronautical and automotive. The active LDH treatments can bring significant benefits when applied in these situations. The respective relevant substrates are chosen as the main objects of interest: Mg alloys for both applications; Al alloys for both transportation industries as well; galvanized steel as a main material for automobiles. Moreover the suggested surface treatments, especially the one with active self-healing ability, are also considered for light-weight multi-material structures which are prone to fast galvanically-induced corrosion. The increase of the fault tolerance and reliability of hybrid designs is aimed in this case. The suggested surface treatments can offer possibility for fast implementation of the process at industrial level. The main expected impacts are related to the improvement of the life cycle of the light-weight structures utilized in transport industries via optimization of the maintenance schedules and increasing the fault tolerance.

 Deliverables

List of deliverables.
Knowledge exchange and outreach activities Documents, reports 2019-05-06 17:10:16

Take a look to the deliverables list in detail:  detailed list of MULTISURF deliverables.

 Publications

year authors and title journal last update
List of publications.
2019 D.E.L. Vieira, D. Sokol, A. Smalenskaite, A. Kareiva, M.G.S. Ferreira, J.M. Vieira, A.N. Salak
Cast iron corrosion protection with chemically modified Mg Al layered double hydroxides synthesized using a novel approach
published pages: 158-163, ISSN: 0257-8972, DOI: 10.1016/j.surfcoat.2019.07.028
Surface and Coatings Technology 375 2019-09-17
2017 D. Mata, M. Serdechnova, M. Mohedano, C. L. Mendis, S. V. Lamaka, J. Tedim, T. Hack, S. Nixon, M. L. Zheludkevich
Hierarchically organized Li–Al-LDH nano-flakes: a low-temperature approach to seal porous anodic oxide on aluminum alloys
published pages: 35357-35367, ISSN: 2046-2069, DOI: 10.1039/C7RA05593E
RSC Advances 7/56 2019-05-30
2017 Maria Serdechnova, Marta Mohedano, Anissa Bouali, Daniel Höche, Boris Kuznetsov, Sergey Karpushenkov, Carsten Blawert, Mikhail Zheludkevich
Role of Phase Composition of PEO Coatings on AA2024 for In-Situ LDH Growth
published pages: 190, ISSN: 2079-6412, DOI: 10.3390/coatings7110190
Coatings 7/11 2019-05-30
2016 M. Serdechnova, M. Mohedano, B. Kuznetsov, C. L. Mendis, M. Starykevich, S. Karpushenkov, J. Tedim, M. G .S. Ferreira, C. Blawert, M. L. Zheludkevich
PEO Coatings with Active Protection Based on In-Situ Formed LDH-Nanocontainers
published pages: C36-C45, ISSN: 0013-4651, DOI: 10.1149/2.0301702jes
Journal of The Electrochemical Society 164/2 2019-05-30
2016 B. Kuznetsov, M. Serdechnova, J. Tedim, M. Starykevich, S. Kallip, M. P. Oliveira, T. Hack, S. Nixon, M. G. S. Ferreira, M. L. Zheludkevich
Sealing of tartaric sulfuric (TSA) anodized AA2024 with nanostructured LDH layers
published pages: 13942-13952, ISSN: 2046-2069, DOI: 10.1039/C5RA27286F
RSC Adv. 6/17 2019-05-30
2017 Tiago L. P. Galvão, Cristina S. Neves, Mikhail L. Zheludkevich, José R. B. Gomes, João Tedim, Mário G. S. Ferreira
How Density Functional Theory Surface Energies May Explain the Morphology of Particles, Nanosheets, and Conversion Films Based on Layered Double Hydroxides
published pages: 2211-2220, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.6b10860
The Journal of Physical Chemistry C 121/4 2019-05-30
2016 Maria Serdechnova, Andrei N. Salak, Filipe S. Barbosa, Daniel E.L. Vieira, João Tedim, Mikhail L. Zheludkevich, Mário G.S. Ferreira
Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1,2,3-benzotriazolate anions in layered double hydroxides: In situ X-ray diffraction study
published pages: 158-165, ISSN: 0022-4596, DOI: 10.1016/j.jssc.2015.10.023
Journal of Solid State Chemistry 233 2019-05-30
2017 M. Mohedano, M. Serdechnova, M. Starykevich, S. Karpushenkov, A.C. Bouali, M.G.S. Ferreira, M.L. Zheludkevich
Active protective PEO coatings on AA2024: Role of voltage on in-situ LDH growth
published pages: 36-46, ISSN: 0264-1275, DOI: 10.1016/j.matdes.2017.01.097
Materials & Design 120 2019-05-30
2016 J. Tedim, A.C. Bastos, S. Kallip, M.L. Zheludkevich, M.G.S. Ferreira
Corrosion protection of AA2024-T3 by LDH conversion films. Analysis of SVET results
published pages: 215-224, ISSN: 0013-4686, DOI: 10.1016/j.electacta.2016.05.134
Electrochimica Acta 210 2019-05-30

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