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N2FEED SIGNED

N2 as Chemical Feedstock – Synthetic Nitrogen Fixation beyond Haber-Bosch

Total Cost €

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EC-Contrib. €

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Partnership

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 N2FEED project word cloud

Explore the words cloud of the N2FEED project. It provides you a very rough idea of what is the project "N2FEED" about.

nitrides    energy    feedstock    molecular    dinitrogen    purpose    subprojects    feasibility    pharmaceuticals    nh3    functional    metal    homogeneous    physical    direct    individually    serve    fundamentally    bond    hence    thereby    consumption    primary    nitrogen    examined    nitrenoid    catalysts    chemistry    record    elementary    ambient    synthesis    splitting    bound    complexes    storage    compounds    platforms    broken    initial    haber    small    rational    transfer    modern    fertilizers    molecules    forcing    fuels    effort    contributions    group    combination    species    activation    bosch    polymers    gives    functionalization    ammonia    catalytic    goals    circumvent    despite    serves    ligands    limited    transition    inorganic    strive    de    compound    almost    containing    computational    subsequent    longstanding    transformation    bioinspired    industrial    fixation    electron    coupling    source    secondary    n2    basis    synthetic    chemicals    yields    pincer    hydrogenation    chemical    besides   

Project "N2FEED" data sheet

The following table provides information about the project.

Coordinator
GEORG-AUGUST-UNIVERSITAT GOTTINGENSTIFTUNG OFFENTLICHEN RECHTS 

Organization address
address: WILHELMSPLATZ 1
city: GOTTINGEN
postcode: 37073
website: http://www.uni-goettingen.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 1˙998˙500 €
 EC max contribution 1˙998˙500 € (100%)
 Programme 1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
 Code Call ERC-2014-CoG
 Funding Scheme ERC-COG
 Starting year 2015
 Duration (year-month-day) from 2015-06-01   to  2020-05-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    GEORG-AUGUST-UNIVERSITAT GOTTINGENSTIFTUNG OFFENTLICHEN RECHTS DE (GOTTINGEN) coordinator 1˙998˙500.00

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 Project objective

The chemical transformation of dinitrogen is one of the most important industrial processes. Thereby produced ammonia serves as nitrogen source for almost any synthetic nitrogen containing compound, such as fertilizers or many polymers and pharmaceuticals. However, despite forcing conditions associated with high energy consumption, the Haber-Bosch process gives low yields in NH3. Hence, homogeneous, bioinspired nitrogen fixation is a longstanding goal, yet with very limited success. In this proposal, we strive to circumvent the Haber-Bosch process for the synthesis of N-containing chemicals by direct N2 functionalization upon initial splitting into molecular nitrides at ambient conditions and subsequent C–N bond formation. Catalytic platforms will be developed based on late, electron rich transition metal complexes with functional pincer ligands, which represents a fundamentally new approach for this purpose. The overall N2 functionalization effort will be broken down into three elementary steps, i.e. N2 splitting, de-/hydrogenation of metal bound N-species, and C–N bond formation. These subprojects are examined individually with a combination of modern synthetic, physical inorganic, and computational methods. These results will finally enable the rational design of homogeneous catalysts. Hence, besides the primary goal to directly use N2 as chemical feedstock this project will also serve the secondary objectives of making important contributions to related timely and challenging topics, such as C–N coupling by nitrenoid transfer or the use of nitrogen compounds, especially ammonia, as chemical fuels in energy storage applications. The previous record of my group in the chemistry of electron-rich transition metal complexes with functional pincer ligands, N2 splitting/coupling, and the activation of other N-containing small-molecules provide a strong basis for the feasibility of these challenging goals.

 Publications

year authors and title journal last update
List of publications.
2019 Florian Schendzielorz, Markus Finger, Josh Abbenseth, Christian Würtele, Vera Krewald, Sven Schneider
Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen
published pages: 830-834, ISSN: 1433-7851, DOI: 10.1002/anie.201812125
Angewandte Chemie International Edition 58/3 2020-02-06
2019 Bastian Schluschaß, Josh Abbenseth, Serhiy Demeshko, Markus Finger, Alicja Franke, Christian Herwig, Christian Würtele, Ivana Ivanovic-Burmazovic, Christian Limberg, Joshua Telser, Sven Schneider
Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction
published pages: 10275-10282, ISSN: 2041-6520, DOI: 10.1039/c9sc03779a
Chemical Science 10/44 2020-02-06
2019 Josh Abbenseth, Martin Diefenbach, Alexander Hinz, Lukas Alig, Christian Würtele, Jose M. Goicoechea, Max C. Holthausen, Sven Schneider
Oxidative Coupling of Terminal Rhenium Pnictide Complexes
published pages: 10966-10970, ISSN: 1433-7851, DOI: 10.1002/anie.201905130
Angewandte Chemie International Edition 58/32 2020-02-06
2019 Daniel Delony, Markus Kinauer, Martin Diefenbach, Serhiy Demeshko, Christian Würtele, Max C. Holthausen, Sven Schneider
A Terminal Iridium Oxo Complex with a Triplet Ground State
published pages: 10971-10974, ISSN: 1433-7851, DOI: 10.1002/anie.201905325
Angewandte Chemie International Edition 58/32 2020-02-06
2018 Lukas Alig, Maximilian Fritz, Sven Schneider
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
published pages: 2681-2751, ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.8b00555
Chemical Reviews 119/4 2020-02-06
2017 Gleb A. Silantyev, Moritz Förster, Bastian Schluschaß, Josh Abbenseth, Christian Würtele, Christian Volkmann, Max C. Holthausen, Sven Schneider
Dinitrogen Splitting Coupled to Protonation
published pages: 5966-5970, ISSN: 0044-8249, DOI: 10.1002/ange.201701504
Angewandte Chemie 129/21 2020-02-04
2019 Josh Abbenseth, Daniel Delony, Marc C. Neben, Christian Würtele, Bas de Bruin, Sven Schneider
Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer
published pages: 6338-6341, ISSN: 1433-7851, DOI: 10.1002/anie.201901470
Angewandte Chemie International Edition 58/19 2020-02-04
2018 Felix Schneck, Florian Schendzielorz, Nareh Hatami, Markus Finger, Christian Würtele, Sven Schneider
Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex
published pages: 14690-14695, ISSN: 0044-8249, DOI: 10.1002/ange.201803396
Angewandte Chemie 130/44 2020-02-04
2017 Josh Abbenseth, Martin Diefenbach, Sarah C. Bete, Christian Würtele, Christian Volkmann, Serhiy Demeshko, Max C. Holthausen, Sven Schneider
A square-planar osmium( ii ) complex
published pages: 5511-5514, ISSN: 1359-7345, DOI: 10.1039/c7cc01569k
Chemical Communications 53/40 2020-02-04
2018 Isabel Klopsch, Florian Schendzielorz, Christian Volkmann, Christian Würtele, Sven Schneider
Synthesis of Benzonitrile from Dinitrogen
published pages: 916-919, ISSN: 0044-2313, DOI: 10.1002/zaac.201800181
Zeitschrift für anorganische und allgemeine Chemie 644/17 2020-02-04
2016 Isabel Klopsch, Markus Kinauer, Markus Finger, Christian Würtele, Sven Schneider
Conversion of Dinitrogen into Acetonitrile under Ambient Conditions
published pages: 4864-4867, ISSN: 0044-8249, DOI: 10.1002/ange.201600790
Angewandte Chemie 128/15 2020-02-04
2018 Felix Schneck, Florian Schendzielorz, Nareh Hatami, Markus Finger, Christian Würtele, Sven Schneider
Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201803396
Angewandte Chemie International Edition 2019-05-30
2018 Arne Glüer, Sven Schneider
Iron catalyzed hydrogenation and electrochemical reduction of CO 2 : The role of functional ligands
published pages: 159-173, ISSN: 0022-328X, DOI: 10.1016/j.jorganchem.2018.02.025
Journal of Organometallic Chemistry 861 2019-05-30
2016 Florian S. Schendzielorz, Markus Finger, Christian Volkmann, Christian Würtele, Sven Schneider
A Terminal Osmium(IV) Nitride: Ammonia Formation and Ambiphilic Reactivity
published pages: 11417-11420, ISSN: 1433-7851, DOI: 10.1002/anie.201604917
Angewandte Chemie International Edition 55/38 2019-05-30
2018 Quinton J. Bruch, Brian M. Lindley, Bjorn Askevold, Sven Schneider, Alexander J. M. Miller
A Ruthenium Hydrido Dinitrogen Core Conserved across Multielectron/Multiproton Changes to the Pincer Ligand Backbone
published pages: 1964-1975, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.7b02889
Inorganic Chemistry 57/4 2019-05-30
2017 Felix Schneck, Markus Finger, Moniek Tromp, Sven Schneider
Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand
published pages: 33-37, ISSN: 0947-6539, DOI: 10.1002/chem.201604407
Chemistry - A European Journal 23/1 2019-05-30
2018 Brian M. Lindley, Richt S. van Alten, Markus Finger, Florian Schendzielorz, Christian Würtele, Alexander J. M. Miller, Inke Siewert, Sven Schneider
Mechanism of Chemical and Electrochemical N 2 Splitting by a Rhenium Pincer Complex
published pages: , ISSN: 0002-7863, DOI: 10.1021/jacs.8b03755
Journal of the American Chemical Society 2019-05-30
2016 Isabel Klopsch, Markus Kinauer, Markus Finger, Christian Würtele, Sven Schneider
Conversion of Dinitrogen into Acetonitrile under Ambient Conditions
published pages: 4786-4789, ISSN: 1433-7851, DOI: 10.1002/anie.201600790
Angewandte Chemie International Edition 55/15 2019-05-30
2018 Markus Kinauer, Martin Diefenbach, Heiko Bamberger, Serhiy Demeshko, Edward J. Reijerse, Christian Volkmann, Christian Würtele, Joris van Slageren, Bas de Bruin, Max C. Holthausen, Sven Schneider
An iridium( iii / iv / v ) redox series featuring a terminal imido complex with triplet ground state
published pages: 4325-4332, ISSN: 2041-6520, DOI: 10.1039/C8SC01113C
Chemical Science 9/18 2019-05-30
2016 Josh Abbenseth, Markus Finger, Christian Würtele, Müge Kasanmascheff, Sven Schneider
Coupling of terminal iridium nitrido complexes
published pages: 469-477, ISSN: 2052-1553, DOI: 10.1039/C5QI00267B
Inorg. Chem. Front. 3/4 2019-05-30
2018 Felix Schneck, Jennifer Ahrens, Markus Finger, A. Claudia Stückl, Christian Würtele, Dirk Schwarzer, Sven Schneider
The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion
published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-018-03239-3
Nature Communications 9/1 2019-05-30
2017 Gleb A. Silantyev, Moritz Förster, Bastian Schluschaß, Josh Abbenseth, Christian Würtele, Christian Volkmann, Max C. Holthausen, Sven Schneider
Dinitrogen Splitting Coupled to Protonation
published pages: 5872-5876, ISSN: 1433-7851, DOI: 10.1002/anie.201701504
Angewandte Chemie International Edition 56/21 2019-05-30
2017 Josh Abbenseth, Sarah C. Bete, Markus Finger, Christian Volkmann, Christian Würtele, Sven Schneider
Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”
published pages: 802-811, ISSN: 0276-7333, DOI: 10.1021/acs.organomet.7b00707
Organometallics 37/5 2019-05-30

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