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SDchirnanocat SIGNED

Sputtering-deposition of metallic nanoparticles onto chiral ionic liquids andapplications in enantioselective hydrogenation

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

SDchirnanocat project word cloud

Explore the words cloud of the SDchirnanocat project. It provides you a very rough idea of what is the project "SDchirnanocat" about.

lt place recyclable synthesis metallic ratio melting separation merge synthesized fast catalytic bulk innocent act advantage catalysts subsequent hydrogenation prevent stabilizing reactions onto converge excellent sdchirnanocat degree newly employment agglomeration easily stabilizers sputtering chiral chemicals instead il media liquids ionic attracted induce asymmetric context broaden environmentally technique surface nanoparticles techniques directionality metal shape tuning point molecules industry recycling immobilized materials start clean ils chemical organic impose size competencies leads salts deposition ordm reducing sd mnps fine appropriate innovative catalysis sound contrast solvents agents fellow mnp independent prepared substrates adds physical avoiding position career small medium

Project "SDchirnanocat" data sheet

The following table provides information about the project.

Coordinator	THE UNIVERSITY OF NOTTINGHAM Organization address address: University Park city: NOTTINGHAM postcode: NG7 2RD website: www.nottingham.ac.uk contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	United Kingdom [UK]
Project website	http://www.nottingham.ac.uk/chemistry/research/research.aspx
Total cost	195˙454 €
EC max contribution	195˙454 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2015
Funding Scheme	MSCA-IF-EF-ST
Starting year	2016
Duration (year-month-day)	from 2016-08-01 to 2018-07-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	THE UNIVERSITY OF NOTTINGHAM THE UNIVERSITY OF NOTTINGHAM Organization address address: University Park city: NOTTINGHAM postcode: NG7 2RD website: www.nottingham.ac.uk contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	UK (NOTTINGHAM)	coordinator	195˙454.00

Map

Project objective

The production of fine chemicals, such as chiral molecules, is one of the main applications of the chemical industry. However, any new process developed should be environmentally sound. Metallic nanoparticles (MNPs) have attracted a large interest as catalytic materials due to their small size and high surface to bulk metal ratio, which leads to a greater catalytic activity. These catalysts are easily recyclable, although stabilizing agents are required to prevent agglomeration. In this context, ionic liquids (ILs), salts with melting point <100 ºC, can act both as stabilizers and as solvents. Moreover, MNPs may be immobilized in this medium, allowing the separation of the products and the subsequent recycling of the system. However, ILs are not “innocent” media and can impose a high degree of directionality over the substrates. The employment of chiral ILs adds a new advantage: its potential use in asymmetric catalysis to induce the formation of chiral products. In this project we will merge the asymmetric properties of newly synthesized ILs with the catalytic activity of MNPs. Instead of classical chemical methods, MNPs in ILs will be obtained by sputtering-deposition (SD), an innovative physical technique which enables the fast synthesis of clean MNPs, avoiding the use of organic solvents and reducing agents. In contrast to other physical techniques, the SD of MNPs onto ILs allows the control of the size and shape of MNPs by the appropriate tuning of the sputtering conditions. These three concepts (MNP, chiral IL and SD) converge into the main aim of this project: The development of a novel chiral catalytic system based on MNPs prepared by SD onto chiral ILs for asymmetric hydrogenation reactions. SDchirnanocat will contribute to broaden the fellow competencies and will place him in an excellent position to start an independent career.

Publications

List of publications.
year	authors and title	journal	last update
2018	Salma Mumtaz, Israel Cano, Nargis Mumtaz, Ahmed Abbas, Jairton Dupont, Humaira Yasmeen Gondal Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates published pages: 20821-20826, ISSN: 1463-9076, DOI: 10.1039/c8cp03881c	Physical Chemistry Chemical Physics 20/32	2019-06-13
2018	Israel Cano, Luis M. MartÃnez-Prieto, Laure Vendier, Piet W. N. M. van Leeuwen An iridiumâ€“SPO complex as bifunctional catalyst for the highly selective hydrogenation of aldehydes published pages: 221-228, ISSN: 2044-4753, DOI: 10.1039/c7cy01953j	Catalysis Science & Technology 8/1	2019-06-13

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