#	Pagina
attuale pagina	/open-h2020/projects/201258/index.html

Opendata, web and dolomites

SDchirnanocat SIGNED

Sputtering-deposition of metallic nanoparticles onto chiral ionic liquids andapplications in enantioselective hydrogenation

Total Cost €

EC-Contrib. €

Partnership

Views

Outcomes and
results

SDchirnanocat project word cloud

Explore the words cloud of the SDchirnanocat project. It provides you a very rough idea of what is the project "SDchirnanocat" about.

directionality prevent newly subsequent fellow medium bulk ordm molecules attracted synthesized media easily ionic stabilizers physical avoiding sdchirnanocat agents solvents melting advantage sound shape mnps mnp competencies sputtering leads innovative fine immobilized stabilizing recycling salts chiral il chemicals agglomeration merge ratio lt onto hydrogenation induce small context prepared catalysis reactions separation materials contrast tuning metal substrates reducing size impose appropriate organic catalysts synthesis recyclable start act technique employment ils excellent sd instead place degree surface position point techniques clean asymmetric career metallic independent catalytic adds industry innocent environmentally converge liquids deposition chemical broaden nanoparticles fast

Project "SDchirnanocat" data sheet

The following table provides information about the project.

Coordinator	THE UNIVERSITY OF NOTTINGHAM Organization address address: University Park city: NOTTINGHAM postcode: NG7 2RD website: www.nottingham.ac.uk contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	United Kingdom [UK]
Project website	http://www.nottingham.ac.uk/chemistry/research/research.aspx
Total cost	195˙454 €
EC max contribution	195˙454 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2015
Funding Scheme	MSCA-IF-EF-ST
Starting year	2016
Duration (year-month-day)	from 2016-08-01 to 2018-07-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	THE UNIVERSITY OF NOTTINGHAM THE UNIVERSITY OF NOTTINGHAM Organization address address: University Park city: NOTTINGHAM postcode: NG7 2RD website: www.nottingham.ac.uk contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	UK (NOTTINGHAM)	coordinator	195˙454.00

Map

Project objective

The production of fine chemicals, such as chiral molecules, is one of the main applications of the chemical industry. However, any new process developed should be environmentally sound. Metallic nanoparticles (MNPs) have attracted a large interest as catalytic materials due to their small size and high surface to bulk metal ratio, which leads to a greater catalytic activity. These catalysts are easily recyclable, although stabilizing agents are required to prevent agglomeration. In this context, ionic liquids (ILs), salts with melting point <100 ºC, can act both as stabilizers and as solvents. Moreover, MNPs may be immobilized in this medium, allowing the separation of the products and the subsequent recycling of the system. However, ILs are not “innocent” media and can impose a high degree of directionality over the substrates. The employment of chiral ILs adds a new advantage: its potential use in asymmetric catalysis to induce the formation of chiral products. In this project we will merge the asymmetric properties of newly synthesized ILs with the catalytic activity of MNPs. Instead of classical chemical methods, MNPs in ILs will be obtained by sputtering-deposition (SD), an innovative physical technique which enables the fast synthesis of clean MNPs, avoiding the use of organic solvents and reducing agents. In contrast to other physical techniques, the SD of MNPs onto ILs allows the control of the size and shape of MNPs by the appropriate tuning of the sputtering conditions. These three concepts (MNP, chiral IL and SD) converge into the main aim of this project: The development of a novel chiral catalytic system based on MNPs prepared by SD onto chiral ILs for asymmetric hydrogenation reactions. SDchirnanocat will contribute to broaden the fellow competencies and will place him in an excellent position to start an independent career.

Publications

List of publications.
year	authors and title	journal	last update
2018	Salma Mumtaz, Israel Cano, Nargis Mumtaz, Ahmed Abbas, Jairton Dupont, Humaira Yasmeen Gondal Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates published pages: 20821-20826, ISSN: 1463-9076, DOI: 10.1039/c8cp03881c	Physical Chemistry Chemical Physics 20/32	2019-06-13
2018	Israel Cano, Luis M. MartÃnez-Prieto, Laure Vendier, Piet W. N. M. van Leeuwen An iridiumâ€“SPO complex as bifunctional catalyst for the highly selective hydrogenation of aldehydes published pages: 221-228, ISSN: 2044-4753, DOI: 10.1039/c7cy01953j	Catalysis Science & Technology 8/1	2019-06-13

Are you the coordinator (or a participant) of this project? Plaese send me more information about the "SDCHIRNANOCAT" project.

For instance: the website url (it has not provided by EU-opendata yet), the logo, a more detailed description of the project (in plain text as a rtf file or a word file), some pictures (as picture files, not embedded into any word file), twitter account, linkedin page, etc.

Send me an email (fabio@fabiodisconzi.com) and I put them in your project's page as son as possible.

Thanks. And then put a link of this page into your project's website.

The information about "SDCHIRNANOCAT" are provided by the European Opendata Portal: CORDIS opendata.