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LiDeNiAc SIGNED

Ligand Design for Nitrogen Activation

Total Cost €

0

EC-Contrib. €

0

Partnership

0

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 LiDeNiAc project word cloud

Explore the words cloud of the LiDeNiAc project. It provides you a very rough idea of what is the project "LiDeNiAc" about.

flagship    training    interdisciplinary    researcher    chemistry    co2    explore    vanadium    materials    ligands    profile    sub    metal    tested    fix    polydendate    applicants    sustainable    benefit    links    molybdenum    harsh    acquire    massive    skills    optimize    accompanied    functionalization    bosch    population    stabilize    emissions    intensive    assimilated    sufficient    bio    crops    structure    mild    n2    resource    plants    atmospheric    vital    complexes    quality    reactive    synthesized    efficient    phosphaalkenes    career    collaborative    ammonia    contrast    bacteria    dinitrogen    inorganic    haber    host    global    homogenous    opportunity    leadership    lower    line    platform    environmental    plays    potent    utilize    usually    nitrogen    valent    feed    donor    electronic    sharpen    transition    energy    subsequent    metals    disciplines    manner    class    solution    renewable    combining    last    incorporating    catalysis    comprehensively    activation    industrially   

Project "LiDeNiAc" data sheet

The following table provides information about the project.

Coordinator
LEIBNIZ - INSTITUT FUR KATALYSE EV AN DER UNIVERSITAT ROSTOCK 

Organization address
address: ALBERT-EINSTEIN-STRASSE 29A
city: ROSTOCK
postcode: 18059
website: www.catalysis.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 171˙460 €
 EC max contribution 171˙460 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-06-01   to  2020-05-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    LEIBNIZ - INSTITUT FUR KATALYSE EV AN DER UNIVERSITAT ROSTOCK DE (ROSTOCK) coordinator 171˙460.00

Map

 Project objective

Nitrogen plays a vital role in the production of sufficient crops to feed a growing global population. While atmospheric nitrogen cannot be directly assimilated by plants, bacteria can fix nitrogen under mild conditions to provide bio-available ammonia. In contrast, industrially ammonia is produced under harsh conditions in the Haber Bosch process, which is energy intensive and accompanied by massive emissions of CO2. Therefore, this project seeks to explore more sustainable pathways of dinitrogen activation and its subsequent functionalization. The utilization of renewable N2 is also in line with the “Resource-efficient Europe” flagship initiatives to optimize the use of materials in order to lower the environmental impact. Systems capable of dinitrogen activation in homogenous solution usually build on highly reduced transition metal complexes. In the proposed studies a novel class of polydendate ligands incorporating phosphaalkenes as a design feature will be synthesized to provide a potent platform for further functionalization. The experienced researcher will utilize these ligands as a donor to stabilize low-valent, highly reactive complexes of the bio-relevant metals molybdenum and vanadium. In a last step these systems will be tested in the activation of dinitrogen and their electronic structure will be comprehensively characterized, in a collaborative manner within the host institute, providing the applicant with high-quality technical training. The project links various sub-disciplines of chemistry and is therefore clearly interdisciplinary, combining the applicants experience in inorganic chemistry with the host-institute’s leadership in catalysis. It is therefore expected that the proposed studies represent an opportunity for the experienced researcher to acquire new skills in the design of ligands for novel complexes capable of nitrogen activation, which is expected to further sharpen the researcher's profile and to benefit his future career.

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The information about "LIDENIAC" are provided by the European Opendata Portal: CORDIS opendata.

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