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CuZnSyn SIGNED

Understanding Copper–Zinc Synergy for Carbon Dioxide Hydrogenation

Total Cost €

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EC-Contrib. €

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Partnership

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 CuZnSyn project word cloud

Explore the words cloud of the CuZnSyn project. It provides you a very rough idea of what is the project "CuZnSyn" about.

significantly    conversion    proximal    connection    direct    co2    hydrogenation    stereo    realistic    climate    zinc    host    active    gaining    vectors    combination    electronic    carbon    groups    interfaces    fuels    12    framework    reaction    conjunction    mechanistic    promoter    oxide    streams    fuel    catalysts    profiles    construction    site    interconversion    energy    dense    characterisation    fundamental    analysed    skills    cuzn    complexes    once    industrial    invaluable    green    critical    meticulously    activation    societal    gas    subsequent    intermediates    isolation    centres    incorporates    debated    isolate    block    adding    methanol    ligand    synergy    special    tuneable    attractive    nanoparticles    tandem    deleterious    deep    multimetallic    synthesis    gain    dioxide    ligands    species    generation    sustainable    made    waste    building    isolated    heterogeneous    sequestering    greenhouse    series    uses    copper    alumina    poorly    harnessed    beneficial    catalyst    binding   

Project "CuZnSyn" data sheet

The following table provides information about the project.

Coordinator
IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE 

Organization address
address: SOUTH KENSINGTON CAMPUS EXHIBITION ROAD
city: LONDON
postcode: SW7 2AZ
website: http://www.imperial.ac.uk/

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country United Kingdom [UK]
 Total cost 224˙933 €
 EC max contribution 224˙933 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2019
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2020
 Duration (year-month-day) from 2020-06-01   to  2022-05-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE UK (LONDON) coordinator 224˙933.00

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 Project objective

Carbon dioxide (CO2) is a greenhouse gas that is significantly contributing to climate change. In tandem with advances in sequestering carbon, beneficial uses for CO2 are of high societal importance for developing a sustainable future. One attractive use of CO2 is in its conversion to energy dense fuels (green energy vectors). One such fuel is methanol, made from CO2 via hydrogenation in conjunction with a multimetallic catalyst. The current best industrial (heterogeneous) catalyst incorporates copper and zinc-oxide nanoparticles with an alumina support. A special synergy is observed between the copper (active site) and zinc (reaction promoter), but these species and their connection is poorly defined and remains debated.

This project aims to isolate proximal copper and zinc centres, the fundamental building block for the construction of critical copper–zinc interfaces, within a well-defined, and highly tuneable ligand framework. Once isolated, the binding, activation and interconversion of key intermediates along the CO2 hydrogenation pathway will be meticulously analysed.

Work package 1 involves the synthesis and characterisation of a series of 12 ligands that encompass a range of stereo-electronic profiles, and subsequent isolation of CuZn complexes using these ligands. Work package 2 will use the complexes to study the activation and interconversion of key intermediates along the CO2 hydrogenation pathway to gain mechanistic understanding. Finally, work package 3 will test the most active complexes as catalysts for the direct hydrogenation of CO2 to methanol.

The combination of my skills (multimetallic systems) and the host groups (mechanistic studies) make achieving the project aims realistic. The knowledge harnessed from gaining deep mechanistic understanding of the synergy between copper and zinc during CO2 hydrogenation will be invaluable in developing the next generation of catalysts for methanol production, adding value to a deleterious waste streams.

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The information about "CUZNSYN" are provided by the European Opendata Portal: CORDIS opendata.

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